Abstract
The initiation of ductile shear zones commonly occurs spatially associated with fluid-rock reactions along brittle precursors. In many cases the relative timing of fracturing, fluid infiltration, reaction, and recrystallisation is unclear, making it difficult to disentangle mechanisms of shear zone initiation from subsequent deformation and recrystallisation. Here we present the study of the transition from a dry plagioclase-diopside-garnet-scapolite host granulite-facies lithology to (1) a low strain amphibolite-facies rock, and (2) a transition from low strain to high strain amphibolite-facies lithologies. Hydration of the granulite-facies precursor at amphibolite-facies conditions produces an assemblage comprised dominantly of plagioclase-amphibole-zoisite-clinozoisite-kyanite-scapolite-quartz. Detailed study of plagioclase chemistry and microstructures across these two transitions using Electron Backscatter Diffraction (EBSD) and Wavelength Dispersive Spectrometry (WDS) allows us to assess the degree of coupling between deformation and fluid-rock reaction across the outcrop. Plagioclase behaves dominantly in a brittle manner at the hydration interface and so the initial weakening of the rock is attributed to grain size reduction caused by fracture damage and fluid infiltration at amphibolite-facies conditions. Extensive fracturing-induced grain size reduction locally increases permeability and allows for continuing plagioclase and secondary mineral growth during shear. Based on plagioclase microstructures, such as, an inherited but dispersed crystallographic preferred orientation (CPO), truncation of chemical zoning, and the dominance of fine (5–150 µm), slightly elongate, polygonal grains we conclude that deformation is dominantly facilitated by dissolution–precipitation creep assisted by grain boundary sliding in the shear zone.
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Introduction
It has long been recognised that shearing is commonly initiated in association with fluid infiltration on brittle precursors (Austrheim 1987; Austrheim and Griffin 1985; Pennacchioni and Mancktelow 2007; Segall and Simpson 1986; Stünitz and Fitz Gerald 1993). One explanation for this may be that the grain size reduction necessary to allow for strain localisation is achieved by reaction between the infiltrating fluid and the brittley fractured host-rock (Berger and Stünitz 1996; Fusseis and Handy 2008; Goncalves et al. 2016; Rutter and Brodie 1995). Alternatively, initial grain size reduction may occur entirely as a result of fracturing (Brander et al. 2012; Imon et al. 2004; Menegon et al. 2013; Nyman et al. 1992; Okudaira et al. 2015) and the fluid infiltration and associated fluid-rock interaction facilitates strain localisation. Which process occurs has implications for the timing of strain localisation after brittle failure and is critical for understanding the role of fluids in determining the strength of the crust.
Both scenarios proposed in the previous paragraph are models where weakening results from a grain size reduction and the infiltration of fluid, allowing for the activation of grain size sensitive creep. The primary difference between the models is the timing and role of reaction in weakening the rock. In the first scenario, from here onwards referred to as the reactive-weakening model, weakening occurs after a significant proportion of the host rock has been reacted to a finer grained or weaker mineralogy. In this scenario, continued fluid-rock interactions should result in progressive weakening at the shear zone margin (e.g., Kaatz et al. 2023), resulting in a shear zone that is widening over time. Thus, the reactive-weakening model is consistent with models involving incrementally thickening shear zones, generally classified as type 1 shear zones (Fossen and Cavalcante 2017; Hull 1988; Means 1984). Such a scenario is described in detail by Mancktelow and Pennacchioni (2005) and Pennacchioni and Mancktelow (2007). In the second scenario, from here onwards referred to as the cataclastic model, weakening is result of mechanical grain size reduction and subsequent fluid infiltration in the fracture damage zone. In the cataclastic model any further strain accumulation will be confined to the initial damage zone and percolation or diffusion of fluid into the surrounding rock will produce an alteration halo without any further weakening. The cataclastic model of shear zone formation is consistent with type 3 shear zones of Fossen and Cavalcante (2017) and the model described by Pennacchioni and Mancktelow (2018) for small scale ductile shear zones (< 1 m thick).
Here, we investigate a larger (~ 10 m thick) ductile shear zone to determine which model is consistent with shear zone initiation. We propose that the prevalent model should be evident in the rock microstructure as in the reactive-weakening model the extent of strain should be proportional to the extent of reaction, whereas in the cataclastic model reaction and deformation will not necessarily be coupled. The outcrop that is the focus of this study, located on Radøy in the Bergen Arcs, Norway, has been described previously by Moore et al. (2019); Moore et al. (2020a); and Moore et al. (2020b). The reaction from a granulite-facies precursor assemblage of plagioclase-garnet-diopside-scapolite to an amphibolite-facies assemblage dominated by plagioclase-amphibole-zoisite-clinozoisite-kyanite-scapolite-quartz has been described in detail by Moore et al. (2020a). Two main conclusions of the previous contribution of Moore et al. (2020a) are: (1) dissolution–precipitation was the governing reaction mechanism, and (2) during the transformation from granulite-facies to low strain amphibolite-facies lithologies the dissolution and precipitation reactions were coupled at the reaction interface, while they were decoupled during the transformation from granulite-facies to the high strain amphibolite-facies lithologies. In this contribution we investigate the relationship between reaction and deformation microstructures in more detail by combined Electron Backscatter Diffraction (EBSD) and Wavelength Dispersive Spectrometry (WDS) mapping of plagioclase in the low strain and high strain amphibolite-facies domains and the granulite precursor. By comparing plagioclase microstructures, chemistry and reaction assemblages across these lithologies we aim to establish whether reaction extent and strain are proportional and whether the difference in reaction coupling or decoupling between low and high strain amphibolite-facies domains described in Moore et al. (2020a) is indicative of the process that resulted in the shear zone formation.
Geological setting
The outcrop that is the focus of this study is situated on Radøy within the Lindås Nappe of the Bergen arcs (Fig. 1). The Lindås Nappe is predominantly comprised of an anorthosite-mangerite-charnockite-granite (AMCG) suite and banded gneiss complexes. After intrusion of the AMCG suite, between 1237 + 45/–35 Ma to 945 ± 33 Ma (Austrheim 1990; Bingen et al. 2001), the rocks underwent granulite-facies metamorphism, between 929 Ma (Bingen et al. 2001) and 910 ± 10 Ma (Cohen et al. 1988). Following a period of quiescence, the Lindås Nappe underwent partial hydration during the Caledonian Orogeny at ~ 460–400 Ma (Austrheim 1987; Bingen et al. 2001; Boundy et al. 1996; Glodny et al. 2008; Kühn et al. 2002, 2020b).
Partial hydration of the previously anhydrous rocks is expressed as localised zones of both statically and dynamically metamorphosed eclogite and amphibolite-facies rocks. The outcrop presented in this study preserves static hydration of the granulite to amphibolite-facies assemblage as well as a transition from low strain to high strain amphibolite-facies lithologies. Here, static hydration of the granulite to amphibolite has been constrained to ambient temperatures of ~ 590–730 °C by Zr-in-rutile thermometry (Moore et al. 2020b) and pressures of 10–14 kbar based on Al-in-hornblende barometry and phase equilibrium modelling (Moore et al. 2019, 2020a), while temperatures have been estimated to have reached up to ~ 860 °C within the shear zone (Moore et al. 2020b).
Description of outcrop and lithologies
In this section we provide a general description of the structural characteristics of the outcrop combined with the general lithological descriptions and interpretations of Moore et al. (2020a). The outcrop can be most simply described as consisting of two metamorphic facies, granulite and amphibolite (Fig. 2). The granulite, characterised as a foliated lilac-coloured mafic cluster bearing medium grained rock, is preserved as a 2–3 m wide body encapsulated by the amphibolite lithology (Fig. 2a–c). Throughout the studied outcrop no evidence or remnants of pseudotachylite were observed. The lilac coloured plagioclase matrix comprises 70% of the volume of the granulite (Moore et al. 2020a). The remainder of the granulite is comprised of scapolite (2%) and the foliation defining 1–2 cm elongate diopside (9%) with coronitic garnet (17%) (Fig. 2c).
Within the granulite, fractures occurring subparallel to the shear zone boundary (SZB) are observed (Fig. 2b & c). These fractures are characterised by a central 1–2 mm wide dark greenish core and 2–4 cm wide alteration halo, within which the granulitic plagioclase is milky white due to an abundance of zoisite, quartz, and kyanite ± muscovite inclusions (Moore et al. 2020a). Mafic clusters that are crosscut by the fracture are not visibly offset (Fig. 2c), indicating that no significant displacement occurred along these small fractures.
Across the granulite to amphibolite transition, the granulite foliation (SG) is continuous (Fig. 2b and d) with the amphibolite foliation (SA) due to the direct replacement of diopside and garnet by amphibole. The replacement of diopside and garnet by amphibole is concomitant with the partial recrystallisation of plagioclase to finer grained aggregates containing abundant zoisite, kyanite, and quartz inclusions (Moore et al. 2020a), resulting in a milky white appearance of the plagioclase. The resulting amphibolite lithology is comprised of plagioclase (47%), amphibole (43%), zoisite (3%), kyanite (2%), and biotite (1%) with additional minor phases (Moore et al. 2020a).
At a distance of 50–100 cm to the east of the granulite to amphibolite transition, SA bends sharply into a shear zone (Fig. 2b). This bending of SA marks the transition from low to high strain amphibolite domains. Beyond the SZB the high strain amphibolite transitions from a zone of parallel planar fabric (Fig. 2e) into a spaced foliation defined by interlayered bands of light (leucocratic domains) and dark (high strain amphibolite) material (Fig. 2f). The shear zone extends from the SZB ~ 10 m to the northeast at which point there is no further outcropping rock.
The interlayering of leucocratic and high strain amphibolite domains in the shear zone is the result of metamorphic differentiation during hydration at amphibolite-facies (Moore et al. 2020a). Here, metamorphic differentiation associated with increasing strain results in an overall decrease in amphibole abundance. The amount of amphibole decreases from 43% in the low strain amphibolite to 18–27% in high strain amphibolite domains and 5% in leucocratic domains. The decrease in amphibole abundance with increasing strain is balanced by an increase in plagioclase and plagioclase hydration reaction products (zoisite, kyanite, and quartz ± muscovite). Plagioclase increases in modal abundance from 47% in the low strain amphibolite to 59% in the high strain amphibolite and 74% in the leucocratic domains. Zoisite, kyanite, and quartz comprise 5% of the low strain amphibolite, 5–13% of high strain amphibolite domains and 7% in the leucocratic domains. Due to the dominance of plagioclase in the granulite precursor lithology and the increasing abundance of plagioclase associated with increasing strain, plagioclase microstructures across the granulite – low strain amphibolite – high strain amphibolite transitions are the focus of this contribution.
Methods
Sample selection and preparation
Fracture, altered granulite, granulite, low strain amphibolite and shear zone samples were taken from the locations indicated in Fig. 2b. Thin section blocks were cut parallel to the lineation (X direction) and normal to foliation (XZ plane) present in the sample (SG in the granulite and SA in the amphibolite samples). Initial polishing of thin sections was followed by mechanochemical polishing with colloidal silica before they were lightly carbon coated (3–5 nm thickness) for EBSD analysis.
Quantitative analysis of mineral composition
Quantitative geochemical mapping using WDS was carried out on the JEOL JXA-8530F Electron Microprobe Analyser (EMPA) at the Centre for Microscopy, Characterisation and Analysis (CMCA) at the University of Western Australia, Perth, Australia. Mapping was performed using an accelerating voltage of 15 kV, a beam current of 20 nA and spot/pixel size of 5 µm.
Element distribution maps were acquired using the following analysing crystals: TAP for Si Kα, Al Kα, Na Kα, and Mg Kα; PETJ for Ca Kα and K Kα; and LiF for Ti Kα and Fe Kα. For these analyses the counting time was 20 s for all elements on each pixel. The standards employed were commercially available silicates, oxides, and metals. Mean atomic number background corrections were employed throughout (Donovan and Tingle 1996). Unknown and standard intensities were corrected for dead time and the ZAF algorithm was used for matrix absorption (Armstrong 1988). On-peak interference corrections were applied as appropriate (Donovan et al. 1992).
Quantification of grain size and crystallographic orientation relationships
EBSD analysis was carried out on the Mira3 variable pressure Field Emission Scanning Electron Microscope (FE-SEM) at the John de Laeter Centre (JdLC), Curtin University, Perth, Australia. Patterns were acquired with Symmetry EBSD detector and indexed with AzTec Synergy software (Oxford Instruments). The FE-SEM was run at a high vacuum with an accelerating voltage of 25 kV and a beam current of 8 nA. The samples were tilted to 70˚ and analysed at a working distance of 20–25 mm.
EBSD data was processed using HKL’s Channel 5 software. Non-indexed solutions were replaced by the most common neighbour orientation to reduce data noise following the procedure tested by Bestmann and Prior (2003); Piazolo et al. (2006); and Prior et al. (2002). Following processing, the MTEX toolbox for Matlab (Bachmann et al. 2010) was used to produce orientation distribution functions (ODFs) and texture index (M-index) values (Mainprice et al. 2015; Skemer et al. 2005).
A table summarising the area size, step size used and phase assemblages of the areas mapped by EBSD for calculation of grain size and plagioclase crystallographic orientation datasets is provided in the supplementary material (Table S1). A step size of 2–2.5 µm and a minimum size of 10 pixels was used for grain size, misorientation and orientation analysis for most of the amphibolite-facies samples, equating to a minimum grain diameter of 7.1–8.9 µm. For the granulite-facies samples a step size of 10 µm and a minimum size of 10 pixels was used. Grain size distributions are plotted in accordance with Cashman and Ferry (1988).
Results
Microstructural evolution of plagioclase across the outcrop
The aim of this section is to describe the textural evolution of plagioclase across the granulite – low strain amphibolite – high strain amphibolite transitions (Figs. 2 and 3). The microstructural classifications of granulitic (PlG) and secondary plagioclase (Pl1 and Pl2) are defined in this section and will be utilised throughout the remainder of this contribution.
PlG are medium-sized (500 µm – 5 mm, average; ~ 1.5 mm), typically optically clear grains with uniform extinction, two intersecting sets of twins, and minor alteration along grain boundaries and few fractures (Fig. 3a). Pl1 is characterised as highly irregularly shaped substructured grains, up to 200 µm in diameter (Fig. 4), with abundant zoisite and kyanite inclusions and partially retained PlG twin orientations (Fig. 3e). Pl2 is characterised by rounded to polygonal grains with zoned extinction (Fig. 3f–h) and a variable but fine grain size (5–150 µm; Fig. 4).
In the altered granulite Pl1 is the dominant plagioclase microstructure. PlG twinning remains evident despite grains containing a high density of zoisite inclusions (Fig. 3b). Zoisite inclusions are particularly concentrated around intragranular fractures and grain boundaries (Fig. 3b), where plagioclase becomes optically turbid. Micron-scale patchy extinction of the plagioclase around fractures and inclusions (Fig. 3b) indicates partial grain size reduction of plagioclase, marking the transformation from PlG to Pl1.
Around fractures in the granulite there are two secondary plagioclase microstructures evident, Pl1 and Pl2 (Fig. 3c and d). Pl1 occurs adjacent to fractures, is optically turbid, and hosts abundant zoisite and kyanite inclusions (Fig. 3c and d). In fractures crosscutting Pl1, Pl2 forms bands of abundant fine (< 50 µm) to very fine (5–20 µm) grains (Fig. 4).
In the low strain amphibolite, there are again two secondary plagioclase microstructures evident, Pl1 and Pl2. Pl1 is the dominant plagioclase microstructure in the low strain amphibolite while Pl2 is locally evident, forming bands of abundant fine (< 50 µm) grains (Fig. 4) that crosscut Pl1 (Fig. 3e).
In the high strain amphibolite and leucocratic domains (Fig. 3f–h) Pl1 is no longer present (Fig. 4). Pl2, while still polygonal, forms bands dominated by 50 – 150 µm grains (Fig. 4) that are elongate parallel to the foliation (Fig. 3f–h). In cross-polarised light images, inheritance of PlG orientation by Pl2 are evident within the shear zone (Fig. 3f), marked by distinct elongate lensoidal bands of Pl2 with similar extinction, indicating some precursor plagioclase grain control on orientation.
Relationship between plagioclase chemistry and microstructure
Combined WDS (Fig. 5a, c, e, g) and EBSD (Fig. 5b, d, f, h) analyses of Pl1 and Pl2 microstructures are presented to examine the spatial relationship between reaction and microstructure (Fig. 5). Plagioclase composition in WDS maps (Fig. 5a, c, e, g) is expressed in terms of anorthite content (XAn). Additionally, mineral orientations are examined to determine whether the precursor PlG has any crystallographic relationship with secondary Pl1 and Pl2 (Fig. 6).
In the altered granulite, PlG is partially transformed to Pl1. The composition of plagioclase in the altered granulite is mostly uniformly close to the PlG composition (PlG XAn = 0.58) (Fig. 5a). Transformation from PlG to Pl1 is marked by the occurrence of “complex” feldspar zoning, as described by Mukai et al. (2014). Here, complex zoning in Pl1 is reflected by compositional variations between XAn = 0.45 and XAn = 0.8 that are associated with inclusions, twin boundaries, discontinuous subgrain boundaries and discrete planes of misorientation visible in Grain Reference Orientation Deviation (GROD) maps (Fig. 5b). The average composition for the Pl1 map area of XAn = 0.53 (Fig. 5c) indicates that there is no addition of external Ca during the reaction from PlG to Pl1. Ca-enrichment associated with inclusions and subgrain boundaries is thus balanced by Ca-depletion in the substructure and inclusion free areas in Pl1. A high density of substructuring within Pl1 is further evidenced in the EBSD maps of fractures in the granulite (Fig. 6b and c). Subgrain boundaries are not associated with gradual lattice bending as indicated by the single uniform orientation of Pl1 grains (Fig. 6b and d). Further, the rotation axes of subgrain boundaries in Pl1 do not coincide with any of the rotation axes of the main slip systems known for plagioclase (Fig. 5i).
In Pl1 of the low strain amphibolite, areas of decreased XAn ≈ 0.3–0.5 occur within a network of intersecting planes of increased XAn ≈ 0.6–0.8 (Fig. 5c). Secondary phases (i.e., zoisite, quartz, and kyanite; Fig. 5b) are commonly associated with these areas of XAn enrichment. In the low strain amphibolite, planes of increased XAn in Pl1 again appear coincident with subgrain boundaries and discrete planes of misorientation (Fig. 5d). As in the altered granulite, subgrain boundaries in Pl1 of the low strain amphibolite are largely discontinuous and 2–5° rotation axes do not coincide with any of the rotation axis of the main slip systems known for plagioclase (Fig. 5j). Relict PlG twin boundaries are largely overprinted (Figs. 3d and 5d).
In the low strain amphibolite, Pl2 exhibits significant intragranular compositional variation ranging between XAn = 0.2 and XAn = 0.9 (Fig. 5e). In some instances, Pl2 grains exhibit clear concentric reverse zoning (e.g. XAn = 0.2 core and XAn = 0.9 rims). However, Pl2 grains also commonly exhibit discontinuous enriched areas and may lack low XAn cores. Pl2 in all lithologies are typically substructure-free grains (Figs. 5f, h and 6c). Further, grain and subgrain boundaries show no spatial correlation with compositional variations in Pl2 (Fig. 5e–h). This is further evident in the high strain amphibolite, where large variations in XAn (0.25–0.9) are observed in the absence of substructuring and zonation is truncated by grain boundaries (Fig. 5g and h).
Around fractures and in the static amphibolite, a large proportion of Pl2 [100]- and [010]-axes orientations are consistent with the orientation of host Pl1 grains (Fig. 6d, f, and g). However, some dispersion is observed, resulting in a “local” CPO. In both the fracture and the amphibolite up to 60° of dispersion of Pl2 orientations away from the host Pl1 occurs.
Relationship between plagioclase fabric and reaction extent
In this section representative areas depicting individual original PlG grains across the outcrop are described for the purpose of comparing changes in fabric, shape, and degree of reaction across the granulite to low strain amphibolite to high strain amphibolite transitions (Fig. 7).
The degree of plagioclase hydration is approximated for each lithology using the following reaction.
This reaction is a simplification, particularly given the complex plagioclase compositions that are associated with the amphibolite-facies reaction (Fig. 5). However, given that zoisite is a hydrous phase that is always spatially associated with the modification of plagioclase composition (e.g., Fig. 3d and h) we consider a reaction involving zoisite to be the best proxy for calculating the extent to which the hydration reaction has affected plagioclase. Using this reaction and PlG and zoisite molar volumes, the amount of plagioclase required to produce the amount of zoisite in the amphibolite-facies can be estimated. This estimation is here called the reaction extent and is reported as a percentage of plagioclase (PlG) needed to produce the amount of zoisite locally present. For the exact method of calculation and the data shown in Fig. 7(i–ii) see Table S2.
The reaction extent is compared with the M index (misorientation index; Skemer et al. 2005) of individual plagioclase clusters in Fig. 7(ii). The M index is a measure of fabric strength, based on the difference between the observed distribution of random-pair misorientation angles and the theoretical random distribution of random-pair misorientation angles (Fig. 7(iii)). Thus, a random fabric will have an M index of 0 and a single crystal will have a M index close to 1.
PlG in the granulite has experienced only minor amounts of hydration (< 1%) and generally has a low aspect ratio (~ 1–2) and little internal deviation in orientation (Figs. 5; 7a (i–ii; M index = 0.9)). The reaction extent of individual clusters of plagioclase examined in the low strain amphibolite varies from < 1–5% (Fig. 7(ii)). In the low strain amphibolite clusters of Pl1, which exhibit a similar orientation, have aspect ratios in the same range as PlG (~ 1–2; Fig. 7b), a restricted local orientation spread (M index = 0.92; Fig. 7b (i)), and a reaction extent of 5%. The orientation spread of Pl1 alone is only slightly weaker than that of PlG, which is consistent with a single crystal orientation with minor spread due to slight misorientations between small areas (cf. Fig. 6c). Clusters of Pl1 and Pl2 have aspect ratios like that of PlG (~ 1–5; Fig. 7c). However, compared to isolated Pl1 clusters, combined Pl1 and Pl2 areas exhibit a considerably weaker fabric strength (M index = 0.46–0.82; Fig. 7 (i)) and a lesser reaction extent (0.4–2.3%; Fig. 7(ii)).
The reaction extent of plagioclase in the shear zone lithologies is highly variable, ranging from 1–3% in the high strain amphibolite (Fig. 7d(ii)) to 4–65% in the leucocratic domains (Fig. 7e(ii)). While Pl2 clusters have in general a higher aspect ratio (4.5–13) their fabric is weaker (M index = 0.24–0.57; Fig. 7(i)), and there appears to be no systematic relationship between reaction extent and the aspect ratio or fabric strength of Pl2 in the shear zone lithologies.
The dispersion of crystal orientations in Pl2 clusters relative to PlG grains, as represented by the M indexes, is further demonstrated in the misorientation angle distributions (MAD) (Fig. 7(iii)). The random pair misorientation distribution for Pl1 exhibits a single strong peak at low angles (~ 10–30°). For areas representing a combination Pl1 and Pl2 there are two weaker peaks, one at low angles (~ 10–40°) and one at high angles (~ 150–180°). Finally, in Pl2 there are two broad peaks around low-moderate (~ 20–80°) and high (~ 130–180°) angles.
Comparison of bulk plagioclase fabric
Pole plots of plagioclase orientations shown in Fig. 8 exhibit all acquired points, sampled from the EBSD map data at 10 µm intervals, so that the data is equivalently area-fraction weighted for each of the samples. This approach enables an area-weighted comparison of the strength and characteristic of all indexed plagioclase orientations in the granulite versus the shear zone rocks, allowing for an assessment of the change in the overall difference in plagioclase fabric strength between the two lithologies. In addition, orientation data has been rotated so that it is plotted in respect to the SZB, to allow for easy comparison between samples.
Based on 235 individual PlG grains, plagioclase in the granulite does not exhibit a clear CPO when contoured at a halfwidth of 10° (Fig. 8a(i)) even though some CPO is seen for (001). Plagioclase orientation data in the shear zone lithologies represents 45 clusters of Pl2, each cluster is interpreted to reflect an individual precursor PlG grain. When the granulite plagioclase data is smoothed, the smoothed (20° halfwidth) orientations exhibit a similar fabric to Pl2 of the shear zone lithologies (Fig. 8a(ii) and b). Both exhibit weak (010)-plane maxima subparallel to the SZB and weak (001)-plane maxima at 30–70° to the SZB, however the bulk CPO in the shear zone is weaker.
Discussion
Brittle fracturing and replacement of PlG
Previous work on the textural and mineralogical associations of this outcrop has established that the reaction from PlG to Pl1 is accomplished primarily via interface-coupled dissolution–precipitation reactions at ca. 720 °C and 10–14 kbar (Moore et al. 2020a). This interpretation is supported by the observation of microstructures in Pl1 that are typical of dissolution–precipitation such as the inheritance of crystallographic orientation (Fig. 6d), discontinuous subgrain boundaries, and inconsistency between 2–5° rotation axes and plagioclase crystallographic axes directions (Fig. 5b, d) (Spruzeniece et al. 2017).
The brittle behaviour of PlG associated with fracturing is evidenced by the shared orientation of Pl1 grains on either side of the fracture and fragment-like Pl1 included within the fracture plane (Fig. 6a–c). Calcium enrichment along subgrain boundaries and discrete lines of misorientation in Pl1 (Fig. 5a–d) is consistent with previous observations of annealed brittle fractures in plagioclase (Petley-Ragan et al. 2020; Petley‐Ragan et al. 2018; Pittarello et al. 2008). Therefore, we infer a strong association between fracturing and reaction during the transformation of PlG to Pl1. This brittle behaviour of PlG may also explain the orientation inheritance exhibited by Pl2 (Figs. 6 and 7). If PlG underwent comminution during fracturing, the resulting grain fragments may have acted as seeds for growth of Pl2.
Deformation mechanism in the shear zone
The following observations, consistent with previous work (Marti et al. 2018; Mukai et al. 2014; Stünitz et al. 2020), support dissolution–precipitation creep as the primary mechanism for Pl2 deformation in the shear zone lithologies:
-
1.
A weak to random CPO of Pl2 in the shear zone (Fig. 8b) that is unfavourably oriented for slip on the dominant plagioclase slip system ((010) < 001 > ; Ji and Mainprice 1988; Kruse et al. 2001; Stünitz et al. 2003; Svahnberg and Piazolo 2010), and is not apparently related to the kinematic framework defined by the foliation and lineation.
-
2.
Grains show very little systematic internal orientation changes (Figs. 5b, d and 6d), which would be expected if dislocation creep was dominant (e.g., Kruse et al. 2001; Svahnberg and Piazolo 2010).
-
3.
Truncation of the Pl2 anorthite zoning by grain boundaries oriented parallel to the shear zone (SA) foliation (Fig. 5g), suggesting preferential dissolution of Pl2 grains parallel to the principal shortening axis.
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4.
The polygonal, slightly elongate (Fig. 7d and e), shape and small grain size (5–150 µm) of Pl2 grains in the shear zone lithologies (Fig. 3f, g), allowing for a grain size-dependent creep mechanism, such as dissolution–precipitation creep, to be dominant.
Here, we suggest another potential microstructural indicator of dissolution–precipitation creep in plagioclase:
-
5.
The preservation of distinct bands of similar orientation representing parent plagioclase (PlG) grains. In this instance, resulting in a weak inherited CPO in elongated Pl2 clusters of shear zone lithologies (Figs. 6 and 7).
This microstructure has previously been attributed to diffusion creep assisted by grain boundary sliding at greenschist-facies conditions (Jiang et al. 2000; Wheeler et al. 2001). Those authors also observe a weakening of fabric and a shift in the MAD peak towards higher angles within individual parent grain domains with increasing strain (Fig. 7(ii)), supporting progressive dispersion of crystal axes by a grain boundary sliding mechanism. Grain boundary sliding evident here by both the dispersion of fabric within Pl2 clusters representing original PlG grains and the dominance of small, polygonal grains in the shear zone lithologies (Fig. 7). However, we favour a dissolution–precipitation rather than diffusion creep mechanism as the increase of hydration reaction products with strain (Fig. 7(i)) indicates that deformation occurred in the presence of fluid. Consequently, identifying the dominant mechanism as dissolution–precipitation creep, which is a mechanism that is enabled by the presence of grain boundary fluid, as the appropriate mechanism is more appropriate than the use of the generalised diffusion creep term.
Therefore, the Pl1 microstructure in the low strain amphibolite represents dissolution–precipitation reaction without shear localisation (i.e., the hydration transition) while Pl2 in the high strain amphibolite and shear zone lithologies represents reaction with shear localisation (i.e., the deformation transition) and successive dissolution–precipitation creep assisted by grain-boundary sliding. In the following, the plagioclase microstructures across the hydration-deformation transitions are discussed to determine which are the important factors for determining the occurrence of shear localisation.
Shear zone initiation
In our previous work (Moore et al. 2020a) we suggested that two reaction zones can be distinguished at the hydration transition based on reaction textures and calculated H2O activity for the mineral assemblages: type 1 zones exhibit limited permeability and thus limited mass transport, and type 2 zones are characterized by high permeability and thus enhanced mass transport.
In type 1 zones reactions proceed by near pseudomorphic replacement of the granulite-facies assemblage by the amphibolite-facies assemblages, such as the replacement of PlG by Pl1 (e.g., Fig. 3b). Pseudomorphic reaction textures indicate that the dissolution and precipitation steps of the reaction remained coupled at the grain-scale reaction interface (Putnis 2002, Putnis et al. 2005). Further, the observed orientation inheritance of Pl1 replacing PlG (Fig. 6b and d) is consistent with an interface-coupled reaction mechanism. It has been demonstrated that where a crystallographically compatible host phase is present, the coupling of the dissolution and precipitation reaction steps at the interface allows for crystallographic information to be transferred from the parent to the product (Putnis et al. 2005; Ruiz-Agudo et al. 2014; Spruzeniece et al. 2017; Xia et al. 2009). However, the replacement is not always perfect, hence misorientations develop during such replacement reactions resulting in orientations that are slightly dispersed relative to the crystallographic orientation of the original grain (Spruzeniece et al. 2017). In this case, rotation axes are not related to specific slip systems, and are near random (e.g., Fig. 5i). Hydration reactions in low permeability zones (type 1 zones) thus occur predominantly via interface-coupled dissolution–precipitation reactions. In this study low permeability zones are represented by lithologies dominated by Pl1, such as the low strain amphibolite.
By contrast, amphibolite-facies minerals within intergranular fractures (e.g., Fig. 6a–c) and leucocratic domains of the shear zone are inferred to represent type 2 zones where dissolution and precipitation steps are decoupled allowing for mass transport at least at the grain scale (Moore et al. 2020a). As a result, reaction sites of dissolution and precipitation are not the same. In these zones, if far-field stresses are present, dissolution surface will be at high angle to the maximum stress axis and precipitation will occur in low stress areas. In this study, these higher permeability zones are represented by Pl2 dominated lithologies, i.e., those occurring in the shear zone. Type 1 zones of limited permeability thus coincide with lithologies that do not undergo significant creep, while type 2 zones of high permeability coincide with zones of strain localisation. The preservation of these two contrasting reaction textures implies that comparatively low and high permeability zones were present before or during reaction. We therefore suggest that grain size reduction resulting in higher permeability and allowing for fluid infiltration and weakening occurred prior to reaction.
In addition, there seems to be no dependency between reaction extent and fabric strength or aspect ratio in plagioclase clusters in either the low strain or the high strain amphibolite (Fig. 7(i–ii)). The fact that plagioclase in the low strain amphibolite undergoes a similar degree of hydration reaction as in the shear zone lithologies (Fig. 7(i)) but does not undergo any considerable deformation, indicates that the localisation of strain is not entirely dependent on reaction extent as may be expected from the reactive-weakening model of shear zone initiation.
The inference is that Pl2 microstructures are derived from PlG, dependent on the degree of damage from fracturing and syn-damage comminution, consistent with the cataclastic model of shear zone initiation. A progressive increase in Pl2 grain size from the fractures to the statically hydrated amphibolite and then finally the shear zone lithologies is predicted to occur due to surface energy-driven grain growth (Masuda et al. 1997; Pearce and Wheeler 2011) and is in agreement with previous observations of coarsening due to growth and recrystallisation after fracture-induced fragmentation (Menegon et al. 2013). This would lead to a more pronounced polygonal microstructure (Figs. 3f, g and 5f, h) and unimodal grain size distribution (Fig. 4). In summary, our observations support an original brittle origin for Pl2. Syn-imbrittlement comminution is followed by fluid influx causing reaction and surface energy-driven grain growth coupled with deformation dominated by dissolution–precipitation creep assisted by grain boundary sliding.
Thus, we propose a brittle origin for the formation of the shear zone in type 2 zones, represented by Pl2 microstructures, consistent with previous interpretations for the formation of shear zones in the dry lower crustal rocks of the Bergen arcs (Austrheim 1987; Austrheim and Engvik 1997; Jamtveit et al. 1990). Here shear localisation in plagioclase is the result of fracturing-induced grain size reduction (Brander et al. 2012; Okudaira et al. 2015). Grain size reduction and comminution results in localized high permeability and initial fluid influx (e.g., Fusseis and Handy 2008; Menegon 2015), which allows continued reaction, growth and deformation via dissolution–precipitation creep. In contrast, type 1 zones, represented by Pl1 microstructures, only experienced damage without comminution, allowing for fluid infiltration and reaction but not significant deformation.
Conclusions and implications
This study presents the apparent progression from plagioclase in dry, relatively undeformed anorthositic gabbro granulite to a plagioclase-rich shear zone rock that was deformed at conditions of ca. 720 °C and 10–14 kbar. The three representative plagioclase microstructures presented here represent the transformation from dry (PlG) to either hydrated (Pl1) or to fine-grained sheared plagioclase (Pl2). We observe no clear evidence for an evolution from Pl1 to Pl2. The lack of clear evidence for a progression through the plagioclase microstructures and the abundance of brittle microstructures in PlG and Pl1 suggests that Pl2 is formed by the brittle fracturing of PlG. The formation of Pl2, and thus the shear zone, via comminution of PlG is consistent with the inherited CPO in the shear zone, suggesting PlG fragments acted as seeds for Pl2 growth. The initial grain size reduction and comminution in the fracture damage zone creates a zone of higher permeability, which then allows for the infiltration of fluid and reaction. Fluid percolation and/or diffusion into the surrounding low permeability rock allows for reaction but not for the localisation of strain. Strain is localised within the area of initial high damage, consistent with the cataclastic model of shear zone formation. The shear zone morphology should thus be consistent with the morphology of the initial high damage zone.
We suggest that the following microstructures observed in Pl2 indicate that dissolution–precipitation creep, supported by grain boundary sliding, was the dominant mechanism of deformation in the shear zone:
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Local, inherited CPO, clearly indicated by distinct bands of similar orientation representing parent plagioclase grains.
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A bulk CPO that is weak to near random, and is unfavourably oriented for both slip on the dominant plagioclase slip system ((010) < 100 >) and in relation to the kinematic framework.
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Fine-grained (5–150 µm), slightly elongate, polygonal grains.
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Truncation of anorthite zoning.
Such plagioclase microstructures may therefore be used to identify where shear zone formation has occurred via brittle fracturing and subsequent dissolution–precipitation creep. In particular, the inheritance of distinct bands of similar orientation may be an important indicator of a cataclastic model of shear zone initiation.
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Acknowledgements
This manuscript has benefitted greatly from the suggestions of Holger Stünitz and an anonymous reviewer. This research was funded by the Australian Research Council Discovery Project of Putnis, Raimondo, and Daczko (ARC grant number DP160103449). The authors acknowledge the facilities, and the scientific and technical assistance of the Australian Microscopy and Microanalysis Research Facility at the Centre for Microscopy, Characterisation and Analysis, The University of Western Australia, a facility funded by the University, State and Commonwealth Governments. Part of this research was undertaken using the EM instrumentation (ARC LE130100053) at the John de Laeter Centre, Curtin University.
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Moore, J., Piazolo, S., Beinlich, A. et al. Brittle initiation of dissolution–precipitation creep in plagioclase-rich rocks: insights from the Bergen arcs, Norway. Contrib Mineral Petrol 179, 61 (2024). https://doi.org/10.1007/s00410-024-02141-0
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DOI: https://doi.org/10.1007/s00410-024-02141-0