Abstract
Calcium-aluminoborate (CAB) glasses were developed to sequester new waste compositions made of several rare-earth oxides generated from the pyrochemical reprocessing of spent nuclear fuel. Several important wasteform properties such as waste loading, processability and chemical durability were evaluated. The maximum waste loading of the CAB compositions was determined to be ~56.8 wt%. Viscosity and the electrical conductivity of the CAB melt at 1300 °C were 7.817 Pa·s and 0.4603 S/cm, respectively, which satisfies the conditions for commercial cold-crucible induction melting (CCIM) process. Addition of rare-earth oxides to CAB glasses resulted in dramatic decreases in the elemental releases of B and Ca in aqueous dissolution experiments. Normalized elemental releases from product consistency standard chemical durability test were <3.62·10−5 g·m−2 for Nd, 0.009 g·m−2 for Al, 0.067 g·m−2 for B and 0.073 g·m−2 for Ca (at 90, after 7 days, for SA/V = 2000m−1); all meet European and US regulation limits. After 20 d of dissolution, a hydrated alteration layer of ~ 200-nm-thick, Ca-depleted and Nd-rich, was formed at the surface of CAB glasses with 20 mol% Nd2O3 whereas boehmite [AlO(OH)] secondary crystalline phases were formed in pure CAB glass that contained no Nd2O3.
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Introduction
Pyrochemical reprocessing technologies have been developed to recycle radioactive uranium and trans-uranium elements from spent nuclear fuels1,2. During these recycling processes, new families of radioactive wastes are generated. For instance, rare-earth (RE) metals in the LiCl-KCl eutectic salts3,4,5 are converted to oxides (REOs) during the oxidation process designed to recycle the chloride salts. These wastes consist of eight rare-earth oxides: 39.22 Nd2O3; 22.69 CeO2;11.72 La2O3; 10.86 PrO2; 8.13 Sm2O3; 4.80 Y2O3; 1.30 Eu2O3; 1.28 Gd2O3 (mol%). One of the glasses designed for the immobilization of REO-containing wastes is lanthanide alumino borosilicate (LABS) glass6. It can accommodate up to 55 wt% of combined fission product (alkali + alkaline earth + lanthanide) with good chemical durabilities. However, this glass has high crystallization tendency when more than 35 wt% of REO was added. REO wastes generated from the pyrochemical processing contain highly concentrated REOs and therefore, it is necessary to develop a new family of glasses with high REO solubilities.
The key factors to be considered when developing new wasteforms are waste loading, processability and chemical durability. Waste loading represents the amount of waste that can be incorporated in a wasteform and processability determines the feasibility of large scale and economical fabrication; relevant parameters are melting temperature TM, viscosity, electrical conductivity and crystallization tendencies of the melts. Several wasteforms have been reported for REO immobilization; each has advantages and disadvantages7,8,9,10,11. For example, ceramic wasteforms synthesized using solid-state sintering have low leaching rate of ~10−5 g·m−2d−1 for RE, but can only achieve REO loading of ~20 wt% by using a relatively complex synthesis processes11.
Borate glasses are well-known for their low TM, high REO solubility and moderate chemical durability, particularly for calcium aluminoborate (CAB) glasses though borate glasses are generally less durable than silicate glasses11,12,13. The dissolution mechanisms of borate glass systems are poorly understood because they have not been studied as extensively as in borosilicate glasses. In binary alkali borate glasses, only congruent dissolution has been reported; this observation suggests that network modifiers and waste constituents are leached at the same rate as the borate network12. Less-soluble REs are retained in the alteration layer of borosilicate glasses13, but the formation of alteration layers during dissolution of borate glasses has not been reported. Therefore, addition of REO can be expected to improve the weak chemical durability of normal alkali borate glasses while keeping their TM < 1300 °C. It is also anticipated that insoluble RE-O bonds can lead to the formation of the alteration layer on the surface of the glass that may result in an increase in its chemical durability.
In this study, we investigate the applicability of using calcium-aluminoborate (CAB) glasses for immobilization of REO wastes produced by pyrochemical reprocessing. We present our findings related to processability, waste loading, and in particular, durability, by using high-resolution techniques to observe the glass dissolution mechanisms of borate glasses.
Methods
Sample preparation
The nominal compositions (mol %) of the calcium aluminoborate (CAB) specimens prepared were (1 − x/100)(25.00CaO 18.75Al2O3 56.25 B2O3) + xNd2O3 (x = 0, 10, 20, 30); they were prepared as batched compositions (Table 1). We used Nd2O3 as a representative of all REOs to simplify the glass compositions that appears reasonable since most REOs have similar physical and chemical characteristics14. The glasses are coded by Nd2O3 content as CABx (x = 0, 10, 20, 30). Starting powders were weighed, mixed in a rotary miller for 3 h, then melted in an alumina crucible at 1300 °C for 30 min at ambient atmosphere. The melt was quenched by pouring it onto a brass mold in air, then annealed at 370 °C for 2 h. The resulting glasses digested in a 4:4:1 HF-HNO3-HClO4 solution, then their compositions were measured using ICP-AES (PERKIN-ELMER, OPTIMA 8300)15. To evaluate the suitability of the glasses for use in the cold crucible induction melter (CCIM) process, a rotary viscometer (Ravenfield Designs Ltd, FG MkIV) was used to measure the glass viscosity η [mPa·s] at 1300 and 1350 °C at a rotating speed of 100 rpm as
where τ [10−7N·m] = torque, Ω [rad·s−1] = rotating speed, R1 [cm] = radius of inner spindle, R2 [cm] = radius of crucible and h [cm] = height of spindle immersed in the mold flux. The electrical conductivity of CAB20 glasses was determined by measuring the resistance at three different points of the glasses at temperatures of 1100 ~ 1300 °C with 1-kHz alternating current. The electrical conductivity was calculated by substituting the constants obtained from linear fits of these three resistances.
Chemical Durability Analysis
The chemical durability of the glass products was assessed according to ASTM C-1220, Product Consistency Test-B (PCT-B)16. CAB0, CAB10, and CAB20 glasses were ground and sieved to powder with 75–150 μm in size. 1.5 g of each powder were immersed in 15 mL of de-ionized (DI) water in Teflon bottles and placed in an oven at 90 °C for 7 d. The surface areas of the powders were calculated on the assumption that the particles are spherical with a Gaussian size distribution17,18,19 (SA/V = ~2000 m−1). Concentrations of elements leached into the solution were analyzed using ICP-AES three times; the average values were used. All the tests were duplicated. The normalized elemental mass release NL i [g·m−2] of element i was calculated as
where c i [ppm, mg·L−1 or g·m−3] is the concentration of element i in solution, f i (unitless) is the mass fraction of element i in the glass, and SA/V [m−1] is the sample’s surface-area-to-volume ratio.
In addition to dissolution tests at high SA/V, monolith samples of CAB0 and CAB20 were prepared for dissolution and subsequent analysis of the altered glass surface20,21. The samples had dimensions of 70 mm × 70 mm × 2 mm and were polished to a 1-μm finish by using diamond suspension. Monolithic specimens with SA/V = 10 m−1 were immersed in DI water at 90 °C for 2, 7 or 20 d. Concentrations of elements leached into the solution were analyzed to calculate the normalized release NL i [g·m−2] of element i following the same method used for the PCT analysis.
The surface morphology and elemental distribution in leached CAB0 and CAB20 monoliths were analyzed using the electron energy loss spectra (EELS) in a high-resolution transmission electron microscope (HR-TEM, JEM-2200FS, JEOL, Japan). The specimens for EELS analysis were prepared using the focused ion-beam (FIB, FEI, Helios, Pegasus) milling technique, which was manipulated to observe the plane perpendicular to the leached surface. Carbon and platinum coating were applied to the dissolved surface to reduce the charge accumulation and increase the electrical conductivity of the specimens. Elemental depth profiling from the altered surface into the bulk of a specimen of CAB20 was performed using a time-of-flight/secondary-ion mass spectroscope (TOF-SIMS, ION-TOF GmbH, TOF-SIMS5) in negative mode with a 2-keV Cs + beam. X-ray diffraction (XRD, RIGAKU, D/MAX-2500) patterns were recorded to identify the crystals formed upon dissolution. Cu-Kα (λ = 1.54059 nm) radiation was used at a voltage of 40 kV and a current of 100 mA.
Results and Discussion
Evaluation of waste loading and processability of calcium aluminoborate glasses
As-prepared glasses containing up to 20 mol% Nd2O3 (CAB0, CAB10, and CAB20) were homogeneous and transparent. As Nd2O3 concentration increased. the glasses developed a deep purple color due to Nd3+ (Fig. 1). It is known that all RE ions have similar chemical and physical properties since they have similar ionic radii with partially occupied 4f levels14. In addition, they all normally act as network-modifiers inside the glass structure and therefore, there will be no serious discrepancy if we use Nd2O3 as a representative of all REO. Analysis of the glass samples and comparison with the as-batched concentrations (Tables 1–2) showed negligible volatilization of components during the melting processes. The alumina concentration was somewhat higher than the as-batched composition; this difference is attributed to contamination from the alumina crucible. We fabricated CAB glasses containing up to 22 mol% (56.8 wt%) Nd2O3, without crystallization, but the melt that contained 30 mol% devitrified during cooling when melted at 1300 °C for 30 min in ambient atmosphere. The maximum REO waste loading in the glasses is higher than in alkali borosilicate glass or ceramics, which is typically 20 wt% REOs8,9,10,11.
Low TM is essential, especially for glasses with high REO concentration, because REO addition generally raises the characteristic temperatures22. All glasses prepared in this study were melted at T ~1300 °C under ambient atmosphere. The temperature and waste loading achieved in this study are anticipated to be acceptable for use in a conventional glass melter. To meet the requirements of vitrification in a CCIM, the viscosity of the melt should be 1 ≤ η ≤ 10 Pa·s. Sample CAB20 had η = 7.817 Pa·s at 1300 °C and 5.170 Pa·s at 1350 °C; both meet these requirements, despite concerns that addition of REO increases the viscosity of melt. CCIM requires electrical conductivity of 0.1 ≤ G ≤ 1 Ω−1·cm−1; at 1300 °C, sample CAB20 had G = 0.4603 Ω−1·cm−1, which is also suitable. Average Vickers hardness of CAB20 glasses is 5.72 GPa that is comparable to values of sodium alumino-borate glasses (5.1–5.3 GPa)23 and monazite-type ceramic (5.0 GPa)11. Glass transition temperature of CAB20 glass is ~680 °C.
Table 3 compares the important characteristics of various wasteforms developed for REO immobilization. Waste loading of CAB is the highest among all wasteforms. In addition, CAB glasses can be prepared by the conventional cold crucible induction melting(CCIM) technique since they possess suitable melting points, viscosities and electrical conductivities. Values of the elemental mass release of RE are low in all wasteforms including CAB glasses investigated in this study.
Dissolution characteristics
A standard product consistency test (PCT) was performed to evaluate the chemical durability of CAB glasses (Table 4). The normalized mass loss NL i [g·m−2] of all elements in all specimens (0.06 ≤ NL B ≤ 0.67, 0.07 ≤ NL Ca ≤ 0.47 and NL Al < 0.02) was below the EA standard glass limit (6.68 g/m2) for HLW borosilicate glasses and the US criteria of <2 g·m−2 for Hanford LAW glasses24. Concentrations of Nd in solution from CAB20 glass were below the detection limit of ICP-AES (<0.1 ppm) that corresponds to NL Nd ~10−5 g·m−2. This value is comparable to that of competitive REO-containing borosilicate glasses (Table 4)7,8,25. The normalized elemental release of boron from CAB20 (NL B = 0.067 g·m−2) was significant smaller than that from alkali-borosilicate glass containing REO (36–46 g·m−2)8. Even though borate glass is generally known to be less durable than silicate glass26, the addition of REO was shown to improve its durability. For example, addition of 0 to 20 mol% Nd2O3 resulted in ~10% decrease in the normalized release of B and Ca (Table 4). These results concur with previous results in which addition of 12 mol% REO into borosilicate glass decreased the dissolved silicon concentration from 120 g·m−3 to 20 g·m−3 27. The same trends were observed for monolith samples subject to MCC-1 experiments; the normalized releases of all elements from monolith samples were significantly lower in CAB20 than CAB0. Values were NL B = 0.19 g·m−2, NL Ca = 0.83 g·m−2, and NL Al = 0.16 g·m−2 in CAB20, compared with NL B = 25.91 g·m−2, NL ca = 20.25 g·m−2 and NL Al = 1.57 g·m−2 for in CAB0 (Table 5).
To determine the mechanism of dissolution in calcium aluminoborate glass samples, we used TEM/EELS to investigate the morphology and elemental distribution at the surface of samples with (CAB20) and without (CAB0) addition of REO. TEM was used to obtain micrographs of a surface of CAB0 in cross-section before (Fig. 2a) and after dissolution for 20 d (Fig. 2b). On the surface of CAB0, boehmite crystals [AlO(OH)], aluminium oxide hydroxide, PDF 83–2384) of dentritic shape with ~2 μm in length formed after dissolution for 7 d (Fig. 3). B and Ca (and probably Al) seem to have dissolved congruently, and boehmite crystals precipitated onto the glass surface by reacting with water. Such secondary precipitation behaviour has previously been observed for other alkali borate glasses containing Al28.
In contrast, samples of calcium aluminoborate glasses with added Nd did not show boehmite precipitates in TEM micrographs of CAB20 either before (Fig. 2c) or after dissolution for 20 d (Fig. 2d) After dissolution for 2, 7 and 20 d, an alteration layer of thickness ~150 to 250 nm thick formed. To our knowledge, this is the first report of the formation of an alteration layer in a borate glass system. As observed in our normalized leaching data, the dissolution of CAB glasses was congruent; therefore the formation of an alteration layer in these glasses was somewhat unexpected. The addition of Nd, therefore, must play an important role in formation of the alteration layer in CAB glasses. One can speculate that the congruent dissolution of elements from the glass did not occur when a certain amount of Nd2O3 was added. Instead, an alteration layer was formed, that is similar to those normally observed in silicate glasses.
Results of the EELS elemental mapping of CAB20 glass (Fig. 4) show that of the five elements, concentrations of hydrogen and calcium in the alteration layer are worth mentioning. Hydrogen ions penetrated the alteration layer as either water, hydronium ion (H3O+) or H+; Ca ions were depleted in the same region. This observation can be explained by the ion-exchange process:
where \(\varnothing \) and 0 represent the bridging and non-bridging oxygen in the glass network, respectively. Behavior expressed by equation (3) is similar to that of borosilicate glasses during dissolution; exchange of hydrogen and alkali ions (particularly Na) is the accepted mechanism during the initial stage of dissolution behavior. Similar elemental distribution was observed in TOF-SIMS analysis of the samples (Fig. 5). H ions penetrated the sample surface to a depth of up to 124 nm, at which point the signal from Ca content began to decrease.
EELS and TOF-SIMS results both show that Nd, Al and B are retained in the alteration layer, albeit at lower concentrations than in the bulk glass. For Nd and Al, these results are acceptable because these elements are relatively insoluble in water and typically remain in the alteration layer that forms when borosilicate glasses dissolve27. The low concentration of Nd released to solution (Tables 4–5) supports this conclusion. Dissolution behavior of B is rather anomalous. The observation that B is retained in the alteration layer is in contrast to previous studies of borosilicate glasses that show B has a tendency to dissolve rapidly into solution during the early stage of leaching; this behavior is similar to that of alkali elements29.
The effect of REO addition on dissolution characteristics of CAB glasses can be summarized as follows. When CAB0 glass with no Nd2O3 was subject to dissolution in water at 90 °C, all constituent elements such as B, Ca and Al dissolved congruently, and boehmite crystals concurrently precipitated on the surface of CAB0. The formation of boehmite consumed Al ion from solution and further increased the dissolution rate30. When CAB20 glass was subjected to dissolution under the same conditions, ions such as Ca with a high reactivity to water started to dissolve from the glass surface. In the rare-earth metaborate glass: RE3+ ions act both as charge compensators of (BO4)− units and as modifiers that form NBOs in the borate network31. Then, high field strength of RE3+ compared to other mono- or divalent cations induces strong bonding between RE3+ and neighboring O. La-O has higher bond strength (244 kJ·mol−1) than Sr-O (134 kJ·mol−1)22,31. We believe that strong networks of B-O-RE form when Nd2O3 is added. This reinforced network compared to connections with alkali elements would retard the dissolution rate of some elements, and thereby increase the differences in elemental dissolution rate by hydrolysis of network-components compared to that by alkali leaching; these schemes can be considered to resemble incongruent dissolution. This rate difference could lead to formation of an alteration layer, and thereby further decrease the dissolution rate.
Conclusion
Calcium aluminoborate glasses containing ~20 mol% of Nd2O3 (CAB20: 20 CaO − 15 Al2O3 − 45 B2O3 − 20 Nd2O3) were developed to immobilize rare-earth oxide (REO) wastes. The maximum solubility of REOs in glasses was ~22 mol% (56.8 wt%) when the batch was melted at 1300 °C for 30 min. The melt of CAB20 had viscosity of ~ 7.817 Pa·s and electrical conductivity of 0.4603 Ω−1·cm−1 at 1300 °C, suitable for CCIM application. The normalized released amount after PCT tests were <0.1 g·m−2 for Ca2+, Al3+ and B3+ and below the limit of detection of ICP-AES (<0.1 ppm) for Nd3+. Boehmite [AlO(OH)] secondary phase formed on the surface after 20 d dissolution in water when no Nd2O3 was added. In contrast, a ~200-nm-thick hydrated alteration layer, deficient in Ca2+ and enriched in B3+ and Nd3+ formed when 20 mol% of Nd2O3 was added.
Data availability statement
The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.
References
Williamson, M. A. & Willit, J. L. Pyroprocessing Flowsheets for Recycling Used Nuclear Fuel. Nucl. Eng. Technol. 43, 329–334 (2011).
Lee, H. S. et al. Pyroprocessing Technology Development at Kaeri. Nucl. Eng. Technol. 43, 317–328 (2011).
Cho, Y. Z. et al. Eutectic (LiCl-KCl) waste salt treatment by sequencial separation process. Nucl. Eng. Technol. 45, 675–682 (2013).
Cho, Y. Z. et al. Minimization of Eutectic Salt Waste from Pyroprocessing by Oxidative Precipitation of Lanthanides. J Nucl Sci Technol 46, 1004–1011 (2009).
Cho, Y. Z., Kim, I. T., Yang, H. C., Park, H. S. & Lee, H. S. Separation of Lanthanide Fission Products in a Eutectic Waste Salts Delivered from Pyroprocessing of a Spent Oxide Fuel by Using Lab-Scale Oxidative Precipitation Apparatus. Proceedings of the 12th International Conference on Environmental Remediation and Radioactive Waste Management 2009 1, 299–302 (2010).
Crum, J. V. et al. Baseline Glass Development for Combined Fission Products Waste Streams. (Pacific Northwest National Laboratory (PNNL), Richland, WA (US), 2009).
Choi, J. H. et al. Fabrication and physical properties of lanthanide oxide glass wasteform for the immobilization of lanthanide oxide wastes generated from pyrochemical process. J. Radioanal. Nucl. Chem. 299, 1731–1738 (2013).
Kim, C. W. & Lee, B. G. Feasibility Study on Vitrification for Rare Earth Wastes of PyroGreenProcess. J. Korean Radioact. Waste Soc. 11, 1–9 (2013).
Kim, M. & Heo, J. Vitusite glass-ceramics wasteforms for immobilization of lanthanide wastes generated by pyro-processing. Ceram Int 41, 6132–6136 (2015).
Kim, M. & Heo, J. Calcium-borosilicate glass-ceramics wasteforms to immobilize rare-earth oxide wastes from pyro-processing. J. Nucl. Mater. 467, 224–228 (2015).
Ahn, B., Park, H., Kim, I., Choand, Y. & Lee, H. Immobilizationof Lanthanide Oxides Waste from Pyrochemical Process. Energy Procedia 7, 529–533 (2011).
Velez, M., Tuller, H. L. & Uhlmann, D. R. Chemical durability of lithium borate glasses. J. Non-Cryst. Solids 49, 351–362 (1982).
Leturcq, G., Berger, G., Advocat, T. & Vernaz, E. Initial and long-term dissolution rates of aluminosilicate glasses enriched with Ti, Zr and Nd. Chem Geol 160, 39–62 (1999).
Rokhlin, L. L. Magnesium alloys containing rare earth metals: structure and properties. (Crc Press, 2003).
Sun, Yc, Chi, Ph & Shiue, My Comparison of different digestion methods for total decomposition of siliceous and organic environmental samples. Anal. Sci. 17, 1395–1399 (2001).
Jantzen, C. M. & Bibler, N. Nuclear waste glass Product Consistency Test (PCT), Version 3. 0. (Westinghouse Savannah River Co., Aiken, SC (USA), 1990).
Standard Test Methods for Determining Chemical Durability of Nuclear, Hazardous, and Mixed Waste Glasses and Multiphase Glass Ceramics: The Product Consistency Test (PCT). (ASTM International, West Conshohocken, PA., 2002).
Icenhower, J. P. & Steefel, C. I. Dissolution rate of borosilicate glass SON68: A method of quantification based upon interferometry and implications for experimental and natural weathering rates of glass. Geochim. Cosmochim. Acta 157, 147–163 (2015).
Fournier, M. et al. Glass dissolution rate measurement and calculation revisited. J. Nucl. Mater. 476, 140–154 (2016).
Kim, C. W., Park, J. K. & Hwang, T. W. Analysis of leaching behavior of simulated LILW glasses by using the MCC-1 test method. J Nucl Sci Technol 48, 1108–1114 (2011).
Strachan, D., Turcotte, R. & Barnes, B. MCC-1: A standard leach test for nuclear waste forms. Nucl. Technol. 56, 306–309 (1982).
Smiljanić, S. V. et al. Effect of La2O3 on the structure and the properties of strontium borate glasses. Chem. Ind. Chem. Eng. Q. 22, 111–115 (2016).
Ghoneim, N. A., El Batal, H. A. & Nassar, M. A. A. Microhardness and softening point of some alumino-borate glasses as flow dependent properties. Journal of Non-Crystalline Solids 55, 343–351 (1983).
Schumacher, R. et al. In Environmental Issues and Waste Management Technologies in the Ceramic and Nuclear Industries VIII: Proceedings of the symposium held at the 104th Annual Meeting of The American Ceramic Society, April 28-May1, 2002 in Missouri, Ceramic Transactions. 209 (John Wiley & Sons) (2002).
Fadzil, S. M., Hrma, P., Schweiger, M. J. & Riley, B. J. Liquidus temperature and chemical durability of selected glasses to immobilize rare earth oxides waste. J. Nucl. Mater. 465, 657–663 (2015).
Huang, W., Day, D. E., Kittiratanapiboon, K. & Rahaman, M. N. Kinetics and mechanisms of the conversion of silicate (45S5), borate, and borosilicate glasses to hydroxyapatite in dilute phosphate solutions. J. Mater. Sci. Mater. Med. 17, 583–596 (2006).
Molieres, E. et al. Chemical Durability of Lanthanum-Enriched Borosilicate Glass. Int J Appl Glass Sci 4, 383–394 (2013).
Wang-hong, A. Y. & Kirkpatrick, R. J. Hydrothermal reaction of albite and a sodium aluminosilicate glass: A solid-state NMR study. Geochim. Cosmochim. Acta 53, 805–819 (1989).
Gin, S. & Mestre, J. SON 68 nuclear glass alteration kinetics between pH 7 and pH 11.5. J. Nucl. Mater. 295, 83–96 (2001).
Ebert, W. & Mazer, J. Laboratory testing of waste glass aqueous corrosion; Effects of experimental parameters. Mater Res Soc Symp Proc 333 (1993).
Pytalev, D. et al. Structure and crystallization behavior of La2O3·3B2O3 metaborate glasses doped with Nd3+ or Eu3+ ions. J. Alloys Compd. 641, 43–55 (2015).
Acknowledgements
This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP:Ministry of Science, ICT and Future Planning) (No. NRF-2015M2A7A1000191 & NRF-2017R1A2B4006754). NCH is grateful to the NDA and Royal Academy of Engineering for financial support and EPSRC under grants EP/M026566/1, EP/L018616/1 and EP/L014041/1. CLC is grateful to EPSRC for the award of an ECR Fellowship (EP/N017374/1).
Author information
Authors and Affiliations
Contributions
M.K. and J.H. conceived the experiments, M.K. conducted the experiments and wrote the manuscript, M.K., C.C., N.H. and J.H. analyzed the results. All authors reviewed the manuscript.
Corresponding author
Ethics declarations
Competing Interests
The authors declare no competing interests.
Additional information
Publisher's note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
About this article
Cite this article
Kim, M., Corkhill, C.L., Hyatt, N.C. et al. Development, characterization and dissolution behavior of calcium-aluminoborate glass wasteforms to immobilize rare-earth oxides. Sci Rep 8, 5320 (2018). https://doi.org/10.1038/s41598-018-23665-z
Received:
Accepted:
Published:
DOI: https://doi.org/10.1038/s41598-018-23665-z
- Springer Nature Limited
This article is cited by
-
Structure, mechanical, and chemical performance evolution of aluminosilicate glass modified by Nd2O3
Journal of the Australian Ceramic Society (2024)
-
The effects of ultrasonic cavitation on the dissolution of lithium disilicate glass
Scientific Reports (2022)