Abstract
A series of functionalized carbonaceous adsorbents were prepared by means of reaction with urea and chemical activation of Polish brown coal. In order to obtain nitrogen groups bonded in different ways to the carbon structure, the reaction with urea was performed at two different stages of processing, with precursor or char. Additionally, the influence of annealing under nitrogen atmosphere at 600 and 800 °C or in hydrogen/nitrogen mixture at 600 °C on the textural, acid–base and thermal properties of activated carbons prepared was tested. The resulting materials were characterized by elemental analysis, low-temperature nitrogen sorption, determination of the number of surface oxygen groups as well as by thermogravimetric study in helium atmosphere. The final products were microporous nitrogen-enriched activated carbons of very well-developed surface area reaching from 1303 to 2004 m2 g−1, showing different content of nitrogen (from 0.5 to 2.3 mass%) and different chemical character of the surface (from weakly acidic to intermediate acidic–basic), depending on the sequence of particular processes and variant of further thermochemical treatment. According to the results of thermal study, the nitrogen functional groups introduced into the carbon structure by the reaction with urea (especially at the char stage) show moderate thermal and chemical stability. Under the effect of high temperature, some of these groups underwent decomposition or transformation into more thermally stable nitrogen species. It was also proved that the thermochemical treatment of modified activated carbons led to considerable deterioration of their textural parameters as well as caused significant changes in the acid–base character of their surface.
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Introduction
Modified adsorbents have been for a long time the subject of interest of research groups all over the world [1–9] mainly because of a wide spectrum of their application. They are used both in protection of the natural environment as adsorbents of toxic gases [10–14] or liquids [15, 16] and in modern industry as catalyst or catalyst supports [17–19] as well as electrode materials for electrochemical capacitors [20, 21]. This wide range of their use is a consequence of their unique properties determined by the well-developed porous structure and the possibility of their modification with different functional groups incorporated into their structure. No wonder that much research work aimed at development of new materials of the target physicochemical properties at optimization of the already known ones is continuously going on.
Of particular interest from among modified carbon materials are those enriched in oxygen and/or nitrogen functional groups. The first attempts at developing such materials date back to the beginning of the twentieth century when the activated carbon materials were obtained by pyrolysis and activation of organic substances containing significant amounts of nitrogen, like polyamides or animal blood. It was followed by the period of intense studies on the obtaining of nitrogenized activated carbons and their potential use.
As follows from literature data, the materials can be obtained by many ways, but all of them are based on one of the three fundamental methods: (1) thermal processing of the precursor or activated carbon in the presence of the so-called N-reagents, so compounds containing nitrogen in their structure (e.g. ammonia [22, 23], urea [24, 25], nitrogen oxides [26], hydroxyl amine and hydrazine [27], (2) pyrolysis/activation (mainly physical) of polymers or rich in nitrogen vegetation origin precursors (e.g. polyacrylonitrile [28], polyamides [29], polyimides [30] and waste material left after soybean growing and processing [31]; and (3) impregnation of carbons with solutions of amines and imines of any order [32, 33] or coating carbons with a layer of polymers containing nitrogen in their structure [34]. Depending on the type of precursor and the variant of its modification, the carbon materials obtained are characterized by different contents of nitrogen and their different types, i.e. different types of functional groups and their different position in the carbon structure.
In previous studies, nitrogen-doped activated carbons have been prepared mainly by physical activation with steam or carbon dioxide, whereas much less attention has been paid to chemical methods of activation. Therefore, the main aim of this study was to obtain nitrogen-enriched activated carbons by reaction with urea and chemical activation of brown coal and to check the influence of thermochemical treatment on their textural, acid–base and thermal properties.
Experimental
Materials preparation
The starting raw sample (S) was prepared from Polish brown coal (Konin colliery, ash = 25.3 mass%, volatile matter = 55.6 mass%, moisture = 11.3 mass%, fixed carbon = 61.4 mass%). At the beginning, the precursor was milled and sieved to the grain size of 0.5–1 mm and then it was subjected to demineralization by treatment with concentrated HCl and HF. After that, the demineralized coal (D) was subjected to two different modes of treatment: (1) reaction with urea followed by pyrolysis and chemical activation by KOH (UPA sample) and (2) pyrolysis followed by reaction with urea and chemical activation (PUA sample). The unmodified activated carbon (PA) was used as a reference.
Incorporation of nitrogen (U): 20 g of carbonaceous materials was impregnated with urea at the mass ratio of 1:1, dried at 110 °C to constant mass and then subjected to thermal treatment. The process proceeded in a glass reactor under atmospheric pressure for 3 h, at 350 °C, in air flow (100 mL min−1). The nitrogen-enriched materials were washed with hot distilled water in order to remove the unreacted part of urea and dried to constant mass. Nitrogen was incorporated to demineralized coal as well as to the product of its pyrolysis.
Pyrolysis (P) was performed in a quartz tubular reactor heated by a resistance furnace at 700 °C, under argon flow (flow rate of 170 mL min−1). The samples were heated at the rate 5 °C min−1 from room temperature to final pyrolysis temperature, maintained for 1 h and finally cooled down to room temperature.
Activation (A): KOH was directly mixed at room temperature with samples at the mass ratio of 4:1. After the physical mixing, the samples were heated at 700 °C under argon flow (flow rate 330 mL min−1) for 45 min, in a ceramic tubular reactor heated by a resistance furnace. The obtained activated carbons were washed first with 5 % HCl solution and then with distilled water until free of chloride ions. The washed activated carbons were dried at 110 °C to constant mass.
Thermochemical treatment of the activated carbons: all prepared samples were subjected to annealing for 3 h in three variants: under nitrogen atmosphere at 600 °C (6), under nitrogen atmosphere at 800 °C (8) and in hydrogen/nitrogen mixture at 600 °C (H).
Analytical procedures
Proximate analysis of the starting material (determination of moisture, ash and volatile matter) was performed according to PN-80/G-04511, PN-ISO 1171:2002 and PN-ISO 562:2000 standards, respectively. Elemental analysis of all samples under investigation was carried out using the Elementar Analysensysteme instrument, model Vario EL III.
The textural characterization of the samples was based on nitrogen adsorption–desorption isotherms measured at −196 °C with a Quantachrome Autosorb iQ surface area analyser. Before measurements, the samples were out-gassed at 150 °C for 8 h. Surface area and pore size distribution were calculated by BET (Brunauer–Emmett–Teller) and BJH (Barrett–Joyner–Halenda) methods, respectively. Average pore diameter and total pore volume were determined as well. Micropores volume was calculated using the t-plot method. The calculations of the PSDs (pore size distributions) were performed using the carbon–N2 NLDFT standard slit model implemented in the SAIEUS software (Micromeritics), www.nldft.com.
The surface functional groups of acidic and basic character were determined according to the Boehm method.
Thermogravimetric analysis of investigated materials was performed on a SETSYS 12, made by Setaram. The samples (~20 mg, particle size below 0.1 mm) were heated at the rate 10 °C min−1, from room temperature to 900 °C, under helium atmosphere.
Results and discussion
Elemental composition of materials prepared
According to the data presented in Table 1, demineralization removes over 97 % of the mineral substance from the raw brown coal and leads to only insignificant changes in the organic components of this coal. Thermochemical treatment of the demineralized coal (irrespective of the variant) brings a substantial increase in the content of Cdaf, accompanied by a slight increase in the nitrogen contribution (in UPA and PUA samples) and considerable decrease in the content of the other elements. These changes are certainly related to the high temperature of the processes, which is responsible for breaking of the least stable chemical bonds present in the material, removal of heteroatoms in the form of simple gas or liquid compounds and consequently for the ordering of carbonaceous structure. The increase in nitrogen content observed for UPA and PUA samples is most probably related to the nitrogen building into the carbon structure during the reaction with urea, in the form of amines, amides, imines, lactams or nitriles [35, 36]. Nevertheless, under the effect of high temperature (during pyrolysis or activation processes), a considerable part of these groups underwent decomposition or transformation to more thermally stable nitrogen species (e.g. N-5, N-6 or N-Q [35, 36]) and consequently the amount of nitrogen in the products of activation is not too high, especially for sample PUA, modified with nitrogen just before the activation process. High-temperature treatment of the demineralized coal causes also a significant increase in the ash content, as evidenced by the fact that the activation products are characterized by almost twice higher content of mineral substances than the starting material.
As follows from further analysis of the data collected in Table 1, each of the post-activation treatments performed led to significant changes in the content of mineral substance and in the contribution of particular elements (C, H, N, S, O) in the activated carbons structure. The character of changes depends significantly on the variant of modification and to a lower extent on the type of material subjected to the thermochemical treatment. First of all, we can observe a significant increase in the contribution of carbon, accompanied by a simultaneous decrease in the oxygen content as well as slight changes in the nitrogen and hydrogen content. These changes are more pronounced for UPAH, PUAH and PAH samples, annealed at 600 °C in nitrogen/hydrogen mixture. Exposure of the activated carbon to N2/H2 mixture leads mainly to a considerable decrease in the content of oxygen (over twofold) and nitrogen. Annealing of the activated carbons under a stream of nitrogen (even at 800 °C) causes smaller changes in the elemental composition, than heat treatment in N2/H2 mixture. Similarly as for UPAH, PUAH and PAH samples, we can observe a decrease in the oxygen content, especially for UPA8, PUA8 and PA8 samples, but the intensity of these changes is much lower. It should be also noted that the nitrogen content decreases to a much smaller extent. This fact indicates a relatively high thermal stability of the nitrogen groups present in the activated carbons structure. On the other hand, a significant decrease in the nitrogen content observed for UPAH and PUAH samples (heated in a stream of N2/H2) suggests weak chemical bonds of the introduced nitrogen functional groups. However, verification of this supposition needs further studies.
Acid–base properties of materials prepared
To establish the acid–base properties of the activated carbon samples obtained, the contents of functional groups of acidic or basic character were determined. As follows from the data presented in Table 2, the carbonaceous materials differ significantly in the number and type of acidic and basic functional groups. The content of the surface functional groups depends to a high extent on the sequence of processes to which the demineralized coal was subjected (reaction with urea, pyrolysis, activation). The greatest amount of surface groups (from among the materials not subjected to post-activation treatment) was determined in sample UPA subjected to the reaction with urea at the stage of precursor, while the lowest was in the sample unmodified with nitrogen (PA). Moreover, for all the activated carbons not subjected to heat treatment, a great (almost twofold) predominance of acidic groups was observed. The amount of acidic and basic moieties (similarly as the total content of functional groups) to a high degree depends on the stage at which the sample was subjected to reaction with urea.
According to the data presented in Table 2, annealing of the activated carbons under nitrogen or nitrogen/hydrogen mixture results in substantial changes in their acid–base properties. Irrespective of the variant of thermal treatment, we observed mainly a significant decrease in the acidic group content. This process occurs with the highest efficiency for the samples heated at 800 °C in nitrogen atmosphere, especially for UPA8 sample, which contains almost twice less acidic species on their surface, than UPA sample, not subjected to thermal modification. These changes are certainly related to the high temperature of the process, which contributes to the decomposition of acidic moieties. In the samples modified in N2/H2 mixture and nitrogen atmosphere at 600 °C, the changes are similar to the former, but are less pronounced. Moreover, all of the samples subjected to heat treatment are characterized by lower content of surface groups of basic character than the corresponding unmodified activated carbons; however, the difference is not so much pronounced as for the acidic moieties.
Textural parameters of materials prepared
Textural parameters of the samples studied were determined from the low-temperature nitrogen adsorption/desorption measurements performed on a Quantachrome Autosorb iQ surface area analyser. As follows from the results shown in Table 3, all the activated carbons prepared from brown coal have well-developed surface area and porous structure with dominant contribution of micropores. The efficiency of porous structure development depends on the sequence of the processes to which the demineralized coal was subjected. The activated carbons subjected to reaction with urea at the stage of demineralized coal (UPA) and at the stage of char (PUA) have much greater surface area than those to which nitrogen was not introduced (PA). The same tendency is observed for total pore volume as well as micropore contribution. The most probable reason for such a strong development of the porous structure of the samples enriched in nitrogen (in particular at the precursor stage) is the enhanced reactivity of the modified precursor and char towards activating agent, following from the presence of reactive nitrogen and oxygen functional groups introduced upon reaction with urea, which promote a stronger development of the porous structure.
Table 3 data clearly illustrate a considerable influence of the conditions of post-activation heat treatment on the porous structure of the activated carbons. As shown, thermal modification of UPA, PUA as well as PA samples (both in nitrogen and nitrogen/hydrogen atmosphere) leads to the deterioration of their surface area and pore volume. This phenomenon is probably a result of destruction of walls between neighbouring pores and formation of wider micropores and small mesopores. This hypothesis is confirmed by a considerable increase in the average pore diameter as well as by a simultaneous decrease in micropores contribution. The deterioration of textural parameters after thermal modification is the most pronounced for the activated carbons heated in nitrogen atmosphere at 800 °C, especially for UPA8 and PUA8 samples, whose surface area is over 20 % lower than for the corresponding samples UPA and PUA, not subjected to heat treatment. A similar tendency is observed for UPA6, UPAH and PUA6 samples. For the remaining activated carbons annealed at 600 °C (under N2 or N2/H2 atmosphere), the deterioration of surface area is lower and varies from 3 to 12 %.
Microporous character of the structure of the activated carbons obtained is also confirmed by the pore size distributions presented in Figs. 1–3 . According to these results, the porous structure of all carbons studied mainly contains micropores and small mesopores of diameters below 30 Å. Analysis of the results also implies that different variants of thermochemical treatment cause different changes in the contributions of particular type pores. A decrease in the contribution of micropores of diameters about 10 Å is observed accompanied by an increase in the contribution of pores of larger diameters. It is particularly well seen for samples UPA and PUA annealed under N2 at 800 °C or in N2/H2 atmosphere.
Thermal properties of materials prepared
Thermal properties of the samples under investigation were characterized by thermogravimetric measurements in the helium atmosphere. As follows from the character of TG and DTG curves, presented in Figs. 4–9, the activated carbons differ significantly in thermal stability. The thermal properties of the materials studied depend on the sequence of the processes to which the demineralized coal was subjected as well as on the variant of the post-activation heat treatment. The most thermally stable (among samples not subjected to post-activation treatment) is sample PA, to which nitrogen was not introduced at any stage of processing. The total mass loss for this sample is only 4 % (Fig. 6). The DTG curve recorded for this sample (Fig. 9) shows four slightly marked minima: at about 50–60 °C corresponding to the desorption of the physically adsorbed water, at about 250 and 400 °C which can be assigned to decomposition of poorly thermally stable oxygen functional groups generated on the carbon surface upon the activation process (such as carboxyl and lactone groups), while the minima at 620–630 °C can be attributed to decomposition of acidic anhydrides. There is also a broad peak above 700 °C which can be related to slow decomposition of the organic components of carbon matrix.
For the nitrogen-enriched activated carbons (UPA and PUA, Figs. 4, 5, respectively), the mass loss is considerably higher and reaches up to 12–13 %. The DTG curves of these samples (Figs. 7, 8) also show a characteristic minimum attributed to the desorption of physisorbed water (at 60–80 °C); however, it is much more pronounced than for sample PA, particularly for the sample subjected to the reaction with urea at the precursor stage (UPA). The presence of this minimum suggests that incorporation of significant amount of nitrogen and oxygen functional groups causes a considerable increase in the hydrophilic properties of the samples’ surfaces. The DTG curves of UPA and PUA show also two very broad peaks with minima at about 270–320 and 700–720 °C. The first of them can be assigned to the decomposition of poorly thermally stable nitrogen moieties introduced upon reaction with urea (for example imines and lactams) as well as oxygen groups generated during chemical activation with KOH. The second peak can be assigned to the decomposition of nitrogen groups in which nitrogen is built into the aromatic ring, so pyridine, pyrrole or pyridine N-oxide.
As follows from further analysis of the data presented in Figs. 6–9, each of the post-activation treatments performed resulted in significant changes in the thermal properties of activated carbons. As a result of annealing of the activated carbons in nitrogen atmosphere (especially at 800 °C), the thermal stability of the samples considerably increases. It is clearly evidenced by the lower mass loss during the thermogravimetric study (Figs. 4–6) as well as by the lower intensity of particular minima observed on DTG curves and their shift to higher temperatures. It is particularly well seen for samples UPA6 and UPA8 (Fig. 7). A similar effect can be achieved by exposition of the activated carbon to a nitrogen/hydrogen mixture. However, thermal stability of so-prepared materials is intermediate between the values obtained for the samples heated in nitrogen at 600 and 800 °C.
Conclusions
The above-discussed results have proved that it is possible to obtain from brown coal a large gamut of nitrogen-enriched activated carbons of very well-developed porous structure, showing different content of nitrogen and acid–base properties of the surface, depending on the sequence of particular processes and variant of thermochemical treatment.
Thermal study results have evidenced that nitrogen functional groups introduced into carbon structure by the reaction with urea show moderate thermal and chemical stability. Under the effect of high temperature and/or potassium hydroxide, a part of these groups underwent decomposition or transformation into more thermally stable nitrogen species. However, verification of this supposition needs further studies.
It has been also proved that the thermochemical treatment of nitrogen-enriched activated carbons led to considerable deterioration of their textural parameters as well as caused significant changes in the acid–base character of their surface.
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Acknowledgements
This work was partially supported by Ministry of Science and Higher Education of Poland (Project Iuventus Plus No. IP2012 004072).
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Nowicki, P. Effect of heat treatment on the physicochemical properties of nitrogen-enriched activated carbons. J Therm Anal Calorim 125, 1017–1024 (2016). https://doi.org/10.1007/s10973-016-5254-8
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DOI: https://doi.org/10.1007/s10973-016-5254-8