Abstract
In chemical enhanced oil recovery (cEOR) techniques, surfactants are extensively used for enhancing oil recovery by reducing interfacial tension and/or modifying wettability. However, the effectiveness and economic feasibility of the cEOR process are compromised due to the adsorption of surfactants on rock surfaces. Therefore, surfactant adsorption must be reduced to make the cEOR process efficient and economical. Herein, the synergic application of low salinity water and a cationic gemini surfactant was investigated in a carbonate rock. Firstly, the interfacial tension (IFT) of the oil-brine interface with surfactant at various temperatures was measured. Subsequently, the rock wettability was determined under high-pressure and high-temperature conditions. Finally, the study examined the impact of low salinity water on the adsorption of the cationic gemini surfactant, both statically and dynamically. The results showed that the low salinity water condition does not cause a significant impact on the IFT reduction and wettability alteration as compared to the high salinity water conditions. However, the low salinity water condition reduced the surfactant’s static adsorption on the carbonate core by four folds as compared to seawater. The core flood results showed a significantly lower amount of dynamic adsorption (0.11 mg/g-rock) using low salinity water conditions. Employing such a method aids industrialists and researchers in developing a cost-effective and efficient cEOR process.
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The demand for oil and gas continues to soar higher due to the ever-increasing global demand for energy1,2. Carbonate reservoirs hold 60% of the global oil reserves3. Despite the huge resource potential of these reservoirs, they are characterized by several complexities such as fractures, heterogeneities, and low permeabilities, which limit production4,5. Moreover, carbonate reservoirs are typically characterized by high temperature and high salinity conditions. Due to these and other factors, oil recovery from such reservoirs after primary production and waterflooding is low6. To recover additional oil, several enhanced oil recovery (EOR) schemes have been developed7,8,9,10.
Surfactant flooding—a chemical EOR (cEOR) technique has been investigated for its oil recovery efficiency from carbonate rocks11,12,13,14,15,16. Surfactants’ amphiphilic nature makes them capable of modifying the wettability of reservoir rock and lowering oil–water interfacial tension (IFT), which are desirable for oil production17,18. Several studies have highlighted the ability of surfactants to improve pore-scale displacement efficiency19,20,21. Nonetheless, surfactants show limited efficiency under harsh reservoir conditions, especially in the case of carbonate reservoirs. High concentrations of divalent ions in the reservoir system cause surfactant precipitation22,23,24. Moreover, partitioning and high retention of surfactants are exacerbated under high salinity conditions, which reduces surfactant efficiency and may render the process uneconomical25,26,27.
Recently, low-salinity waterflooding (LSWF) has been coveted for EOR due to its efficiency28,29,30,31. The process involves injecting brine of low salinity compared to the formation water. This method is appealing due to its ease of implementation, low cost, and relative simplicity32. The major mechanism proposed for oil recovery via the process is the wettability alteration of the reservoir rock system33. Other mechanisms postulated include mineral dissolution, formation of the microemulsion, fines migration, pH increase, and multi-ion exchange34. However, the application of the process does not significantly influence the fluid–fluid interaction within the rock.
The effectiveness of low salinity water (LSW) and a natural surfactant for EOR in carbonate core plugs was studied35. The authors reported IFT reduction (1.02 mN/m) and wettability alteration (31.25°). Besides, the combination of LSW and surfactant resulted in a 12.5% incremental oil recovery over LSWF. Ahmadi et al. evaluated the effects of controlled brine salinity (smart water) on the efficiency of anionic and cationic surfactants for chemical EOR in carbonates36. Tests on carbonate cores via spontaneous imbibition at high temperatures indicated that the combination of smart water and 1000 ppm sodium dodecyl sulfate (SDS) recorded 64.5% oil recovery while the combination of smart water with cetyltrimethylammoniumbromide (CTAB) achieved 72% oil recovery. Similarly, Souayeh et al.37 noted that the combination of carboxylate surfactant with polyethoxylated nonionic surfactant and LSW yielded 74% of the original oil in place (OOIP) from oil-wet limestone cores. Moradi et al. observed that the synergic application of smart water and surfactant yielded 72% OOIP38. Undoubtedly, the potential of LSW and surfactant offers a higher oil recovery than EOR method individually.
More recently, cationic gemini surfactants have been courted and investigated for chemical EOR39. This unique type of surfactant is characterized by two head groups linked with a spacer40. As compared to conventional surfactants, the presence of the spacer enhances the hydrophobicity and functionality of the surfactant13,41. This surfactant demonstrates sterling and fascinating properties such as low critical micelle concentration (CMC), high salt and temperature tolerance, good viscoelastic property, the ability to lower IFT and alter the wettability of rock surface41. The low CMC of the surfactant implies a low quantity of the surfactant is required to achieve the desired efficiency. However, surfactant loss may occur due to adsorption and phase trapping during the surfactant flooding process.
Surfactant adsorption poses a significant challenge during surfactant flooding and can have a decisive impact on the success of the enhanced oil recovery (EOR) process. The main mechanism behind the surfactants’ adsorption on the surface of the rocks is the electrostatic attraction between the surfactant molecules and the rock surface, which carries an opposite charge42,43. Surfactant adsorption results in the depletion of surfactant molecules from the aqueous solution, leading to a decrease in surfactant concentration. Hence, the economic viability and effectiveness of surfactant flooding depend greatly on the surfactant's adsorption. Therefore, anionic surfactants are considered favorable for sandstone reservoirs because of their lower tendency for adsorption on such rocks. In contrast, cationic surfactants are chosen for carbonate rocks as they exhibit reduced adsorption tendencies on these types of formations. Nevertheless, even with the selection of a specific surfactant based on the rock type, the presence of impurities such as clay and silicate minerals can lead to surfactant adsorption44,45. Several studies are talking about surfactant adsorption and its reduction46,47,48,49,50,51,52. The traditional practice is to use an alkali to reduce the adsorption of anionic surfactants on sandstone rocks43. Sodium polyacrylate has also been reported as a sacrificial agent to reduce the adsorption of anionic surfactant on sandstone rocks53. Another study shows the use of silica nanoparticles to reduce the adsorption of a natural anionic surfactant on different types of rock surfaces, including sandstone, carbonate, and bentonite54. There are some studies as well talking about the adsorption reduction of cationic surfactants on carbonate rocks. Ahmadali et al.55 revealed that calcium and magnesium cations have a significant inhibitory effect on the adsorption of cationic surfactants on carbonate rocks. A recent study demonstrated that the addition of methylene blue to the aqueous solution of a cationic surfactant resulted in a decrease in the surfactant adsorption on carbonate rocks52. Another approach is to use an acidic medium. Such as the use of CO2 to acidify the surfactant solution, increasing the positive charge of the carbonate surface45. Consequently, the adsorption of cationic surfactant was decreased because of the electrostatic repulsion45. A most recent study found that adding formic acid to the aqueous solution of surfactant significantly reduces surfactant adsorption on carbonate rocks51.
Most studies talk about conventional monomeric surfactants and the use of alkalis, nanoparticles, or polymers to reduce surfactant adsorption43. Herein, the synergistic combination of LSW and a novel, in-house-synthesized, cationic, gemini surfactant was studied to investigate the surfactant adsorption on carbonate rocks. The surfactant used in this study is an in-house developed dicationic amphiphile and it was designed in a way to address the challenges associated with the chemical EOR. For example, the ethoxy groups were introduced between the lipophobic ammonium head and lipophilic alky tail, and due to these ethoxy groups, the surfactant was found to be soluble in low to high-salinity brine. In addition, the insertion of amide group [–NH–(C(O)–] in the chemical structure displayed several advantages such as low toxicity, low CMC, good biodegradability, and intermolecular hydrogen bonding which leads to the high thermal stability of the molecule. It is well known that the spacer group in gemini surfactant plays a significant role and increasing the length of the spacer group leads to improved interfacial and thermal properties. Therefore, we selected a large spacer group (12 carbon) to obtain better physicochemical properties. Moreover, the developed surfactant is cationic, and the carbonate rocks contain a positive charge and due to charge repulsion, the surfactant adsorption can be minimized. The underlying mechanisms of the EOR method were also examined using this surfactant: 1. The IFT of the oil/brine system and 2. The wettability of the rock-fluid interface. To the best of our knowledge, such comprehensive investigations were never reported before. The research objectives have been accomplished by implementing a systematic approach. Firstly, X-ray diffraction (XRD) and X-ray fluorescence (XRF) techniques were utilized to conduct mineralogical and elemental analyses on rock samples, respectively. After that, IFT and wettability measurements were conducted under different levels of salinity. Static and dynamic adsorption tests were performed under different conditions. Dynamic adsorption tests were carried out using an oil-free core flood setup. For the determination of surfactant concentration, the effluents underwent analysis using high-performance liquid chromatography (HPLC).
Experimental work
Materials
Brine
Synthetic seawater and formation brine were prepared by dissolving several salts in the deionized water. The low salinity water was made by mixing synthetic seawater with deionized water at a ten-fold dilution. Constituents of the three aqueous phases are shown in Table 1.
Crude oil
The properties of crude oil used in this study are listed in Table 2.
Gemini surfactant
The cationic gemini surfactant employed in this study was synthesized in-house using the route depicted in Fig. 157. The chemical structure was confirmed using FTIR and NMR characterization techniques. The compound is a quaternary ammonium gemini surfactant with bromide as the counterions. Given that the hydrophobic tail and spacer length are both C12, it is a 12-12-12 gemini surfactant. 12-12-12 is also abbreviated as GS12 in this manuscript. The surfactant demonstrates outstanding stability under high salinity and temperature conditions57. More details on the synthesis and characterization of the surfactant have been discussed in our previous studies58,59.
Rock characterization
Indiana limestone core samples with an average permeability of 10 mD and porosity of 13% were used in this study. Table 3 presents the results obtained from X-ray fluorescence (XRF), while Fig. 2 displays the findings from X-ray diffraction (XRD). XRF shows a higher content of calcium and a lower content of silicon, while XRD depicts a high content of calcite and low content of silicate minerals, indicative of carbonate rocks.
IFT measurement
The oil-brine IFT was determined using the pendant drop method in a Kruss Scientific drop shape analyzer. Prior to measurement, bulk fluid was injected into the measuring chamber. The equipment is equipped with a needle (size = 1.57 mm) used to calibrate the measurement. Afterwards, the oil was suspended from the tip of the needle into the bulk fluid. The IFT between the crude oil and LSW, low salinity surfactant solution (LSS), or surfactant in seawater solution (SSW) was measured at three temperatures (25, 50, and 80 °C). The surfactant concentration in LSS and SSW was 1500 ppm.
Wettability alteration
With Indiana limestone as substrate, the rock-fluid interactions of the various additives were evaluated via contact angle measurement. Each core sample had a diameter of 38 mm and was trimmed to a thickness of 4 mm. Subsequently, the trimmed samples were polished and cleaned with toluene to remove impurities and then dried in an oven at 80 °C. The samples were then aged in the crude oil for 1 week to render the surface oil wet. The cores were treated with LSW as well as LSS and SSW at a surfactant concentration of 1,000 ppm. Afterward, oil with the same properties listed in Table 2 is used as a droplet on the substrate surface, and the contact angles were measured. Each measurement was repeated thrice, and the average value was reported. All experiments were conducted at 80 °C and 1500 psi pressure.
Static adsorption
To determine the amount of surfactant adsorbed onto a carbonate rock surface, static adsorption tests were performed. After crushing the rock sample into powder, the sample was mixed with the surfactant solution at a ratio of 1:15 and thoroughly shaken for 24 h at ambient conditions. The mixture was subjected to centrifugation at 3000 rpm for 20 min, following which the supernatant was collected and filtered. Subsequently, the unknown concentration of the surfactant was analyzed via high-performance liquid chromatography (HPLC). The sensor used with HPLC was an evaporative light scattering detector (ELSD). Static adsorption was found utilizing Eq. 1.
where \(\Gamma_{static}\) (mg/g-rock) denotes the static adsorption of the surfactant on the rock surface, \({C}_{0}\) (ppm) represents the pre-adsorption surfactant concentration, C (ppm) shows the post-adsorption surfactant concentration, \({V}_{s}\) (mL) denotes the surfactant solution volume, and \(m\) (g) is the mass of the powdered rock sample.
Dynamic adsorption
Two dynamic adsorption tests were performed on Indiana limestone samples in the core-flooding apparatus shown in Fig. 3. Both experiments were conducted under the following conditions: a confining pressure of 2500 psi, a back pressure of 1500 psi, and a liquid injection rate of 0.25 cc/min. The effluent of the core flood was analyzed with HPLC. Dynamic adsorption was calculated using Eq. 2.
where \(\Gamma_{dynamic}\) (mg/g-rock) is the surfactant’s dynamic adsorption, C0 (ppm) denotes the concentration of the injected surfactant, V (L) is the total volume of injected surfactant solution, Ci (ppm) represents the surfactant concentration, and Vi (L) corresponds to the volume of the effluent collected at different time intervals. The total mass of the dry core sample is denoted as m (g), and the total number of collected effluent samples is represented by N.
Results and discussion
IFT results
The oil-brine IFT measurements are presented in Fig. 4. With LSW alone, the IFT values were 26.67 \(\pm\) 0.53, 21.84 \(\pm\) 0.24, and 19.82 \(\pm\) 0.35 mN/m at 25, 50, and 80 °C, respectively. This shows the relatively small effect of LSW. This agrees with previous studies that had a similar conclusion60,61,62. On the other hand, the LSS solution caused the IFT to drop drastically at all temperatures reaching 1.48 \(\pm\) 0.0355 mN/m at 80 °C. The lowest IFT measured was with SSW, which reached 0.754 \(\pm\) 0.015 mN/m at 80 °C. The increased salinity pushes more surfactant molecules to the oil-brine interface leading to lower IFT. As compared to conventional surfactants that precipitate at high salinity conditions, the cationic gemini surfactant utilized in this work is tolerant to high-temperature high-salinity (HTHS) conditions, hence its stability. Additionally, it was observed that the IFT decreases as the temperature condition increases. This can be adduced to the temperature-dependent nature of the formation of rigid interfacial films at the interface. Increasing temperature induces higher mobility at the fluid–fluid interface and increases the entropy of the system. Resultantly, the Gibbs free energy reduces and a lower IFT value is recorded63.
Wettability results
The wettability of the rock samples aged in crude oil was assessed as depicted in Fig. 5. The average contact angle between oil and DI water (Fig. 5a) was about 138° indicating the oil wetness of the rock. With LSW (Fig. 5b), LSS (Fig. 5c), and SSW (Fig. 5d) the average contact angles were 94°, 60° and 65°, respectively. These results indicate that LSW has a significant impact on rock wettability, shifting it to neutral. The mechanism of carbonate wettability alteration by LSW, especially at high temperatures, has been adduced to multivalent ionic exchange and electrostatic interaction30,33. The results also show that the addition of surfactant further altered the rock surface to water wet both under high salinity and low salinity conditions. Wettability alteration results using LSS and SSW were found comparable.
Adsorption experiments
Static adsorption
The static adsorption of the cationic gemini surfactant on the rock is displayed in Table 4, showcasing the results obtained when the surfactant was dissolved in deionized water (DI), high salinity water (HSW), and low salinity water (LSW). A fixed surfactant concentration of 1500 ppm was used in this study because the adsorption plateau was found at around 1000 ppm surfactant concentration51. The highest adsorption was found in DI at 1.51 mg/g-rock50. The static adsorption was decreased to 0.72 mg/g-rock in HSW and was further reduced to 0.18 in LSW showing a ~ eightfold drop with reference to the base case of DI50. In the case of surfactant solution made in DI water, there is no salt present in the aqueous solution. Therefore, there exists a natural interaction between surfactant and the rock surface. The adsorption is high because of the strong electrostatic attraction between the cationic surfactant and the negative binding sites due to silica and clay impurities on the carbonate surface44,49. Adsorption of the cationic gemini surfactant was attributed to the formation of an interdigitated bilayer on the carbonate rock39,40. On the other hand, in the presence of seawater, there exist monovalent and divalent salts in high concentrations. Therefore, an attraction of divalent ions on the negative binding sites of the carbonate rock surface is expected, leading to a reduction in surfactant adsorption. Ahmadali et al.55 also investigated that calcium and magnesium cations have a substantial inhibitory impact on the adsorption of cationic surfactants on carbonates. However, in the case of using low-salinity water conditions, the surfactant adsorption was dramatically reduced. The surfactant adsorption reduction could be due to the expansion of the electric double layer at the solid–liquid interface.
Given that the adsorption of GS12 was highest in DI water, the surfactant dissolved in DI water was chosen as the reference for the dynamic adsorption experiment. Further details regarding this experiment will be discussed in the following section.
Dynamic adsorption
To study the impact of solution salinity on the dynamic adsorption of GS12 surfactant on Indiana limestone, two different core floods were conducted, one with DI water as solvent as a base case51, and the other with LSW. The characteristics of the two flooded core samples are shown in Table 5. In both floods, the core sample was initially fully saturated with the solvent phase, and around 20 PVs of the GS12 solution with a concentration of 1500 ppm was injected at 0.25 cc/min followed by about 5 PVs of the solvent phase.
Figures 6 and 7 show the effluent surfactant concentration and the computed dynamic adsorption profiles for both floods, respectively. The injection of GS12 continued for about 20 pore volumes, followed by low salinity waterflooding to capture the desorption of the surfactant as shown in Fig. 6. Dynamic adsorption of the surfactant made in DI water was 0.269 mg/g-rock on carbonate rock (Indiana Limestone) as shown in Fig. 751. Figure 7 shows that the adsorption of GS12 in LSW was 0.11 mg/g-rock, which is about 60% lower than in DI. In low salinity conditions, the electric double layer at the solid–liquid interface undergoes expansion64, which causes a decrease in surfactant adsorption. Nourani et al.65 also discovered that the surfactant adsorption was reduced using low salinity conditions. The considerable decrease in surfactant adsorption, amounting to around 60% (from 0.269 to 0.11 mg/g-rock), holds economic significance. One direct consequence is the potential for cost savings through a decreased consumption of gemini surfactant. The cost of manufacturing low-salinity water needs to be determined depending on the geographical location. The utilization of such an approach assists industrialists and researchers in the economical and efficient application of a cEOR process.
Conclusions
The fluid–fluid and fluid-rock interactions of low salinity water (LSW) with a cationic gemini surfactant (GS12) are summarized as follows.
-
1.
LSW has a small effect on the oil-brine IFT.
-
2.
LSW alters the wettability of oil-wet limestone to intermediate wetting conditions (138° to 94°).
-
3.
The introduction of GS12 surfactant to LSW leads to a substantial decrease in IFT to 1.48 ± 0.0355 mN/m at 80 °C. However, the lowest IFT measured was with SSW, which reached 0.754 ± 0.015 mN/m at 80 °C.
-
4.
LSS and SSW altered the wettability of the oil-wet limestone to the water-wet condition. The corresponding average contact angles were 60° and 65° using LSS and SSW, respectively.
-
5.
With LSS, the static adsorption of the surfactant on the limestone was lowered by about 75% compared with SSW.
-
6.
With LSS, the surfactant’s dynamic adsorption on the limestone was found very low (0.11 mg/g-rock), which illustrates that the use of the gemini surfactant along with LSW will reduce the surfactant adsorption dramatically, therefore, making the chemical EOR process economical and efficient.
-
7.
The synergic combination of LSW and GS12 surfactant shows good potential for recovery of oil in carbonate reservoirs based on good IFT reduction, good wettability alteration, and minimal dynamic adsorption properties.
Data availability
The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.
Abbreviations
- cEOR:
-
Chemical enhanced oil recovery
- CTAB:
-
Cetyltrimethylammoniumbromide
- CMC:
-
Critical micelle concentration
- DI:
-
Deionized water
- EOR:
-
Enhanced oil recovery
- ELSD:
-
Evaporative light scattering detector
- GS12:
-
Cationic gemini surfactant with spacer length of C12
- HSW:
-
High salinity water
- HPLC:
-
High-performance liquid chromatography
- HTHS:
-
High-temperature high-salinity
- IFT:
-
Interfacial tension
- LSWF:
-
Low-salinity waterflooding
- LSW:
-
Low salinity water
- LSS:
-
Low salinity surfactant solution
- OOIP:
-
Original oil in place
- PVs:
-
Pore volumes
- SSW:
-
Surfactant in seawater solution
- TDS:
-
Total dissolved solids
- XRD:
-
X-ray diffraction
- XRF:
-
X-ray fluorescence
- \(\Gamma_{static}\) :
-
Surfactant’s static adsorption (mg/g-rock)
- \(\Gamma_{dynamic}\) :
-
Surfactant’s dynamic adsorption (mg/g-rock)
- \({C}_{0}\) :
-
Pre-adsorption surfactant concentration, ppm
- C :
-
Post-adsorption surfactant concentration (ppm)
- Ci :
-
Surfactant concentration at time interval i (ppm)
- \(m\) :
-
Mass of the powdered rock sample (g)
- N :
-
Total number of collected effluent samples
- \({V}_{s}\) :
-
Surfactant solution volume in the static adsorption test (mL)
- V :
-
The total volume of injected surfactant solution in the dynamic adsorption test (L)
- Vi :
-
Volume of the effluent collected solution in the dynamic adsorption test at time interval i (L)
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Acknowledgements
This publication is based upon work supported by the KFUPM-KU Joint Research Program. The author(s) at KFUPM would like to acknowledge the support received under grant # KU201001. The author(s) at Khalifa University acknowledges the support received under award # KFUPM-KU-2020-14.
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S.K.: Performed experiments and wrote the manin manuscript text. S.A.A.-K.: Wrote the manuscript, and supervised the work. A.O.G., Performed partial experiments and contributed in the writeup. S.P.: Supervision and writeup. M.S.K.: Supervision, project managment and writeup. S.M.S.H.: Synthesized the surfactants and contributed to writeup. D.A.-S.: Contributed in the write-up and project management. E.A.S.: Experimental Methodology and supervision. K.K.M.: Experimental methodology and supervision. All authors reviewed the manuscript.
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Kalam, S., Abu-Khamsin, S.A., Gbadamosi, A.O. et al. Static and dynamic adsorption of a gemini surfactant on a carbonate rock in the presence of low salinity water. Sci Rep 13, 11936 (2023). https://doi.org/10.1038/s41598-023-38930-z
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DOI: https://doi.org/10.1038/s41598-023-38930-z
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