Abstract
A review of the lithostratigraphic units in the Río de la Plata Craton and of new and previously published geochronological, isotopic and geophysical data is presented. Sm–Nd TDM model ages between 2.6 and 2.2 Ga characterize the Piedra Alta Terrane of this craton. Crystallization ages between 2.2 and 2.1 Ga for the metamorphic protoliths and 2.1–2.0 Ga for the post-orogenic granitoids indicate juvenile crust, followed by a short period of crustal recycling. Cratonization of this terrane occurred during the late Paleoproterozoic. Younger overprinting is not observed, suggesting it had a thick and strong lithosphere in the Neoproterozoic. A similar scenario is indicated for the Tandilia Belt of Argentina. Sm–Nd TDM model ages for the Nico Pérez Terrane show two main events of crustal growth (3.0–2.6 and 2.3–1.6 Ga). The crystallization ages on zircon ranges between 3.1 and 0.57 Ga, which is evidence for long-lived crustal reworking. The age for cratonization is still uncertain. In the Taquarembó Block, which is considered the prolongation of the Nico Pérez Terrane in southern Brazil, a similar scenario can be observed. These differences together with contrasting geophysical signatures support the redefinition of the Río de la Plata Craton comprising only the Piedra Alta Terrane and the Tandilia Belt. The Sarandí del Yí Shear Zone is regarded as the eastern margin of this Craton.
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Introduction
Almeida et al. (1973) originally defined the Río de la Plata Craton (RPC) to include the “ancient cratonic areas” of the southernmost South American Platform, “already consolidated in the upper Precambrian”. Most of the RPC consists of juvenile Paleoproterozoic crust, but negative Nd isotopic signatures in Tandilia suggest part of the craton was mature continental crust (Cordani et al. 2000; Pankhurst et al. 2003; Peel and Preciozzi 2006; Rapela et al. 2007). Over large areas, Phanerozoic sediments cover the Craton. Rapela et al. (2007) presented U–Pb SHRIMP data for drill cores demonstrating the westward continuity of the RPC under the sedimentary cover, as far as the surroundings of the Pampean Ranges of Córdoba. The main outcrop areas of the RPC include (Fig. 1) the crystalline basement in the central to southwestern Uruguay (Dalla Salda et al. 1988), the Buenos Aires Complex of the Tandilia Belt in Argentina (Cingolani et al. 2002) and the Taquarembó block of Brazil (Hartmann 1998, Hartmann et al. 1999). A tectonostratigraphic terrane approach (Bossi and Campal 1992; Bossi et al. 1993b) takes the Sarandí del Yí Shear Zone as basis for defining two different terranes in the Río de la Plata Craton, namely the Piedra Alta Terrane in the west and the Nico Pérez Terrane in the east. Only in the latter, remnants of Archean crust have been recognized (Hartmann et al. 2001). The Río de la Plata Craton is a key piece in the assembly of western Gondwana. The collision with the São Francisco/Congo and the Kalahari Cratons on its eastern margin is related to the evolution of the Dom Feliciano, Kaoko and Gariep Belts, while the collision against the Pampia Terrane on the western margin resulted in the Eastern Sierras Pampeanas. This paper reviews the recent progress in the knowledge of the craton and presents new geochronological, geochemical, Sm–Nd and Pb isotope data. Utilizing this data, a new definition of the craton can be made.
Geological overview of the Río de la Plata Craton
The Buenos Aires Complex of the Tandilia Belt (Argentina)
The knowledge of the basement of Tandilia, called Buenos Aires Complex after Marchese and Di Paola (1975), has been summarized recently by Dalla Salda et al. (2006). This basement comprises granitic to tonalitic gneisses, migmatites and amphibolites. U–Pb SHRIMP ages on zircon of these gneisses yielded ages between ~2.2 and ~2.1 Ga (see Table 1). Supracrustal rocks associated with the orthogneisses include micaschists and dolomitic marbles. Delpino and Dristas (2008) estimated the peak metamorphic conditions for the marbles from Punta Tota (NE Tandilia Belt) at 750–800°C and 5–6 kb and metamorphic conditions that followed a counterclockwise P–T trajectory suggesting extension and thinning of the crust in an intraplate setting or a marginal back-arc basin.
Granitic intrusions comprising tonalites to granites were emplaced in migmatitic gneisses (Cingolani et al. 2002). The ages of these intrusions ranges between 2.05 and 2.04 Ga (see Table 1).
Transcurrent shear zones are oriented nearly E–W, show a width up to 4 km and are a common feature in the Tandilia Belt. The shear-sense indicators point to dextral shearing, where a pure shear component is active during transpressive deformation (Cingolani et al. 2002 and references therein). Frisicale et al. (2007) estimated the P–T conditions at 400–450°C and 6 kbar during the deformation in the Azul megashear zone of Tandilia. Pankhurst et al. (2003) reported Sm–Nd TDM on granitoids from the Tandilia Belt ranging between 2.53 and 2.68 Ga, indicating the main period of crust formation was late Archean to Paleoproterozoic. No evidence was found, neither of younger accretion of juvenile material to the crust nor of Neoproterozoic overprinting (Cingolani et al. 2002).
The Piedra Alta Terrane of southwestern Uruguay
The Piedra Alta Terrane crops out in southwestern Uruguay and is bordered to the east by the Sarandí del Yí Shear Zone (SYSZ). The latter is the tectonic boundary with the Nico Pérez Terrane located to the east (Fig. 2).
The terrane is composed of vast granitic gneiss areas separated by supracrustal metamorphic belts. Two main belts have been recognized: (1) the San José belt (Bossi et al. 1993b; Oyhantçabal et al. 2003, 2007b; Sánchez Bettucci et al. 2010) located in southernmost Uruguay and (2) the Arroyo Grande Belt (Bossi and Ferrando 2001), which crops out in the northern part of the terrane (Fig. 2).
Arroyo Grande Belt
The Arroyo Grande Belt, about 15 km in width and 50 km in length, strikes E-W and is located at the northern edge of the exposed area of the Piedra Alta Terrane (Ferrando and Fernandez 1971; Fernandez and Preciozzi 1974; Bossi et al. 1993b; Preciozzi 1993). The belt contains the supracrustal Arroyo Grande Formation and several associated intrusive granitoids. The Arroyo Grande Formation is a greenschist facies folded volcano-sedimentary succession, with the bottom in the north and cut by the Paso de Lugo fault in the south. Siliciclastic rocks predominate in the succession and display preserved primary structures including metarenites, quartzites, metarkoses, metapelites and rarely metaconglomerates. The metavolcanic rocks are restricted to the southern zone and include metabasalts and metaandesites, with a paragenesis of chlorite, epidote, albite, quartz, opaque minerals and calcite, and metadacites. Observed mineral assemblages indicate greenschist facies metamorphism.
San José Belt
Low- to medium-grade metamorphic rocks are exposed in the basement areas flanking a Mesozoic rift (Santa Lucía Basin) in the southern Piedra Alta Terrane (Fig. 2). Originally conceived as two different metamorphic belts: Montevideo and San José (Bossi et al. 1993b) are now regarded, based on geographic proximity and similarity of structural trend and U–Pb ages (Table 1) as belonging to a single belt interrupted by the development of a rift. The name San José Belt is preferred due to the better exposure in the surroundings of the City of San José (Oyhantçabal et al. 2007b).
The Montevideo Formation (Fig. 2) comprises amphibolites, paragneisses and garnet and staurolite-bearing micaschists. The San José Formation—probably the continuation of the former—is almost exclusively composed of paragneisses and garnet and staurolite-bearing micaschists (Preciozzi 1993; Oyhantçabal et al. 2003, 2007b).
The Paso Severino Formation occurs to the north of the Cufré Shear Zone and is a greenschist facies folded volcano-sedimentary succession. The formation is divided into NE- and NW-trending sectors, due to the influence of conjugate NNW dextral and ENE sinistral shear zones (Fig. 2).
Sedimentary lithologies include predominant metapelites and rarely dolomitic marbles and banded iron formations. The metavolcanic rocks include metabasalts and metaandesites, metadacites and metatuffs. At least two deformation events are recognized in the belt (Campal 1990; Preciozzi 1993; Oyhantçabal et al. 2007b). The last event is associated with syn-tectonic granites and the above-mentioned conjugate shear system.
U–Pb SHRIMP ages on zircon from a metadacite of the Paso Severino Formation yielded an age of 2,146 ± 7 Ma (Santos et al. 2003; see Table 1). This age matches the crystallization age of the metamorphic protoliths on a regional scale in the Río de la Plata Craton (2.22–2.1 Ga).
Florida central granitic gneiss belt
Gneisses and granites make up the bulk of the central area located between Arroyo Grande and San José Belts. Decameter- to kilometer-sized xenoliths of micaschists, paragneisses and amphibolites are common within the granites and gneisses. Several post-tectonic granites also intrude the central granitic gneiss belt. U–Pb age determinations are not available, but Rb–Sr whole-rock ages (2,015 ± 40 Ma, Piedra Alta granodiorite; 2,030 ± 75 Ma, Carmelo granodiorite and 1,970 ± 55 Ma, Conchillas granitic gneiss; Umpierre and Halpern 1971) and field relationships (Oyhantçabal et al. 2007b) indicate that the late- to post-orogenic intrusions correspond to the same magmatic event responsible for the 2.08–2.05 Ga post-orogenic plutons that intruded into the Arroyo Grande and San José Belts.
Paleoproterozoic late- to post-orogenic granitoids and gabbros
Several late- and post-orogenic plutons intrude the Florida, San José and Arroyo Grande Belts. Available major element composition data summarized in Fig. 3 indicate that most of the intrusions are calc-alkaline with medium to high-K contents, although some alkaline plutons have been also recognized. SHRIMP U–Pb ages of 2,065 ± 9 and 2,074 ± 6 Ma were obtained for the Isla Mala pluton (Hartmann et al. 2000) and 2,053 ± 14 Ma (conventional multi-grain U–Pb zircon; Peel and Preciozzi 2006) for the Cufré Granite. Post-orogenic gabbros are also frequently associated (e.g. Mahoma, Rospide and Carreta Quemada Gabbros). U–Pb SHRIMP ages for zircons from the Rospide Gabbro yielded 2,076 ± 6 and 2,086 ± 7 Ma (Hartmann et al. 2008a). The similar ages of gabbros and granites point to a coeval magmatism. The Soca Granite is a unique intrusion in the Piedra Alta Terrane. It shows high contents of LIL and HFS elements and high FeO*/[FeO* + MgO] ratios, similar to the typical rapakivi granites in southern Finland (Oyhantçabal et al. 1998), but it belongs to the A2-type post-collisional granites of Eby (1992). A SHRIMP zircon U–Pb age of 2,056 ± 6 Ma, reported by Santos et al. (2003), is the best estimation of the crystallization age of this granite. This confirms that the Soca Granite should not be considered an example of the typical anorogenic rapakivi association, but an A2-type rapakivi granite of the rapakivi granite-shoshonite rock series, formed after continent collision or arc magmatism (Eby 1992; Larin 2009). In summary, this late- to post-orogenic association of granite and gabbro magmatism occurred at 2,080–2,050 Ma and includes medium- to high-K2O calc-alkaline, alkaline and rapakivi intrusions.
Florida dike swarm
The Florida dolerite dike swarm is more than 100 km in width, trends c. 060° and extends for more than 250 km from the westernmost exposed RPC in Uruguay to the Sarandí del Yí Shear Zone in the east. Individual dikes are subvertical, with a thickness attaining 50 m and a length up to 20 km. Whole-rock geochemistry and petrographic features allow the distinction of high and low TiO2 tholeiitic dikes of andesitic-basalt and andesitic composition, respectively (Bossi et al. 1993a). The swarm displays positive εSr and negative εNd typical of an EM1-type mantle source (Mazzucchelli et al. 1995). A U–Pb determination on baddeleyite of 1,790 ± 5 Ma is the best estimate of the crystallization age of the high Ti dikes, considered younger than the low Ti dikes (Halls et al. 2001).
Neoproterozoic volcano-sedimentary and sedimentary successions
Neoproterozoic cover is usually lacking in the Piedra Alta Terrane, an exception is a small outcrop area corresponding to the Piedras de Afilar Formation (see Fig. 2). The formation comprises very low-grade (metamorphic?) arenites, shales and limestones intruded by dolerite sills (Pecoits et al. 2008).
The Nico Pérez Terrane of eastern Uruguay
Valentines–Rivera Granulitic Complex
This complex, exposed in the northern part of the Nico Pérez Terrane, is represented by felsic to mafic granulitic orthogneisses and relicts of a platform supracrustal succession (the Vichadero Formation) including BIFs, pyroxene fels, micaschists and exceptional forsterite-bearing marbles (Ellis 1998). Mesoperthitic alkali feldspar dominates in the leucocratic orthogneisses, mostly in sub-equant grains showing triple-point junctions. Orthopyroxene and garnet is present in the mafic granulites and sillimanite and garnet in the micaschists. The felsic granulitic orthogneisses of Rivera display a high-K calc-alkaline signature compatible with a magmatic arc setting. The observed parageneses suggest a metamorphic peak at pressures of 6–9 kbar and temperatures of ~800°C (Vidal 2009).
Santos et al. (2003) determined a crystallization U–Pb SHRIMP age of 2,140 ± 6 Ma and a metamorphic age of 2,077 ± 6 Ma in a metatrondhjemite from Rivera. Similar U–Pb SHRIMP ages were obtained by these authors in the granitic granulite of Valentines: 2,058 ± 3 Ma for the metamorphism and 2,163 ± 8 Ma for the magmatic crystallization, but in this case some inherited older cores (2,224 ± 4 Ma) are observed.
Pavas Block (Preciozzi et al. 1979) ~ La China Complex (Hartmann et al. 2001)
The Pavas Block is characterized by a predominance of mafic to ultramafic rocks associated with quartzites. Oyhantçabal and Vaz (1990) describe amphibolic gneisses, garnet amphibolites, nearly monomineralic actinolitite, interpreted as metaultramafic rocks, and fuchsite-bearing quartzites. An orthogneiss analyzed by Hartmann et al. (2001) showed metamorphic overgrowths on zircon that yielded U–Pb SHRIMP ages of 3.1 and 2.7 Ga, while an age of 3.41 Ga obtained in a zircon core is considered to represent the magmatic age.
Paleo- and neoproterozoic granites
The Illescas Batholith is a large intrusive body that is cut in the west by the Sarandí del Yí Shear Zone. It is considered to be a rapakivi granite with a Pb–Pb age of 1,784 ± 5 Ma. Isotopic and geochemical data of this batholith are still lacking, but an A-type intrusion in an anorogenic setting is assumed (Campal and Schipilov 1995).
Neoproterozoic granites are widespread in the Nico Pérez Terrane and are related to the Brasiliano cycle. Examples for better constrained ages include the Puntas del Santa Lucía Granite (633 ± 8 Ma; U–Pb zircon; Hartmann et al. 2002), the Puntas del Mataojo Granite (627 ± 23 Ma; U–Pb on zircon; Oyhantçabal et al. 2009), the Solís de Matojo Granite, emplaced in the Sarandí del Yí Shear Zone (584 ± 13 Ma; Pb–Pb on sphene; Oyhantçabal et al. 2007a) and the Arroyo Mangacha Granite (583 ± 7; U–Pb SIMS on zircon; Gaucher et al. 2008).
Mesoproterozoic volcano-sedimentary successions
Oyhantçabal et al. (2005) reported Mesoproterozoic ages in metavolcaniclastic rocks and gabbros associated with marbles and micaschists and erected the Zanja del Cerro Grande Group to embrace the Mesoproterozoic volcano-sedimentary successions of the Nico Pérez Terrane. The supracrustals of the Zanja del Cerro Grande Group occur as tectonic slices in the gneissic basement of the Nico Pérez Terrane (Campanero Unit). For additional information about these Mesoproterozoic successions see Gaucher et al. (2010, this volume).
Neoproterozoic volcano-sedimentary and sedimentary successions
The Neoproterozoic cover is related to the evolution of the Dom Feliciano Belt and comprises a schist belt (pre-collisional sequences) and a foreland belt. The schist belt is not part of the Nico Pérez Terrane (see discussion below) and includes the Lavalleja Group of Uruguay and the Porongos (Rio Grande do Sul) and Brusque (Santa Catarina) Groups of southern Brazil (Basei et al. 2008a).
The foreland belt consists of several volcano-sedimentary and sedimentary successions: the Arroyo del Soldado and the Maldonado Groups (Gaucher 2000; Gaucher et al. 2003, 2004; Pecoits et al. 2004, 2008). The age is constrained by the occurrence of Ediacaran microfossils (Gaucher et al. 2003) and U–Pb zircon dating of associated volcaniclastic rocks (Hartmann et al. 2002; Oyhantçabal et al. 2009).
Santa Maria Chico Granulitic Complex (basement of the Taquarembó block)
The basement of the Taquarembó consists of granulites and gneisses of the Santa Maria Chico Granulitic Complex. The protolith age is Paleoproterozoic (2,366 ± 8 Ma and 2,489 ± 6 Ma; U–Pb SHRIMP; Hartmann et al. 2008b) and it was metamorphosed during the Paleoproterozoic (2.2–2.0 Ga; Hartmann 1998; Hartmann et al. 1999).
Neoproterozoic overprinting is widespread and 600–550 Ma intrusions are common as in case of the Rivera Block of Uruguay (Hartmann and Nardi 1982). Felsic and mafic granulites are observed like in Uruguay, but in the case of the Santa Maria Chico Granulitic Complex, the felsic granulites show low-K calc-alkaline affinity. Geographic proximity, metamorphic style and age correlations strongly support the idea that the basement of the Taquarembó Block should be considered the prolongation of the Valentines–Rivera Granulitic Complex of Uruguay.
Basement inliers in the Dom Feliciano belt (Campanero unit and Punta del Este Terrane of eastern Uruguay; Encantadas Complex of southernmost Brazil)
Campanero Unit, southernmost Uruguay
The Campanero Unit (Fig. 4) was defined as pre-tectonic granitoids with mylonitic to gneissic texture (Sánchez Bettucci 1998). Oyhantçabal (2005) described orthogneisses, stripped orthogneisses, scapolite gneisses, amphibolites, micaschists, banded iron formations and migmatites. Major and trace element data for the orthogneiss (Oyhantçabal 2005) indicate that the protoliths are granites related to a high-K2O calc-alkaline magmatic arc. Mallmann et al. (2007) reported a U–Pb SHRIMP determination on zircon that yielded a concordant age of 1,754 ± 7 Ma, interpreted as the age of the magmatic crystallization of the protolith. A similar age, 1,735 +32/−17 Ma, but using the conventional U–Pb systematic was found by Sánchez Bettucci et al. (2004). It is remarkable that the roughly coeval Illescas Rapakivi Granite corresponds to an anorogenic setting that did not experience high-grade metamorphism, suggesting both units were allochthonous in the Paleoproterozoic. Amphibole from an amphibolite of the Campanero Unit yielded a weighted average age of plateau-like fractions of 564 ± 4.1 Ma (Oyhantçabal et al. 2009), which constrain the Ediacaran cooling history (at c. 500°C) of this unit.
The Punta del Este Terrane of eastern Uruguay
The Punta del Este Terrane, located east of the Sierra Ballena Shear Zone (Preciozzi et al. 1999) and considered a pre-Brasiliano basement (Fig. 3), comprises orthogneisses, paragneisses, amphibolites and migmatites of the Cerro Olivo Complex (Masquelin 2004). Conditions for the metamorphic peak are estimated at temperatures ranging between 770° and 850°C and pressures between 7 and 11 kbar (Masquelin et al. 2001). Magmatic ages at 850–750 Ma on zircon and high-temperature metamorphism dated at 650–600 Ma confirm the correlation between the Punta del Este Terrane and the Coastal Terrane of the Kaoko Belt (Oyhantçabal et al. 2009; Gross et al. 2009). Similar ages have also been reported in xenoliths of the Pelotas Batholith (da Silva et al. 1999) and in the Neoproterozoic basement of the Brusque Group (843 ± 12 Ma, U–Pb SHRIMP on zircon; Basei et al. 2008b).
Encantadas complex, southernmost Brazil
The Encantadas Complex (not shown in Fig. 4; for details see Saalmann et al. 2010, this volume) comprises Paleoproterozoic gneisses of tonalitic and trondhjemitic composition and minor associated amphibolites and metaultramafic rocks and extends in Rio Grande do Sul from Pinheiro Machado in the southeast to Porto Alegre in the northeast (Hartmann et al. 2003; Philipp et al. 2008). Saalmann et al. (2010, this volume) discuss the possibility that the Porongos Schist Belt and Pelotas Batholith belong to a tectonic unit (Encantadas microcontinent) which was later amalgamated to the Rio de la Plata Craton and the São Gabriel Block.
Geophysics
Gravity data acquisition in Uruguay was undertaken during the last 50 years by the Military Geographic Service and the Geological Survey (DINAMIGE). A dataset of Bouguer anomalies with fairly good spatial coverage (2,566 measurements; ca 1/70 km2) is available from DINAMIGE. The isostatic residual Bouguer anomaly map of Uruguay is shown in Fig. 5. Gravity signature confirms most structural features of the Precambrian Basement of Uruguay. The Piedra Alta Terrane shows E–W oriented gravity highs matching the San José and Arroyo Grande supracrustal belts. The Sarandí del Yí Shear Zone coincides with a low-gravity lineament, whose prolongation can be traced with NW trend to Argentina. In eastern Uruguay, the gravity signature is characterized by a c. N–S trend, in concordance with the structure of the southern Dom Feliciano Belt and a roughly E-W gravity high related to the Mesozoic Laguna Merín Basin (Fig. 5).
Hallinan et al. (1993) presented the first revision of the structure of the southern Brazilian Shield based on gravity and magnetic data and concluded that gravity data do not support the prolongation of the Río de la Plata Craton into Brazil and that “…any linkage between Nico Perez Terrane and the Rio de la Plata Craton is necessarily speculative, if more detailed investigations are not available, such as petrographic and geochronological studies.” The isostatic residual Bouguer anomaly map presented in Fig. 5 confirms the conclusions of these authors.
U–Pb geochronology
Selected U–Pb ages, most of them SHRIMP ages on zircon, from the basement of the Río de la Plata Craton are presented in Table 1. Crystallization ages of protoliths range between 2.1 and 2.22 Ga in the Tandilia Belt, in the Piedra Alta Terrane and in the westernmost boreholes where the basement is not exposed. Late- to post-orogenic igneous activity at 2.0–2.1 Ga is also observed in these units.
Data in the Nico Pérez Terrane and in the Taquarembó Block reflect a protracted history: inherited zircon ages range from 3.41 to 2.2 Ga and are a sign of long-lived crustal recycling processes. Furthermore, high-grade metamorphism is recorded in zircon overgrowths that yielded U–Pb SHRIMP ages of 2.1–2.0 Ga.
These data suggest different tectonic settings at 2.0–2.1 Ga in the Nico Pérez Terrane and the Taquarembó Block, where high-grade peak metamorphism and deformation occurred, compared to the rest of the Río de la Plata Craton, where late- to post-orogenic events took place. In addition, calc-alkaline arc–related magmatism at c. 1.7 Ga (orthogneiss of the Campanero Unit) and Mesoproterozoic volcano-sedimentary rocks occur exclusively in the Nico Pérez Terrane.
In accordance with the original definition of Almeida et al. (1973), the Río de la Plata Craton was “already consolidated in the upper Precambrian”. Excluding the Nico Pérez Terrane, not finally cratonized until the Phanerozoic, the Río de la Plata Craton is characterized by two tectonothermal Transamazonian events at 2.2–2.1 and 2.1–2.05 Ga, which can be correlated with the second and third Transamazonian orogenies of Santos et al. (2003). These data suggest the Nico Pérez Terrane could be considered an allochthonous terrane, which was accreted to the Río de la Plata Craton since at least Neoproterozoic time. Constraints on accretion age are discussed below.
Sm–Nd isotope data
Thirteen samples of metasedimentary and igneous rocks from the crystalline basement of Uruguay were analyzed (analytical data and location of the samples are available in the electronic appendix) and model ages calculated. Samples were selected in order to cover the different basement units of Uruguay including the Piedra Alta Terrane (4 samples), the Nico Pérez Terrane (5 samples) and the Punta del Este Terrane (4 samples). The latter, located in the easternmost part of Uruguay, is a basement unit related to the Dom Feliciano Belt and probably of African affinity (Oyhantçabal et al. 2009; Gross et al. 2009).
The Piedra Alta Terrane shows TDM crustal residence times between 2.28 and 1.76 Ga (mean 2.03 Ga, n = 4); in the Nico Pérez Terrane, TDM ages varies between 2.72 and 1.86 Ga and finally in the Punta del Este Terrane values between 2.19 and 1.44 Ga (mean = 1.82 Ga, n = 4) were found.
For more statistical significance, these new data are analyzed together with those previously published for the Río de la Plata Craton (Fig. 6). The Tandilia Belt (24 samples) and the Piedra Alta Terrane (16 samples) show quite similar histograms, where most of the values are clustered between 2.7 and 2.2 Ga. TDM ages in the Piedra Alta Terrane seems to be slightly younger, but the difference is not statistically significant. The younger TDM ages, 1.92 and 1.76 Ga, were obtained in Neoproterozoic sediments of the Piedras de Afilar Formation, for this reason some contribution from a source in the adjacent Nico Pérez Terrene or the Dom Feliciano Belt is expected and confirmed by previously published U–Pb ages of detrital zircons (Gaucher et al. 2008). This similarity in crustal residence times, together with the above-mentioned similarity in U–Pb geochronology indicates that the Tandilia Belt and the Piedra Alta Terrane are not allochthonous, and rather rule out the hypothesis of Bossi and Cingolani (2009).
The Nico Pérez Terrane presents a bi-modal distribution of TDM ages: one cluster at 3.0–2.6 Ga and the other at 2.3–1.6 Ga. This is consistent with the wide range of U–Pb ages and indicates two main events of crustal extraction from the mantle. TDM ages for the analyzed samples of the Punta del Este Terrane range between 2.19 and 1.44 Ga. The pattern looks similar to the younger cluster of the Nico Pérez Terrane, but the data are not sufficient to draw any conclusion.
Preliminary whole-rock Pb–Pb data
Pb isotopic signatures have been used to discriminate between different basement domains (Schwartz and Gromet 2004; Drobe et al. 2009). Six samples of metasedimentary rocks from the crystalline basement of Uruguay were analyzed. Results and location of the samples are presented as an electronic appendix. All samples are metasedimentary rocks, one from the Piedra Alta Terrane, four from the Nico Pérez Terrane and two from the Punta del Este Terrane. Most of the samples plot in a near linear array that overlaps the different compositional fields defined for western Gondwana (Fig. 7). Samples from Nico Pérez and Punta del Este Terranes plot very close to one another, suggesting a similar reservoir and the possibility that both terranes are not allochthonous, but other criteria discard this correlation (see discussion below). The sample from the Piedra Alta Terrane (UYM 1-06) displays higher 207Pb/204Pb and 206Pb/204Pb ratios than all the other samples. It plots in the 208Pb/204Pb versus 205Pb/204Pb diagram outside the linear trend defined by the other samples. Additional data are necessary in order to allow the definition of allochthonous blocks based on Pb isotopic data.
Muscovite K–Ar age constraints on tectonothermal events
Nineteen muscovite samples, along a transect across the major tectonic units of the Río de la Plata Craton (Piedra Alta Terrane and Nico Pérez Terrane) and the Dom Feliciano Belt in southern Uruguay, were selected for K–Ar isotopic analysis to constrain the timing of the medium temperature (350 to 420°C) cooling history. Analytical results are shown in the electronic appendix.
The K–Ar cooling ages provide time constraints for the exhumation and cooling in the Piedra Alta Terrane between 2,057 and 1,796 Ma and demonstrate that this terrane was not thermally overprinted during Meso- or Neoproterozoic times (Fig. 8). Neoproterozoic cooling ages (628–545 Ma) characterize the basement domains located east of the Sarandí del Yí Shear Zone (Nico Pérez Terrane and the Dom Feliciano Belt), which is in agreement with the geological evidence of widespread Neoproterozoic reworking.
The Ediacaran Piedras de Afilar Formation in the Piedra Alta Terrane, containing Mesoproterozoic detrital zircons (Gaucher et al. 2008), provides proof that the Piedra Alta and Nico Pérez Terranes were juxtaposed prior to the Ediacaran. Nevertheless, it is remarkable that no Ediacaran overprinting is observed in the K–Ar isotopic system, even in the easternmost outcrops sampled in the Piedra Alta Terrane, although they are less than 25 km away from the Sarandí del Yí Shear Zone. Furthermore, cooling ages change abruptly from Paleoproterozoic in the Piedra Alta Terrane to Neoproterozoic in the Nico Pérez Terrane. These findings are consistent with the results of Teixeira et al. (1999) showing 40Ar–39Ar plateau ages of 2,016 ± 11 Ma (hornblende) and 1,817 ± 10 Ma (biotite) in a post-tectonic granodiorite from the Piedra Alta Terrane, and 596 ± 5 (hornblende) and 563 ± 4 Ma (biotite) in a granodiorite from the Nico Pérez Terrane.
Discussion
Magmatic and metamorphic events and isotopic signatures
The tectonostratigraphic chart of Fig. 9 shows the age of the main events on the different terranes and domains of the Río de la Plata Craton and the contiguous Dom Feliciano Belt. The Piedra Alta Terrane is characterized by magmatic events at 2.2–2.1 Ga (age of the protolith magmatism) and at 2.1–2.0 Ga (late- to post-orogenic granitoids and gabbros). The metamorphism is therefore constrained between both magmatic events. TDM model ages span between 2.8 and 2.3 Ga, indicating remnants of older continental crust contributing to the magma. K–Ar cooling ages on muscovite point out cratonization at 1.7–1.8 Ga and that this terrane remained unaffected by younger tectonothermal events. A similar scenario is observed in the case of the Tandilia Belt. Available isotopic data do not support the hypothesis that the Tandilia Terrane is an allochthonous unit as suggested by Bossi et al. (2005).
The histogram of TDM model ages of the Nico Pérez Terrane shows two main events of crustal growth (3.0–2.6 and 2.3–1.6 Ga), consistent with U–Pb zircon ages showing long-lived crustal recycling processes (Oyhantçabal et al. 2009). U–Pb geochronology indicates magmatic events at 3.1 to 2.5 Ga (age of the protolith magmatism), and high-T metamorphism at 2.08–2.05 Ga (felsic and mafic granulites). A similar scenario is observed in the Santa María Chico Granulitic Complex, and therefore we suggest that the Taquarembó Block of Río Grande do Sul is part of the Nico Pérez Terrane. Granites showing a Brasiliano age, which are subduction-related as well as post-tectonic, are widespread in the Nico Pérez Terrane and in the Taquarembó Block.
Proterozoic mafic dike swarms
Table 2 summarizes the available petrological and geochronological data of the Precambrian dike swarms of the Río de la Plata Craton. A calc-alkaline dike swarm intruded near-coeval with the post-orogenic granitic plutonism, which stands out in the Tandilia (Teixeira et al. 2002). In the Nico Pérez Terrane of Uruguay, a dike swarm of similar age has not been recognized yet, but numerous gabbro intrusions, like Mahoma, Rospide and Carreta Quemada, could represent this event of mafic post-orogenic magmatism.
Iacumin et al. (2001) underlined the geochemical similarities between the tholeiitic Florida dike swarm in the Piedra Alta Terrane (1.79 Ga) and the tholeiitic dikes of Tandilia (~1.59 Ga, Teixeira et al. 2002; more precise age determinations are still lacking). Both dike swarms are probably coeval and may correspond to anorogenic extension roughly 200 Ma after the Transamazonian orogeny in the Río de la Plata Carton (Teixeira et al. 2002). In the Nico Perez Terrane, the Illescas Granite (1.79 Ga) is the only known example of pre-Neoproterozoic anorogenic magmatism. Extensional anorogenic events at 1.75–1.68 Ga are well recorded in most of the cratons of the Brazilian shield (see Table 13 in Teixeira et al. 1999). In contrast, Neoproterozoic dike swarms have only been identified in the Nico Pérez Terrane (Table 2).
Redefinition of the boundaries and internal structure of the RPC
The Piedra Alta Terrane and a redefinition of the Río de la Plata Craton
The definition of the boundaries of the Río de la Plata Craton depends on how a craton is defined. After the extraction of basaltic magmas from the mantle, continents can build a buoyant and refractory mantle lithosphere stagnant to subduction and to deformation (Sengör 1999; Slepp 2005). If a continent with such a lithosphere is left untouched more than 1 Ga, cooling will make it very strong. Nowadays a craton is defined as a “core region of a continent that has remained stable on a billion-year (Ga) time scale” (Hoffman 1988; Eaton et al. 2009). Alkmim (2004) defines cratons as differentiated components of the continental lithosphere that are provided with thick, cold, old and buoyant mantle roots, and as a consequence a high lithospheric strength that avoids pervasive deformation.
A sharp contrast in behavior, in relation to tectonothermal Brasiliano events, is observed between the Piedra Alta Terrane and the Nico Pérez Terrane. The Piedra Alta Terrane is not affected by tectonic or thermal Neoproterozoic Brasiliano orogenic events. In contrast, the Nico Pérez Terrane as well as the Taquarembó Block show Neoproterozoic widespread reworking, including granitic intrusions, shear zones and foreland deposits.
These pieces of evidence indicate cratonization of the Piedra Alta Terrane occurred at Paleoproterozoic times and that already in the Precambrian this terrane developed a thick lithosphere, probably after the extensional episode related to the Florida dike swarm (~1.79 Ga). 40Ar–39Ar plateau ages on hornblende (1,727 ± 10 Ma) and biotite (1,725 ± 10 Ma) from this dike swarm, obtained by Teixeira et al. (1999), confirm that they intruded into a cold crust. In contrast, the Nico Pérez Terrane was not endowed with a thick and strong lithosphere during Brasiliano events and was therefore strongly reworked. Lithospheric thicknesses in the present-day crust is probably similar in both terranes, but the geological record indicates that this was probably very different during the Neoproterozoic. Despite the occurrence of older continental crust surviving in the Nico Pérez Terrane and in the Taquarembó Block, repeated tectonothermal events probably prevent cratonization (Fig. 9).
An alternative hypothesis that may explain the different degree of observed Neoproterozoic reworking includes the Paleoproterozoic stretching of the crust during widespread extensional events at 1.7–1.8 Ga, which is observed in both terranes. This could have resulted in slices of thinned continental crust being later re-amalgamated. However, the following pieces of evidence rule out this alternative hypothesis, and therefore the terranes should be considered exotic:
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Lack of Eo-, Paleo- or Mesoarchean crust-forming events in the Piedra Alta Terrane
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High-temperature regional metamorphism and foliation development in granulites of the Valentines–Rivera and Santa María Chico complexes at 2.08–2.05 Ga is coeval with post-orogenic granites in Piedra Alta Terrane and Tandilia (2.09–2.05 Ga) and calc-alkaline unmetamorphosed dikes in Tandilia.
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Extension at ~1.8–1.7 Ga occurred in both terranes, but extension of this age is a common feature of all cratons and blocks of the South American Platform (Teixeira et al. 1999).
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Mesoproterozoic supracrustal successions only occur in the basement inliers of the Dom Feliciano Belt (as discussed in the literature and considered a part of the Nico Pérez Terrane; Bossi and Cingolani 2009) and are lacking in the Piedra Alta Terrane and Tandilia.
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Lack of Neoproterozoic reworking in the Piedra Alta Terrane, but widespread granitic intrusions, shear zones and K–Ar–Ar–Ar thermal resetting of this age in the Nico Pérez terrane.
The main question that arises is when both terranes were accreted. There is an abundance of Mesoproterozoic detrital zircons in quartz arenites of the Ediacaran Piedras de Afilar Formation from the Piedra Alta Terrane (Gaucher et al. 2008), where no Mesoproterozoic source areas occur, and indicate that both terranes were already accreted in Ediacaran times. Emplacement of the syntectonic Solís de Mataojo Granitic Complex in the Sarandí del Yí Shear Zone at 584 ± 13 Ma (Oyhantçabal et al. 2007a) also confirms a pre-Ediacaran age of accretion.
Bossi and Cingolani (2009) suggested that the Sarandí del Yí Shear Zone records dextral shearing at 1,200–1,250 Ma, based on a K–Ar age on muscovite from a pegmatite in a thrust plane. Using this data as the age for accretion is quite speculative. First, this age determination is in a thrust plane, more than 10 km away (see Fig. 2 in Gaucher et al. 2010, this volume), and not in the transcurrent shear itself. Additionally, there is still lack of detailed information indicating if thrusting is pre-, syn- or post-transcurrent shear zone. Secondly, deformation conditions in the Sarandí del Yí Shear Zone, with evidence of incipient feldspar recrystallization, indicate temperatures in the range 550–450°C (Oyhantçabal et al. 2010), and therefore this age could represent, at best, only a cooling age. On the other hand, the radical difference in behavior with respect to the Brasiliano Orogeny points out that accretion of both terranes did not occur over a long time before this event; otherwise, the lithospheric thickness and strength would be more similar in both terranes. An examination of the tectonostratigraphic chart (Fig. 9) indicates that the accretion age is poorly constrained, at best between 1.75 and 0.6 Ga, and that the possibility of an accretion during the Neoproterozoic should not be excluded. The above-mentioned arguments indicate that the Río de la Plata Craton does not include the Nico Pérez Terrane and that the Sarandí del Yí Shear Zone is the eastern boundary of the craton.
The Nico Pérez Terrane, the Taquarembó Block and the basement inliers in the Dom Feliciano Belt
The medium- to high-grade basement units located east of the Sarandí del Yí Shear Zone have undergone a quite complex geological evolution, and different authors have assumed different definitions and models. Archean to Paleoproterozoic rocks crop out, but Neoproterozoic reworking is widespread (Figs. 4 and 9). The record of the Neoproterozoic Brasiliano Orogeny includes volcano-sedimentary successions, shear zones and granitoids (Campal and Schipilov 1999; Mallmann et al. 2007; Bossi and Cingolani 2009 and Sánchez Bettucci et al. 2010). Some units, for instance the Campanero Unit, are discussed in terms of basement inliers of the Dom Feliciano Belt or part of the Nico Pérez Terrane, depending on whether the Sierra Ballena Shear Zone or the Fraile Muerto-María Albina Shear Zone is regarded as the eastern boundary of the Nico Pérez Terrane (Bossi and Cingolani 2009; Sánchez Bettucci et al. 2010). Furthermore, the relationship between the pre-Brasiliano basement on the eastern side of the Sierra Ballena and the Nico Pérez Terrane is still not clear.
Preciozzi et al. (1979) originally recognized the Valentines Block between the Sarandí del Yí and the Fraile Muerto-Maria Albina shear zones (Sánchez Bettucci et al. 2010). Bossi and Campal (1992) later defined the Nico Pérez Terrane, to include all units located between the Sarandí del Yí Shear Zone and the Sierra Ballena Shear Zone. According to Hartmann et al. (2001), the Nico Pérez Terrane includes the Valentines Complex, the La China Complex, the Las Tetas Complex, the Fuente del Puma Formation and the Arroyo del Soldado Group. In this contribution, we agree with Preciozzi et al. (1979) and Sánchez Bettucci et al. (2010) and consider the Fraile Muerto-Maria Albina Shear Zone as the eastern boundary of the Nico Pérez Terrane. Regarding the lithostratigraphic similarity between the Valentines—Rivera Granulitic Complex and the Santa Maria Chico Granulitic Complex of the Taquarembó Block, we propose the continuation of the Nico Pérez Terrane until the Ibaré Lineament in Río Grande do Sul. This lineament represents the contact with the juvenile Neoproterozoic Sao Gabriel Block (Saalmann et al. 2005).
The affinity of the basement inliers in the Dom Feliciano Belt in Uruguay (Campanero Unit and the Cerro Olivo Complex = Basement of the Punta del Este Terrane) is still unclear due to the scarcity of data. The same holds true for the basement of the Dom Feliciano Belt in Río Grande do Sul. The so-called Encantadas Complex represents the pre-Brasiliano basement of the Porongos Group and the Pelotas Batholith (Saalmann et al. 2010, this volume). The possibility arises, that all these basement inliers were part of the Encantadas microcontinent (see Saalmann et al. 2010, this volume). On the other hand, available data indicate that the Nico Pérez Terrane and the Taquarembó Block were not part of the Encantadas microcontinent: the c. 1.75 Ga calc-alkaline magmatism of the Campanero Unit is different from the roughly coeval 1.75 Ga rapakivi Illescas Granite; additionally, magmatism at ~770 Ma and metamorphism at 640 Ma is recorded only in the Dom Feliciano Belt. A separate pre-650 Ma evolution is therefore more realistic (see Saalmann et al. 2010, this volume).
Conclusions
A review of lithostratigraphic units in the Río de la Plata Craton, new and previously published geochronological, isotopic data and gravity signatures reveal the following main conclusions:
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1.
The Piedra Alta Terrane is characterized by a single event of crustal growth with Sm–Nd TDM model ages between 2.8 and 2.3 Ga. Crystallization ages of 2.2–2.1 Ga for the metamorphic protoliths and 2.1–2.05 Ga for the granitoids indicate juvenile crust and a short period of crustal recycling. Cratonization, as revealed from K–Ar and Ar–Ar geochronology, occurred at Paleoproterozoic times (Statherian) and a lack of Meso- or Neoproterozoic overprinting is a distinctive feature, pointing out that this terrane already had a thick and strong lithosphere in the Neoproterozoic. A similar scenario is indicated for the Tandilia Belt of Argentina.
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2.
The histogram of Sm–Nd TDM model ages for the Nico Pérez Terrane shows two events of crustal growth (3.0–2.6 Ga and 2.3–1.6 Ga). Crystallization ages on zircon show ages between 3.1 and 0.57 Ga, which is evidence that the continental crust was reworked during several events in the Paleo-, Meso- and Neoproterozoic. A cratonization age cannot be defined, and Neoproterozoic overprinting, expressed in the granites, shear zones and folded supracrustals, is extensive. A similar scenario is observed in the Taquarembó Block, which is considered the prolongation of the Nico Pérez Terrane in southern Brazil.
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3.
The difference in gravity signatures observed in the residual Bouguer gravity map reinforce the lack of affinity between the Piedra Alta and Nico Pérez terranes.
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4.
The basement inliers of the Dom Feliciano Belt (Campanero Unit and Encantadas Complex) seems to record a pre-Brasiliano geological history different from those of Piedra Alta and Nico Pérez terranes, but further investigation is required.
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5.
The above-mentioned differences between the Piedra Alta Terrane and the Tandilia Belt on the one hand, and the Nico Pérez Terrane and the Taquarembó Block on the other, support the redefinition of the Río de la Plata Craton comprising the Piedra Alta Terrane of Uruguay and the Tandilia Belt of Argentina. The Sarandí del Yí Shear Zone is regarded as the eastern margin of this craton.
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Acknowledgments
The authors thank K. Simon (Abt. Geochemie, GZG Göttingen) and R. Naumann (GFZ Potsdam) for geochemical analyses and Robert Frei (Institute of Geography and Geology, University of Copenhagen) for Pb–Pb isotopic determinations. We like to thank Kerstin Saalmann and Augusto Rapalini for rigorous and constructive reviews.
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Appendix
Appendix
Analytical techniques
For geochemical and isotope geochemical whole-rock analyses, the sample material was crushed following standard techniques using a jaw crusher and an agate mill. Major elements were analyzed at the Geoforschungszentrum (GFZ) in Potsdam using a Panalytical XRF-PW 2400.
K–Ar dating of muscovite samples
Mica separation was performed by the standard techniques such as crushing, sieving, Frantz magnetic separation and selection by hand. The pure micas were ground in alcohol and sieved to remove altered rims, which might have suffered argon loss. The argon isotopic composition was measured in a Pyrex glass extraction and purification line coupled to a VG 1200 C noble gas mass spectrometer operating in static mode. The amount of radiogenic 40Ar was determined by the isotopic dilution method using a highly enriched 38Ar spike from Schumacher, Bern (Schumacher 1975). The spike is calibrated against the biotite standard HD-B1 (Fuhrmann et al. 1987). The age calculations are based on the constants recommended by the IUGS quoted in Steiger and Jaeger (1977). Potassium was determined in duplicate by flame photometry using an Eppendorf Elex 63/61. The samples were dissolved in a mixture of Hf and HNO3 according to the technique of Heinrichs and Herrmann (1990). CsCl and LiCl were added as an ionization buffer and internal standard, respectively. The analytical error for the K–Ar age calculations has a 95% confidence level of 2σ. The procedural details for argon and potassium analyses at the laboratory in Göttingen are given in Wemmer (1991).
Sm–Nd isotope data
Nd and Sm isotopic analyses were performed on representative samples by conventional isotope dilution technique. The samples were weighed into Teflon vials and spiked with a suitable amount of 150Nd–149Sm spike solution prior to dissolution in a mixture of 2 ml HF and 1 ml HNO3 with a PicoTraceTM digestion system. The solutions were processed by standard cation-exchange techniques for purification of the Sm and Nd fractions. For the determination of isotopic compositions, Sm and Nd were loaded with 2.5 N HCl on pre-conditioned double Re filaments. Measurements of isotopic ratios were performed on a Finnigan Triton thermal ionization mass spectrometer (TIMS) measuring in static mode (GZG, Department of Isotope Geology). Repeated measurement of the Nd in-house standard yielded a 143Nd/144Nd ratio of 0.511798 ± 0.000077 (n = 71, 2r) over the course of this study. The obtained Nd isotopic ratios of the samples were normalized to a 146Nd/144Nd ratio of 0.7219. Total procedure blanks were consistently below 150 pg for Sm and Nd. All 143Nd/144Nd ratios are reported with their 2r internal precision plus the uncertainties resulting from the spike correction. The data were calculated according to the model of Goldstein et al. (1984).
Pb isotopic data
Rock powders were pre-treated with HBr, dissolved with HF and HNO3 during addition of HBO3 (Connelly et al. 2006), and then dried and redissolved in HNO3. Pb isotope ratios of whole rocks were analyzed at the Institute of Geography and Geology, University of Copenhagen, using a VG Sector 54 IT mass spectrometer. Chemical separation of Pb was performed over conventional anion exchange columns with HBr–HCl, followed by purification on 200-ml Teflon columns. Fractionation of Pb during static multi-collection-mode mass-spectrometric analysis was monitored by repeated analysis of the NBS 981 standard (Todt et al. 1993) and amounted to 0.105 ± 0.008% per atomic mass unit (amu; n = 12, 2σ). Procedural Pb blanks remained below 50 pg; this low blank does not affect the measured Pb isotopic ratios of the samples significantly.
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Oyhantçabal, P., Siegesmund, S. & Wemmer, K. The Río de la Plata Craton: a review of units, boundaries, ages and isotopic signature. Int J Earth Sci (Geol Rundsch) 100, 201–220 (2011). https://doi.org/10.1007/s00531-010-0580-8
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DOI: https://doi.org/10.1007/s00531-010-0580-8