Highlights
-
Flexible Zn-ion hybrid micro-supercapacitors (MSCs) array was fabricated with Ti3C2Tx as the cathode via laser direct writing method, which present ultrastability up to 50,000 cycles after in-situ annealed treatment.
-
A digital timer driven by the obtained single MSC under bending state, together with a flexible LED displayer of the “TiC” logo lighted by the MSC arrays under twisting, crimping and winding conditions demonstrate the great potential application of the MSCs in integrated wearable electronics.
Abstract
Zn-ion hybrid supercapacitors (SCs) are considered as promising energy storage owing to their high energy density compared to traditional SCs. How to realize the miniaturization, patterning, and flexibility of the Zn-ion SCs without affecting the electrochemical performances has special meanings for expanding their applications in wearable integrated electronics. Ti3C2Tx cathode with outstanding conductivity, unique lamellar structure and good mechanical flexibility has been demonstrated tremendous potential in the design of Zn-ion SCs, but achieving long cycling stability and high rate stability is still big challenges. Here, we proposed a facile laser writing approach to fabricate patterned Ti3C2Tx-based Zn-ion micro-supercapacitors (MSCs), followed by the in-situ anneal treatment of the assembled MSCs to improve the long-term stability, which exhibits 80% of the capacitance retention even after 50,000 charge/discharge cycles and superior rate stability. The influence of the cathode thickness on the electrochemical performance of the MSCs is also studied. When the thickness reaches 0.851 µm the maximum areal capacitance of 72.02 mF cm−2 at scan rate of 10 mV s−1, which is 1.77 times higher than that with a thickness of 0.329 µm (35.6 mF cm−2). Moreover, the fabricated Ti3C2Tx based Zn-ion MSCs have excellent flexibility, a digital timer can be driven by the single device even under bending state, a flexible LED displayer of “TiC” logo also can be easily lighted by the MSC arrays under twisting, crimping, and winding conditions, demonstrating the scalable fabrication and application of the fabricated MSCs in portable electronics.
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
1 Introduction
To meet the demands of flexible and wearable devices including various sensors, detectors, transistors, memristors, etc., the matched energy storage must satisfy both the external requirements of miniaturization, patterning, integration, and comfortableness and internal needs of the superior charge storage capability [1,2,3,4,5]. Excluding the harmful fuel cells, capacitive-type electrode-based supercapacitors (SCs) and diffusion-type electrode-based batteries present their own merits and demerits. Alternatively, metal-ions hybrid SCs could exert the strength of high power density, security, and outstanding stability coming from SCs as well as excellent energy density derived from battery [6,7,8]. Flexible Zn-ion hybrid supercapacitors (SCs) that consist of the flexible substrate, Zn anode, functional cathode as well as gel electrolyte have garnered significant interest owing to their high specific capacity of 823 mAh g−1, the low redox potential of − 0.76 V (vs. standard hydrogen electrode), stability, natural abundance, and non-pollution compared to other metal-ion hybrid SCs [9,10,11]. Functional cathode as the key component affects the electrochemical performance of Zn hybrid SC the most [12,13,14]. 2D transition-metal carbides and nitrides (MXenes) with the general formula Mn+1XnTx, where M is an early transition metal, X represents carbon and/or nitrogen, Tx stands for hydroxyl (–OH), oxygen (–O), or fluorine (–F) termination, n = 1–4 [15], that possesses the features of high conductivity, excellent flexibility, adjustable chemistry, and scalability since the first found in 2011 [16], are widely used in the area of transistors [17], sensors [18, 19], electromagnetic interference shielding [20], catalysis [21], adsorbents [22], particularly in the high-performance energy storage field like photovoltaic cell, metal-ion battery, SCs [23, 24].
Large-scale and efficient manufacturing technology is of great significance to fabricate flexible Zn-ion hybrid SCs and solve the mass production problem. In comparison with the printed process, laser direct writing method of functional materials has been demonstrated the universal adaptability, facility and variable-area patterns with high-resolution, which have no requirement for the solvents, the utilization of binder, additives and the adjustment of the viscosity, surface tension, and wettability of the materials to be processed [25]. Up to now, many high-performance energy storage devices have been developed using laser direct writing technology. For instance, Liu et al. [26] provided an active carbon-based flexible planar interdigitated solid-state supercapacitors based on active carbon electrodes (areal specific capacitance up to 34.7 mF cm−2 at the current density of 0.1 mA cm−2) by employing laser writing methods, but the addition of silver paint current collector complicate the fabrication process. Peng and co-workers [27] reported on an all-Ti3C2Tx MXene-based solid-state interdigital micro-supercapacitors (MSCs) via laser cutting technology, high conductive Ti3C2Tx MXene with large size serve as current collector deeply simplified manufacturing process. However, Ti3C2Tx MXene as cathode material in the design of Zn-ion hybrid SCs suffers from poor cycling performance and rate stability, more efforts should be continuously devoted to solving these problems.
Combing the Ti3C2Tx cathode and low-cost laser writing manufacturing routes, we provided in-suit annealed the fabricated all-solid-state flexible Zn-ion hybrid MSCs on the polyimide substrate at 300 °C for 30 min in Ar atmosphere, showing ultrastability up to 50,000 cycles owing to the removal of the surface oxygen-containing group and the formation of the micropores in Ti3C2Tx structures. To maximize Ti3C2Tx cathode utilization, the optimal thickness of electrodes was discussed in this work. The assembled flexible Zn-ion hybrid MSCs after annealed treatment exhibited the maximum areal capacitance of 72.02 mF cm−2 at scan rate of 10 mV s−1 with a thickness of 0.851 µm (662.53 F cm−3), and provided a power density of 0.50 mW cm−2 at an area energy density of 0.02 mWh cm−2. The flexible MSCs with different patterns and series/parallel combinations also were designed. A digital timer driven by the obtained single MSC under bending state, together with a flexible LED displayer of “TiC” logo lighted by the MSC arrays under twisting, crimping and winding conditions proved the superior performance of the fabricated devices, opening up the way for the feasible prototype of scalable high-performance MSCs fabrication and enhancing the application forms of the MSCs devices in integrated wearable electronics.
2 Experimental Section
2.1 Material Synthesis
2.1.1 Materials
Ti3AlC2 MAX was purchased from Carbon-Ukraine. Hydrofluoric acid (HF, 40%), hydrochloric acid (HCl, 9 M), lithium chloride (LiCl, 99%), Zinc chloride (ZnCl2, 99%) were procured from Aladdin Industrial Inc. Polyvinylalcohol (PVA; MW = 70,000–100,000) was provided by Himedia Laboratories Pvt. Ltd., and polyimide (PI) substrate was supplied by Dupont. Kapton, poly-(dimethylsiloxane) (PDMS) was obtained from SYLGARD 184 Silicone Elastomer Base and Curing Agent. Double distilled water was used for all the experiments. All chemicals were used directly without further purification.
2.1.2 Mono or Fewer Layer Ti 3 C 2 T x MXene
The selective etching method was carried out according to our previous work. In the typical process, 1.5 g of Ti3AlC2 MAX phase was slowly added into a mixture of 13.5 mL deionized (DI) water, 13.5 mL HCl (9 M), and 3 mL HF, and stirred at room temperature for 24 h. The sediment was washed with DI water several times until the pH value reached neutral, then dried at 80 °C for 12 h under vacuum to obtain multi-layer Ti3C2Tx MXene. Subsequently, 1 g of multi-layer Ti3C2Tx MXene was added into 15 mL DI water containing 1.5 g of LiCl under vigorous stirring at room temperature for 12 h. The Ti3C2Tx suspension with large size was washed with DI water several times and collected by centrifugation at 3500 rpm for 5 min assisted by handshaking, while small-sized Ti3C2Tx MXene was obtained after sonication treatment.
2.2 Fabrication Process
2.2.1 Fabrication of Patterned MSCs
The cleaned PI (Kapton HN, DuPont, 100 µm) substrate was put into plasma cleaner for 5 min to enhance the hydrophility and wettability. Then, the large-sized Ti3C2Tx suspension with a concentration of 3 mg mL−1 was spread on the PI substrate and dried at 80 °C for 20 min under vacuum. After that, a laser direct writing process (Power, 20 W) was performed to pattern the electrodes. The patterns were cut by four times. The number of device arrays and the electrode structure can be designed by the preset pattern.
2.2.2 Fabrication of Patterned MSCs
Zn anode was directly obtained via electrodeposition process. A three-electrode system for electrodeposition that consists of the patterned large-sized Ti3C2Tx as the working electrode, a Pt plate as the counter electrode, and Hg/HgO electrode as the reference electrode was employed. The electrolyte aqueous was prepared by adding 0.09 M of Na2SO4, 0.045 M of ZnSO4·7H2O and 0.05 M of H3BO3 to 30 mL DI water. A constant voltage of − 1.5 V for 1 min was applied to prepare Zn film. Afterward, another Ti3C2Tx electrode was coated with small-sized Ti3C2Tx as active materials several times (labeled as layer count). The fabricated devices were then annealed at 300 °C for 30 min in Ar atmosphere and naturally cooled down to remove surface group and improve the stability. Finally, the devices were encapsulated by the transparent and ultrathin PDMS film after spreading the PVA/ZnCl2 gel electrolyte.
2.2.3 Preparation of Gel Electrolyte
The PVA/ZnCl2 gel electrolyte was prepared by adding 3 g PVA and 6 M ZnCl2 in 30 mL DI water with stirring at 98 °C for 30 min until the solution became clear.
2.3 Characterization
The electrochemical performances of the assembled micro Zn-ion supercapacitors were measured by the CHI 760D electrochemical workstations. The surface morphology of the multi and monolayer Ti3C2Tx MXene was investigated via the scanning electron microscopy (SEM) system (NANOSEM 650-6700F) and transmission electron microscopy (HRTEM; JEOLJEM-2010HT). The crystallinity of the prepared samples was collected by powder X-ray diffraction (Rigaku D/Max-2550). The surface morphology and thickness of single Ti3C2Tx flakes were observed by AFM (Bruker Multimode 8). The thickness of the Ti3C2Tx film was conducted by a step profiler (Dektak XT, Bruker, Billerica, MA, USA).
3 Results and Discussion
3.1 Material Characterizations
The structural and morphological characterizations of the synthesized Ti3C2Tx materials are revealed in Fig. 1. Figure 1a shows the SEM image of the multi-layer Ti3C2Tx MXene, where the typical accordion-like structures produced by the HCl/HF etching method can be found [28]. The delamination process is then carried out to obtain monolayer or few-layer MXenes flakes using Li+ metal cations intercalation, the prepared 2D large-sized Ti3C2Tx materials assisted with handshaking can be seen in Fig. 1b. Figure 1c depicts the corresponding mapping images of Ti and C elemental magnified in the selected areal of Fig. 1b. It can be seen from the dot mapping images of the elements that C and Ti uniformly distribute in the 2D Ti3C2Tx nanosheets. The large-sized Ti3C2Tx nanosheets (lateral size > 5 µm) with high conductivity and fewer defects are an excellent candidate for the current collector, while the small-sized Ti3C2Tx flakes with abundant surface defects after the sonication treatment possess better electrochemical performance. Figure 1d exhibits the TEM image of the sonicated Ti3C2Tx flakes. Obviously, the Ti3C2Tx flakes showed an average lateral size of 1 µm. The atomic force microscope (AFM) image (Fig. S1) was provided to show the thickness of the single Ti3C2Tx flakes. Based on Fig. S1, we can see the thickness is about 3.54 nm. The crystallinity and phase composition of the multi-layer, monolayer Ti3C2Tx nanoflakes with large and small size is presented in Fig. 1e. The (002) peaks for the monolayer Ti3C2Tx MXene are located at ~ 6.7° and shifted to the left compared to multi-layer Ti3C2Tx MXene because of the existence of water molecules between MXene flakes [29]. Combined with the morphology and XRD results, it can be concluded that the monolayer Ti3C2Tx MXene is successfully produced.
Figure 1f displays the laser writing manufacturing process of the Ti3C2Tx MXene-based Zn-ion hybrid MSCs on the flexible PI substrate. The spin-coated large-sized Ti3C2Tx current collector was produced according to the designed pattern. Subsequently, the Zn anode was prepared via the electrochemical deposition method. Then, the small-sized Ti3C2Tx cathode with various thicknesses was sprayed. Finally, PVA/ZnCl2 gel electrolyte was spread on the devices. The digital photo of the Ti3C2Tx suspension is displayed in Fig. 1g (left). The MSC arrays (4 in parallel) could be directly attached to the fingernail, exhibiting the wearable features and easy integration in the flexible electronics.
3.2 Device Fabrication
Figure 2a depicts the digital image of various fine-patterned MXene electrodes, such as “USTB” “CAS” “Flextronics” “Institute of semiconductor” words on a transparent PET substrate (size 3 × 3 cm2), showing the universal adaptability of the laser writing method. A cartoon MSC was also fabricated to prove the quick and easy fabrication process. We also prepared a Zn-ion MSC with butterfly-shaped, one wing was deposited with Zn, which demonstrates the possibility to design the MSC based on the wearable electric apparatus. The energy density can be controlled by the series/parallel-multiple connection, as shown in the bottom right corner of Fig. 2a. The optical microscope image of the planar concentric circular Zn-ion hybrid MSC is displayed in Fig. 2b. A legible track with a width of 100 μm divides the Zn anode and Ti3C2Tx cathode. To improve the Ti3C2Tx cathode utilization, the optimal thickness of electrodes was discussed in Fig. 2c. Obviously, as the deposited Ti3C2Tx layers increase, the areal capacitance of the fabricated Zn-ion hybrid MSC is increased first, and then decreased when the layer count reaches 6. The thickness of the Ti3C2Tx cathode with increased layer count was then measured by the step profiler, as displayed in Fig. 2d. The optimum average thickness is about 1.087 µm, which is used as the standard in the following MSC devices fabrication process.
3.3 Electrochemical Performances Analysis
The electrochemical performances of the fabricated Ti3C2Tx-based concentric circular Zn-ion hybrid MSC were systematically gathered, as shown in Fig. 3. Figure 3a displays the CV curves of the fabricated MSCs without annealing treatment at the scan rates ranging from 10 to 120 mV s−1. The CV curves exhibited a quasi-rectangular shape in a voltage window of 1.4 V at low scan rates and the small humps during both the cathodic and anodic sweeps should be contributed to the insertion and ejection of Zn-ion. The GCD curves at various current densities rates from 0.5 to 3 mA cm−2 are exhibited in Fig. S2a. The triangular shape of the GCD curve is typical of capacitive and reversible electric double layer capacitive behavior. High areal specific capacitance of 112 mF cm−2 was obtained at a scan rate of 10 mV s−1 (Fig. S2b). The rate capability of the fabricated Zn-ion hybrid MSCs with gradually increased current is displayed in Fig. S2c. No noticeable decrease after 40 times of continuous cycling at varied current densities ranging from 0.5 to 3 mA cm−2 can be seen. However, after 50,000 charge–discharge cycles, only ~ 54.7% value of its initial capacitance remained for the fabricated devices. Hence, the MSC was annealed at 300 °C for 30 min in Ar atmosphere to remove the surface group and improve the cycling stability.
The CV profiles of the annealed Ti3C2Tx-based Zn-ion hybrid MSCs are revealed in Fig. S3a, which are quite similar to those of the MSCs without treatment, demonstrating the thermal treatment has no damage to the structure of the Ti3C2Tx cathode. To explore the hybrid kinetics of the annealed hybrid MSCs, the separated capacitive current and diffusion current is displayed in Fig. 3b [30]. 58.7% of the total current came from the capacitive-controlled process at a scan rate of 50 mV s−1, which increased to 76.9% when the scan rate increases to 120 mV s−1 (Fig. 3c). The GCD curves of the annealed hybrid MSCs in Fig. 3d exhibit the same triangular shape. The compared areal capacitance of the MSCs with or without annealing treatment (Fig. S3b) shows that, with the scan rate increased, the capacitance of the annealed hybrid MSCs goes near to that of the MSCs without treatment. Another important reason that caused the capacitance reduction for the annealed hybrid MSCs is the lack of the cycling activation process, which will be discussed later. The highest capacitances based on the CV curves were calculated to be 72.02 mF cm−2 at a scan rate of 10 mV s−1, and 662.53 F cm−3, respectively, as shown in Figs. 3e and S3c. The comparison of energy and power densities of our devices and other types of SCs was plotted in the Ragone plot in Fig. 3f. Our devices delivered the largest areal energy density of 0.02 mWh cm−2 at an area power density of 0.50 mW cm−2, the largest volume energy density volume of 0.18 mWh cm−3 at a volume power density of 0.024.63 mWh cm−3 (Fig. S3d), which is much higher that of TiO2//Li hybrid SCs (6.94 µWh cm−2, 0.20 mW cm−2) [31], Zn//MXene hybrid SCs (7.53 µWh cm−2, 0.90 mW cm−2) [32], I-Ti3C2Tx SCs (2.8 µWh cm−2, 0.17 mW cm−2) [33], Ti3C2Tx MSCs (1.37 µWh cm−2, 0.16 mW cm−2) [27], and MXene@rGO MSCs (1.6 µWh cm−2, 0.07 mW cm−2) [34]. The cycling stability (Fig. 3g) was also measured to highlight the ultrastability of the annealed devices, which remains ~ 80% value of its initial capacitance after 50,000 galvanostatic charge/discharge cycles, the active process can be clearly seen from the figures, which is caused by the removal of the surface oxygen-containing functional group and the formation of the micropores in Ti3C2Tx structures. Moreover, electrochemical impedance spectra (EIS) of the annealed devices (Fig. S4) show a low resistance of 47 Ω owing to the high conductivity of the Ti3C2Tx cathode.
3.4 Investigation of the Charge Storage Mechanism
To further understand the charge storage mechanism of the Ti3C2Tx-based Zn-ion hybrid MSC, we provide the schematic illustration of the mechanism, as displayed in Fig. 4a. During the discharge process, Zn transforms to Zn2+ and moves from anode to cathode, then intercalates into the Ti3C2Tx layers or adsorbs on the surface of the Ti3C2Tx cathode. When the MSC device charges, the procedure is the inverse of the above process. This mechanism is also demonstrated by the in/ex-situ SEM and XRD analysis. Figures 4b, c and S5 show the SEM image of the Ti3C2Tx cathode and the corresponding homogeneous Zn, C, Ti element dispersion in the Ti3C2Tx cathode after charging, proving the insertion/adsorption of the Zn2+ in the Ti3C2Tx cathode. The ex-situ XRD analysis (Fig. 4d–f) is then presented to further explain the charge storage mechanism. From the XRD patterns, we can see when the voltage changes from 1.4 to 0 V, the characteristic peak (002) of Ti3C2Tx cathode at 6.7° gradually shifts to the left, revealing the interlayer space becomes wider, which means Zn2+ intercalates into the interlayer of the Ti3C2Tx cathode. Instead when the device charges from 0 to 1.5 V, the characteristic peak gradually shifts to the initial position. This reversible charge/discharge process ensures the outstanding cycling performance of the fabricated devices.
3.5 Flexibility and Application of the Fabricated MSC Arrays
Owing to the utilization of the flexible PI substrate and all-solid-state PVA/ZnCl2 gel electrolyte, the assembled Ti3C2Tx-based Zn-ion MSC presents the superior flexibility, as shown in Fig. 5a. The CV curves of the MSC devices reveal nearly constant shape when the bending state varies from 0° to 180°, showing excellent mechanical stability. The rate stability of the devices after bending for 500 times at each current density in Fig. 5b shows 95.1% of the initial value, which possesses great potential in the fast-charged Zn-ion hybrid MSCs. Figure 5c displays the optical photographs of the digital timer powered by a single Ti3C2Tx-based Zn-ion hybrid MSC under a flat and bending state. The real-time video (Movie S1) demonstrates the digital timer can work continuously for more than 5 min under repetitive bending-flat state, showing an intuitive application in wearable devices and providing new design ideas for the flexible devices. The stability of the Ti3C2Tx-based Zn-ion hybrid MSC under different bending times is also measured, as shown in Fig. 5d. The nearly invariable areal capacitance after bending for 1000 times under each bending state reveals non-reducing capacitance, suggesting its excellent flexibility. The inset shows the digital photos of the fabricated MSCs fixed on the 1D platform from the original state to different bending states. To enlarge the output potential and energy density of the fabricated MSCs, two MSCs connected in series and parallel were designed, respectively, as shown in Fig. 5e, which showed double output voltage or current with the same scan rate. Figure 5f shows the flexible LED array of the “TiC” logo that was lighted by the MSCs array. It can be seen that the LED array even can be powered under various types of deformations like twisting, crimping, and winding. The corresponding real-time video is provided in Movies S2 and S3, providing robust support for the flexible displays or functional wearable and portable electronics.
4 Conclusions
In summary, a high-performance flexible Zn-ion hybrid MSC constructed by a Ti3C2Tx cathode and low-cost laser writing manufacturing routes has been successfully fabricated. The cycling stability of the prepared MSCs was greatly improved because of the in-suit annealed treatment at 300 °C for 30 min in Ar atmosphere, which showed robust cycling stability with 80% of the capacitance retention even after 50,000 charge/discharge cycles. The obtained flexible Zn-ion hybrid MSCs after annealed treatment exhibited a high areal capacitance of 72.02 mF cm−2 at a scan rate of 10 mV s−1 with a thickness of 0.851 µm, (662.53 F cm−3), and provided a power density of 0.50 mW cm−2 at an area energy density of 0.02 mWh cm−2. A digital timer can be driven by the single MSC even under bending state, a flexible LED displayer of the “TiC” logo was lighted by the prepared MSC arrays under different deformations, which demonstrated the high-performance of the fabricated MSCs and provided great potential applications in the next-generation portable electronics and devices.
References
L. Li, Z. Lou, D. Chen, K. Jiang, W. Han et al., Recent advances in flexible/stretchable supercapacitors for wearable electronics. Small 14, e1702829 (2018). https://doi.org/10.1002/smll.201702829
C.G. Núñez, W.T. Navaraj, E.O. Polat, R. Dahiya, Energy-autonomous, flexible, and transparent tactile skin. Adv. Funct. Mater. 27, 1606287 (2017). https://doi.org/10.1002/adfm.201606287
H. Sun, Y. Zhang, J. Zhang, X. Sun, H. Peng, Energy harvesting and storage in 1d devices. Nat. Rev. Mater. 2, 17023 (2017). https://doi.org/10.1038/natrevmats.2017.23
B. Yao, J. Zhang, T. Kou, Y. Song, T. Liu et al., Paper-based electrodes for flexible energy storage devices. Adv. Sci. 4, 1700107 (2017). https://doi.org/10.1002/advs.201700107
M. Zhu, Y. Huang, Y. Huang, H. Li, Z. Wang et al., A highly durable, transferable, and substrate-versatile high-performance all-polymer micro-supercapacitor with plug-and-play function. Adv. Mater. 29, 1605137 (2017). https://doi.org/10.1002/adma.201605137
D. Chen, M. Lu, B. Wang, R. Chai, L. Li et al., Uncover the mystery of high-performance aqueous zinc-ion batteries constructed by oxygen-doped vanadium nitride cathode: cationic conversion reaction works. Energy Storage Mater. 35, 679–686 (2021). https://doi.org/10.1016/j.ensm.2020.12.001
J. Li, J. Cao, X. Li, H.M.K. Sari, L. Li et al., Superior full battery performance of tunable hollow N-doped carbonaceous fibers encapsulating Ni3S2 nanocrystals with enhanced Li/Na storage. Electrochim. Acta 332, 135446 (2020). https://doi.org/10.1016/j.electacta.2019.135446
S. Wu, Y. Chen, T. Jiao, J. Zhou, J. Cheng et al., An aqueous Zn-ion hybrid supercapacitor with high energy density and ultrastability up to 80000 cycles. Adv. Energy Mater. 9, 1902915 (2019). https://doi.org/10.1002/aenm.201902915
Y.F. He, P.P. Zhang, F.X. Wang, L.X. Wang, Y.Z. Su et al., Vacancy modification of Prussian-blue nano-thin films for high energy-density micro-supercapacitors with ultralow RC time constant. Nano Energy 60, 8–16 (2019). https://doi.org/10.1016/j.nanoen.2019.03.042
P. Yu, Y.X. Zeng, H.Z. Zhang, M.H. Yu, Y.X. Tong et al., Flexible Zn-ion batteries: recent progresses and challenges. Small 15, 1804760 (2019). https://doi.org/10.1002/smll.201804760
M. Song, H. Tan, D.L. Chao, H.J. Fan, Recent advances in Zn-ion batteries. Adv. Funct. Mater. 28, 1802564 (2018). https://doi.org/10.1002/adfm.201802564
H. Jia, Z.Q. Wang, B. Tawiah, Y.D. Wang, C.Y. Chan et al., Recent advances in zinc anodes for high-performance aqueous Zn-ion batteries. Nano Energy 70, 4523 (2020). https://doi.org/10.1016/j.nanoen.2020.104523
H. Wang, M. Wang, Y. Tang, A novel zinc-ion hybrid supercapacitor for long-life and low-cost energy storage applications. Energy Storage Mater. 13, 1–7 (2018). https://doi.org/10.1016/j.ensm.2017.12.022
F.Z. Cui, Z. Liu, D.L. Ma, L. Liu, T. Huang et al., Polyarylimide and porphyrin based polymer microspheres for zinc ion hybrid capacitors. Chem. Eng. J. 405, 1–8 (2021). https://doi.org/10.1016/j.cej.2020.127038
G. Deysher, C.E. Shuck, K. Hantanasirisakul, N.C. Frey, A.C. Foucher et al., Synthesis of Mo4VALC4 MAX phase and two-dimensional Mo4VC4 mxene with five atomic layers of transition metals. ACS Nano 14, 204–217 (2020). https://doi.org/10.1021/acsnano.9b07708
M. Naguib, M. Kurtoglu, V. Presser, J. Lu, J.J. Niu et al., Two-dimensional nanocrystals produced by exfoliation of Ti3ALC2. Adv. Mater. 23, 4248–4253 (2011). https://doi.org/10.1002/adma.201102306
J. Xu, J. Shim, J.H. Park, S. Lee, MXene electrode for the integration of WSe2 and MoS2 field effect transistors. Adv. Funct. Mater. 26, 5328–5334 (2016). https://doi.org/10.1002/adfm.201600771
L. Li, X. Fu, S. Chen, S. Uzun, A.S. Levitt et al., Hydrophobic and stable mxene-polymer pressure sensors for wearable electronics. ACS Appl. Mater. Interfaces 12, 15362–15369 (2020). https://doi.org/10.1021/acsami.0c00255
Y. Cheng, Y. Ma, L. Li, M. Zhu, Y. Yue et al., Bioinspired microspines for a high-performance spray Ti3C2Tx Mxene-based piezoresistive sensor. ACS Nano 14, 2145–2155 (2020). https://doi.org/10.1021/acsnano.9b08952
M.K. Han, C.E. Shuck, R. Rakhmanov, D. Parchment, B. Anasori et al., Beyond Ti3C2Tx: Mxenes for electromagnetic interference shielding. ACS Nano 14, 5008–5016 (2020). https://doi.org/10.1021/acsnano.0c01312
J. Zhang, Y. Zhao, X. Guo, C. Chen, C.-L. Dong et al., Single platinum atoms immobilized on an Mxene as an efficient catalyst for the hydrogen evolution reaction. Nat. Catal. 1, 985–992 (2018). https://doi.org/10.1038/s41929-018-0195-1
P. Srimuk, F. Kaasik, B. Krüner, A. Tolosa, S. Fleischmann et al., Mxene as a novel intercalation-type pseudocapacitive cathode and anode for capacitive deionization. J. Mater. Chem. A 4, 18265–18271 (2016). https://doi.org/10.1039/c6ta07833h
X. Xiao, H. Wang, P. Urbankowski, Y. Gogotsi, Topochemical synthesis of 2d materials. Chem. Soc. Rev. 47, 8744–8765 (2018). https://doi.org/10.1039/c8cs00649k
K. Li, M. Liang, H. Wang, X. Wang, Y. Huang et al., 3d Mxene architectures for efficient energy storage and conversion. Adv. Funct. Mater. 30, 2000842 (2020). https://doi.org/10.1002/adfm.202000842
C.J. Zhang, L. McKeon, M.P. Kremer, S.H. Park, O. Ronan et al., Additive-free Mxene inks and direct printing of micro-supercapacitors. Nat. Commun. 10, 1795 (2019). https://doi.org/10.1038/s41467-019-09398-1
C. Liu, H. Liang, D. Wu, X. Lu, Q. Wang, Direct semiconductor laser writing of few-layer graphene polyhedra networks for flexible solid-state supercapacitor. Adv. Electron. Mater. 4, 1800092 (2018). https://doi.org/10.1002/aelm.201800092
Y.-Y. Peng, B. Akuzum, N. Kurra, M.-Q. Zhao, M. Alhabeb et al., All-Mxene (2d titanium carbide) solid-state microsupercapacitors for on-chip energy storage. Energy Environ. Sci. 9, 2847–2854 (2016). https://doi.org/10.1039/c6ee01717g
B. Anasori, A. Sarycheva, S. Buondonno, Z.H. Zhou, S. Yang et al., 2d Metal carbides (mxenes) in fibers. Mater. Today 20, 481–482 (2017). https://doi.org/10.1016/j.mattod.2017.08.001
L. Li, D. Chen, G.Z. Shen, All-Ti3C2Tx MXene based flexible on-chip microsupercapacitor array. Chem. Res. Chin. Univ. 36, 694–698 (2020). https://doi.org/10.1007/s40242-020-0197-9
H. Zhou, C. Liu, J.-C. Wu, M. Liu, D. Zhang et al., Boosting the electrochemical performance through proton transfer for the Zn-ion hybrid supercapacitor with both ionic liquid and organic electrolytes. J. Mater. Chem. A 7, 9708–9715 (2019). https://doi.org/10.1039/c9ta01256g
S.K. Cheah, E. Perre, M. Rooth, M. Fondell, A. Harsta et al., Self-supported three-dimensional nanoelectrodes for microbattery applications. Nano Lett. 9, 3230–3233 (2009). https://doi.org/10.1021/nl9014843
N. Wang, J. Liu, Y. Zhao, M. Hu, R. Qin et al., Laser-cutting fabrication of Mxene-based flexible micro-supercapacitors with high areal capacitance. Chem. Nano Mat. 5, 658–665 (2019). https://doi.org/10.1002/cnma.201800674
C.J. Zhang, M.P. Kremer, A. Seral-Ascaso, S.-H. Park, N. McEvoy et al., Stamping of flexible, coplanar micro-supercapacitors using MXene inks. Adv. Funct. Mater. 28, 1705506 (2018). https://doi.org/10.1002/adfm.201705506
Y. Liu, J. Yu, D. Guo, Z. Li, Y. Su, Ti3C2Tx MXene/graphene nanocomposites: synthesis and application in electrochemical energy storage. J. Alloy. Compd. 815, 152403 (2020). https://doi.org/10.1016/j.jallcom.2019.152403
Acknowledgements
This work was supported by National Natural Science Foundation of China (51672308, 51972025, 61888102 and 62004187).
Author information
Authors and Affiliations
Corresponding authors
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
About this article
Cite this article
Li, L., Liu, W., Jiang, K. et al. In-Situ Annealed Ti3C2Tx MXene Based All-Solid-State Flexible Zn-Ion Hybrid Micro Supercapacitor Array with Enhanced Stability. Nano-Micro Lett. 13, 100 (2021). https://doi.org/10.1007/s40820-021-00634-2
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s40820-021-00634-2