Highlights
-
Animal- and human-inspired nanostructures as supercapacitor electrode materials are summarized.
-
Structural formation and supercapacitive electrochemical applications are comprehensively summarized.
-
Future outlooks such as large-scale production and other properties are proposed.
Abstract
Human civilization has been relentlessly inspired by the nurturing lessons; nature is teaching us. From birds to airplanes and bullet trains, nature gave us a lot of perspective in aiding the progress and development of countless industries, inventions, transportation, and many more. Not only that nature inspired us in such technological advances but also, nature stimulated the advancement of micro- and nanostructures. Nature-inspired nanoarchitectures have been considered a favorable structure in electrode materials for a wide range of applications. It offers various positive attributes, especially in energy storage applications, such as the formation of hierarchical two-dimensional and three-dimensional interconnected networked structures that benefit the electrodes in terms of high surface area, high porosity and rich surface textural features, and eventually, delivering high capacity and outstanding overall material stability. In this review, we comprehensively assessed and compiled the recent advances in various nature-inspired based on animal- and human-inspired nanostructures used for supercapacitors. This comprehensive review will help researchers to accommodate nature-inspired nanostructures in industrializing energy storage and many other applications.
Similar content being viewed by others
Avoid common mistakes on your manuscript.
1 Introduction
Over the years, nature plays an important role in the development of mankind. Many revolutionary discoveries of today’s world have been inspired by nature. In the area of materials science, such inspiration from nature has been successively employed in fabrication processes as well as to design target materials. The highly ordered, diverse, and unique structures of natural things and biomaterials inspired researchers to duplicate and mimic it in nanomaterials through material chemistry [1,2,3,4,5,6,7]. The inspiration from nature and the designing of nanomaterials with appropriate orientation, highly ordered structure, and exceptional mechanical robustness while achieving high energy and power densities have remained a hot topic in developing electrode materials. Many nature-inspired commercial products are also easily available in today’s commercial market [8]. For example, artificial photosynthesis, inspired by the photosynthesis of plant, approach has been successively employed for harvesting solar energy [9, 10]. Other nature-inspired applications include bio-inspired water purification system [11], protein production inspired from the silk making process of spiders [12], bio-inspired materials for plastic replacement [13], etc. have also been reported. Moreover, nature-inspired materials and designs have also been explored to produce natural and renewable resources toward sustainable, low-cost electrode development [14,15,16,– 17].
The enthusiastic development of cutting-edge energy storage devices advances today’s electronics world for the betterment of tomorrow. Supercapacitors (SCs) are one of such elite electrochemical energy storage devices which have gained enormous research interest in last few years [18,19,20,21,22,23,24,25,26,27]. Specially, the charge storage mechanism of electric double layer capacitor (EDLC) does not involve any chemical reaction [28,29,– 30], which plays a crucial role for the designing of sustainable future. Benefitted by their enhanced charge storage mechanism, improved cycling stability, high rate capability, and elevated power density, SCs have shown promising advantages to fulfill the demand of future electronic devices [31,32,33,34,35,36,37,– 38]. In this aspect, several strategies have been employed for enhancing the capacitive performance of SC electrodes. Among them, high porosity, high conductivity, and large surface area are some of the prime factors being considered [39,40,41,– 42]. Basically, the porous nature of electrode materials allows easy and fast transport of electrolyte ions which further improves the electrochemical performance [43,44,45,46,47,48,– 49]. While these properties are important, the morphology of the electrode materials is equally significant too [50,51,52,53,54,55]. The availability of large electrochemical surface area also relieves the stress incurred by long charging/discharging cycles. Among different morphologies, hierarchical morphologies are advantageous toward energy storage application due to their enhanced surface area, low density, controlled, interconnected structure, and enhanced accessible area. Such materials produce electrical, chemical, biological, mechanical, as well as sustainable gains, which are valuable toward the new developments in the energy-related fields [8]. In this aspect, nature-inspired materials with hierarchical structures are highly beneficial, such as, carbon materials with nature-inspired structures displaying high surface area and enhanced porosity. On the other hand, some metal oxides/mixed metal oxides also exhibited promising electrochemical characteristics, benefitted by their special nanoarchitectures [56,57,58,– 59]. Although the nature-inspired materials are long way to go for commercialization, the current research trend is very encouraging for sustainable future. Despite of their impressive characteristics, very few systematic review articles on energy-related applications of nature-inspired materials are available [1, 6, 7, 60, 61]. Therefore, a timely update on such materials in this particular research field is highly necessary.
The aim of this paper is to summarize the applications of nature-inspired (animal- and human body-inspired) morphologies comprehensively for SC as shown in Fig. 1. Categorizing nature-inspired nanostructures according to a group of animal-inspired (honeycomb-, beehive-, spider web-, hedgehog-, whisker-, caterpillar and worm-, nest-, and plume-like) and human body-inspired (spine-, finger-, DNA-, and dendrite-like) nanostructures. This review discusses different factors and certain conditions capable of generating nature-inspired nanostructures. Moreover, the review ends with incorporating the learning from nature-inspired nanostructures with outlook, prospects, and strategies to mitigate the shortcomings of future electrodes in SC and battery applications.
2 Nature-Inspired Structures: Synthesis, Structural Formation, and Supercapacitive Electrochemical System Application
As categorized in the dimensional growth of structures, the formation of 0D, 1D, 2D, and 3D structures are widely investigated in the mechanistic formation of crystals and their morphology [62,63,64,65,66]. Tiwari et al. [67] categorized different nanostructured materials as 0D, such as uniform particles arrays (quantum dots), heterogeneous particles arrays, core–shell quantum dots, onions, hollow spheres, and nanolenses; 1D such as nanowires, nanorods, nanotubes, nanobelts, and nanoribbons; 2D such as junctions (continuous islands), branched structures, nanoprisms, nanoplates, nanosheets, nanowalls, and nanodisks; and 3D such as nanoballs (dendritic structures), nanocoils, nanocones, nanopillars, and nanoflowers.
Even though these structures are classified into dimensional orientations, many studies have shown nanostructures mimicking things that we regularly see in nature. The overlapping and combination of 1D, 2D, and 3D nanostructures that resemble trees, honeycombs, flowers, urchins, etc., have been synthesized and worked effectively as an electrode material for SCs. Depending on many factors, such as choice of precursors, method of synthesis, the structure of an active electrode material can be customized in a way that more surface area can be exposed [53,54,– 55, [68]. For example, carbon with tailored structure can achieve high surface area by engineering its morphology [69,70,71,– 72] (Table 1). Such engineering of structures paved way for researchers to continuously study and evaluate hierarchical structures in a nanoscale level [73,74,– 75].
In this section, we discuss the recent morphologies reported that imitate various nature-inspired such as animal and human body-inspired nanostructures, their method of synthesis, and their electrochemical properties applied as SC. This section is divided into groups according to animal-inspired (honeycomb-, beehive-, spider web-, hedgehog-, whisker-, caterpillar and worm-, nest-, and plume-like) and human body-inspired (spine-, finger-, DNA-, and dendrite-like) nanostructures.
2.1 Animal-Inspired Structures
2.1.1 Honeycomb-Like Structure
With a similar structure, honeycomb and beehive-like structures have uniform and regularly shaped pores. Bio-inspired honeycomb-like [85,86,87,88,89,90,91,92] and beehive-like [76, 93, 94] structures with vertical thin walls have been greatly studied for SCs due to its excellent mechanical properties as well as exceptional active sites [2, 92, [95,96,97,98,– 99]. Aside from SCs, bio-inspired honeycomb structures have also inspired further applications in biomedicine such as tissue engineering and regenerative medicine [97].
Lv et al. [100] reported novel honeycomb-lantern-inspired 3D flexible and stretchable SCs for improved capacitance. The interesting structural flexibility and stretchability in shape of honeycomb-like structure offer mechanical strength as shown in Fig. 2a. The honeycomb-lantern-inspired structure was synthesized based on expandable composite electrode composed of polypyrrole/black-phosphorous oxide electrodeposited on carbon nanotube (CNT) film. The 3D honeycomb-lantern-inspired exhibited enhanced stretchability compared to 2D counterparts, which is useful for wearable devices. More importantly, the device is feasible to lessen the stress from different directions. The 3D SC maintained a capacitance of 95% under the reversible strain of 2000% even after 10,000 stretch and release cycles. Sun et al. [101] reported the metal–organic frameworks (MOFs) as a sacrificial template to prepared honeycomb-like metal sulfide as a SC electrode. Among different electrode materials, the MOF-derived honeycomb-like metal sulfide at 500 °C (Co9S8@C‐500) exhibited superior performance due to enhanced active sites of porous carbon thin nanosheets (Fig. 2b), which suppressed the agglomeration of metal sulfide and the improved conductivity of the electrode material due to carbon nanosheets. The Co9S8@C‐500 exhibited no fade in capacitance for 4000 cycles, confirming its excellent mechanical properties. Peng et al. [102] compared dynamic hydrolysis and static deposition approaches for the fabrication of SC electrode materials. Ruthenium oxide hollow sphere (static deposition) and honeycomb-like (dynamic hydrolysis) nanostructure were compared. The ruthenium oxide honeycomb-like (RHCs) electrode exhibited superior surface area (226 m2 g–1) than ruthenium oxide hollow sphere (RHSs)-like (226 m2 g–1) structure (Fig. 2c-d). Furthermore, the honeycomb-like electrode exhibited 5% higher cycling stability for the same number of cycles. Wu et al. [99] carbonized KOH-treated wheat flour in a single step to obtain 3D honeycomb-like porous carbon (HPC) foam nanostructure. The interconnected HPC (Fig. 2e) electrode material exhibited high surface area and was used for symmetric supercapacitor (SSC) device. The SSC device exhibited superior energy and power densities than reported carbon-based SSC devices as shown in Fig. 2f [77, 99, 103, 104]. In addition to that, various number of honeycomb-like structure have been reported for SC applications, confirming the importance of unique structure for energy storage applications. Table 2 shows the reported honeycomb-like structures.
2.1.2 Spider Web-Like Structure
Nature has always motivated and inspired human being for the fabrication of interesting and attractive nanostructures-based electrode materials [105,106,– 107]. Both materials properties and determination of architectures are important for variety of applications [108, 109]. Spider webs are commonly found anywhere – at parks or even at homes. Spider webs are made from silk known for its exceptional toughness and flexibility, and water resistivity. Inspired by these characteristics, Deng et al. [110, 111] prepared a special design structure for energy storage device with exceptional mass transfer abilities. Figure 3a shows the schematic diagram of the preparation of 3D carbon network (3DCN) with bionic surface using zeolitic imidazolate frameworks (ZIF) as precursors. ZIF-8 polyhedron on carbon surface were connected to each other, forming spider web network-like structure. After annealing at 800 °C in argon for 2 h, the desired structure was achieved by washing away ZIF-8 with HCl and retaining 3D carbon network with “spider web”-like carbon, S-3DCN. The detailed mass transfer abilities for all three samples are given in Fig. 3b. Herein, S-3DCN portrayed a full adsorption of water drop at 8 s, out-performing 3DCN (14 s) and S-C (> 14 s), depicting S-3DCN has the best transportation ability. The as-prepared electrode material was further considered for energy storage applications and the solid-state SSC device (S-3DCN//S-3DCN) was fabricated. The nature-inspired S-3DCN spider web-like microstructures show multiple active sites toward electrolyte, numerous pores, excellent wettability of electrolyte. The designed SSC device successfully illuminated 19 LEDs as shown in Fig. 3c, which confirmed the advantaged of S-3DCN materials toward multiple applications.
The construction and design of 1D nanoarchitecture and the flexibility of binder-free electrode material have shown great interest for electrode fabrication. The practical capacitance and stability of the metal oxide greatly depend on the composition, synthesis condition, and morphology of the structure [43, 63, 112, 113, 114, 115, 116, 117]. Manikandan et al. [118] designed binder-free vanadium oxide spider web-like nanostructure by using facile in situ hydrothermal technique for SSC devices. Figure 4a-b shows the schematic diagram and the scanning electron microscopy (SEM) image of the as-synthesized spider web-like structure. The nature-inspired based SSC device exhibited exceptional stability of 97% after 100,000 cycles (Fig. 4c). Even after 100,000 cycles, the spider web-inspired nanostructure was preserved as shown in the inset of Fig. 4c.
2.1.3 Hedgehog Quills Structure
Hedgehogs are unique pets that have spines consisting of hollow hairs. These spines, called as quills, can be curled, or straightened upon muscle control. Inspired by the curling up and relaxation of their quills and the exterior structure of hedgehogs, researchers have utilized these structures to cater an electrode’s architecture for SC application [119, 120, 121]. Sun et al. [119] reported of hedgehog-inspired electrode material for flexible SC devices. Figure 5a shows the preparation of NiCo2O4@NixCoyMoO4 core–shell hedgehog-like nanoneedle-clusters nanostructures. The synthesis was done in two-step facile hydrothermal method. In the first step, carbon fabric was used as a current collector and a substrate to grow NiCo2O4 hedgehog-like nanoneedles with a maximum diameter of 150 nm (Fig. 5c-d). In the second step, NixCoyMoO4 nanosheets were wrapped on the initially prepared NiCo2O4 nanoneedle clusters, forming NiCo2O4@NixCoyMoO4 core–shell hedgehog-like nanoneedle-cluster nanostructures (Fig. 5e-f). Figure 5b shows the utilization of the hedgehog-like structure for charge transport and stress release mechanism. Such combination of nanosheets grown on nanoneedles may be beneficial in giving sufficient space between the active materials which can provide better electrolyte infiltration and plentiful electroactive sites for redox reaction. The as-assembled all-solid-state flexible battery-type hybrid supercapacitor (HSC), NiCo2O4@NixCoyMoO4//AC, demonstrated outstanding outcomes with a high specific capacitance of 207 F g–1 (1 A g–1) a high energy density (64.7 Wh kg–1 at 749.6 W kg–1) and promising cycling stability (nearly 100% after 10,000 cycles).
2.1.4 Whisker-Like Structures
Luo et al. [122] synthesized self-assembled whisker-like MnO2 arrays on carbon fiber paper (MOWAs) using simple in situ redox replacement reaction in a hydrothermal method (Fig. 6a). In their study, different amount (3–15 mM) of potassium permanganate (KMnO4) was used as precursor to MnO2 yielding to different morphologies. At 7 mM KMnO4, highly ordered whisker-like MnO2 arrays are consistently observed covering the whole carbon fiber (Fig. 6b). At a higher magnification (Fig. 6c), each whisker is made up of many interconnected and ultrathin nanosheets. An individual MOWA is shown in Fig. 6d portraying a length of 3–5 μm and about 0.5 μm in diameter at the middle section. Other morphologies were also observed upon changing KMnO4’s concentration to 3 mM (carbon fiber/MnO2 core–shell nanostructures, MOCSs) and 15 mM (ill-defined carbon fiber/MnO2 core–shell nanostructures, I-MOCSs). Figure 6e shows a comparative study of the cyclic voltammetry (CV) curves of carbon fiber paper (CFP), MOWAs, as well as the two other prepared structures, MOCs and I-MOCs. Among all electrodes, MOWAs exhibited the largest CV curve. The specific capacitance obtained for MOWAs electrode at 100 mA g–1 is 274.1 F g–1. The long-term cycling stability of MOWAs electrode resulted in a retention of 95% after 5,000 cycles (100 mA g–1). With such unique structure of small MnO2 sheets directly attached on CFP, MOWAs’ architecture provided well separated yet conductive sheets that paved way for better ion insertion and transport. Other whisker-like structured electrodes are reported in polyaniline on carbon nanofiber (CNF) [123], floss-like Ni–Co binary hydroxide composites assembled with whisker-like nanowires [124], and polyaniline (PANI) whiskers [125].
2.1.5 Caterpillar and Worm-Like Structures
Caterpillars and worms are both cold-blooded species typically with a long tube-like body. However, worms consist of smooth-structured body that do not have legs, eyes nor hair. In contrast, caterpillars have segmented bodies which appears to be rough and hairy. In a nanostructure level, caterpillar-like and worm-like structures have been investigated in SC applications. For instance, caterpillar-like NiCo2S4 nanocrystal arrays on nanofibers (NF) [126] and polyaniline/CNT hybrids with core–shell structures [127] are successfully synthesized as electrode materials. Figure 7a shows the SEM image of the NiCo2S4 nanosheet@nanowires (NSNW) which exhibits a caterpillar-like structure [126]. The NiCo2O4 consists of vertical nanosheets aligned on NF with each sheet having multidirectional nanowires. Figure 7b shows a transmission electron microscopy (TEM) image of the nanowire with a dimension of bottom core ∼50 nm and a tip ∼30 nm. Aside from the caterpillar-like NiCo2S4 NSNW structures, other structures were prepared by varying the time of maintained reaction. The sealed autoclave maintained at 95 °C for 12, 10, and 8 h yielded the Ni–Co precursor NSNWs, Ni–Co precursor NSNP, and Ni–Co precursor NS, respectively. The difference in morphologies and its effect in electrochemical performance were evaluated and the discharge curves are shown in Fig. 7c. NiCo2S4 nanosheet@nanowires (NSNW, S1), NiCo2S4 nanosheet@nanoparticles (NSNP, S2), and NiCo2S4 porous nanosheets (NS, S3) and their specific capacitances are 1,777, 1,238, and 1,010 F g–1, respectively, at the same current density of 1 A g–1. The caterpillar-like structure also benefited the S1 electrode with a retention of 83% after 3,000 cycles (10 A g–1), compared with S2 (66%) and S3 (73%) (Fig. 7d).
Worm-like structures have been prepared in N-doped graphitized porous carbon [128], mesoporous carbon [129], NiMoO4 coaxially decorated on electro-spun CNF [130], amorphous MnO2 nanowires grown on textiles [131], Ni–Co–P deposited on NF [132], and N/S-co-doped porous carbon [82]. Figure 8a shows the SEM image of a nitrogen-doped worm-like hierarchical porous carbon with graphitized porous carbon embossment (NWHC-GE), which was prepared by polymerization-induced colloid aggregation method followed by coordination–pyrolysis process [128]. The worm-like structure was likely plausible due to the presence of ferrous sulfate heptahydrate (FSH) as a precursor. Aside from the worm-like structure formed from the addition of 0.01 mol FSH in the material preparation, the key influence of FSH leads to formation of other structures, such as N-doped hollow carbon sphere (NHCS, no FSH was added) and N-doped hollow carbon capsule (NHCC, 0.02 mol FSH was added). Figure 8b shows a comparative GCD profiles of NHCS, NWHC-GE, and NHCC at a current density of 20 A g–1 portraying the longest GCD curved favorable to NWHC-GE. At 1 A g–1, the higher specific capacitance of NWHC-GE is 178 F g–1is attained compared to NHCS (114 F g–1) and NHCC (156 F g–1). A better electrical conductivity and lower resistivity were also observed for NWHC-GE (0.39 Ω) than that of NHCS (0.57 Ω) and NHCC (1.58 Ω) (Fig. 8c). Such improved performance is credited to a higher graphitization degree and an optimized nitrogen-doping content for NWHC-GE.
Similarly, Gopalakrishnan et al. [82] reported worm-like hierarchical structures based on nitrogen, sulfur-co-doped porous carbon were derived from ginger. Inspired by ginger as biomass source for carbon, ginger was pre-activated using NaCl/KCl followed by carbonization (800 °C) and removal of salt ions through washing with diluted HCl (product denoted as AGC). To dope AGC with nitrogen and sulfur, thiourea was used as precursor and went under another carbonization (800 °C) (product denoted as DAGC). The final structure of the doped & activated ginger carbon (DAGC) with unique worm-like pore structure and interconnected cavities is shown in Fig. 8d. The worm-like structure not only gained a high specific surface area (720 m2 g–1) but also yielded to an improved electrochemical performance. Figure 8e shows a comparative GCD curves for DAGC, AGC (activated ginger-derived carbon), and GC (ginger-derived carbon without any activation and doping). Clearly, DAGC showed a lengthy charge and discharge profiles which can be acquainted to a better ion storage and high capacitive performance. The highest performance conducted at 1 A g–1 was obtained for DAGC (268 F g–1) compared to GC (75 F g–1) and AGC (172 F g–1). The stability for GC and DAGC were compared at constant current density (Fig. 8f). The superior electrochemical performance can be acquainted to DAGC’s thin carbon nanosheets morphology with worm-like pore structures and heteroatom doping, which utilized rapid ion transfers and maximum charge storage capacity [73, 74, 75].
2.1.6 Plume-Like Structure
A plume is similar to a structure of a bird’s feather that consists of tiny hair-like strands. Jinlong et al. [133] initially deposited graphene oxide (GO) sheets on NF by dipping in a GO dispersion and thermal reduction annealing. Then, Ni3S2 was grown by hydrothermal method on the pre-deposited GO on NF. The final resulting structure is a plume-like Ni3S2 grown on the NF with thermal reduced graphene oxide (rGO) architecture as shown in Fig. 9a. Figure 9b shows the CV curve representing the electrochemical performance of the plume-like structure compared to rGO on NF and Ni3S2 on NF only. At a scan rate of 2 mV s−1, larger non-rectangular CV curves were observed for the Ni3S2 on NF with rGO electrode. The plume-like structured electrode delivered a high capacitance of 1,462 F g−1 (1 A g−1) and retained 98.34% of its capacitance on the first 1,000 cycles. The plume-like Ni3S2 on NF with rGO exhibited better SC performance and improved cycling stability which is valuable for energy storage applications.
2.1.7 Nest-Like Structures
By nature, nests are built by animals, such as birds, to hold their eggs and to serve as a home for the young ones. Bird’s nest comprises of dried leaves, branch, or grasses that is coiled into a cup-shape. Nest-like architectures are studied and structured in electrode materials, such as N- and P-co-doped mesoporous carbon [83], glucose-derived nitrogen-doped hollow carbon [134], Fe-doped MnO2 [135], polyaniline [136], and V3O7 [137]. A nest-like structure based on Ni@Ni1.4Co1.6S2 [138], MnO, and V3O7 [137] are shown in Fig. 10. Mi et al. [138] initially synthesized Ni@Ni3S2 with a nest-like structure. Ni@Ni1.4Co1.6S2 was then synthesized by a Co-exchange method by using Ni@Ni3S2 as a template. The Ni@Ni1.4Co1.6S2 is composed of a network of nanowires which forms numerous micro-/nanoholes mimicking a nest (Fig. 10a). With a similar structure yet with the addition of Co-ions, the specific capacitance of Ni@Ni1.4Co1.6S2 is 122 F g–1, compared to Ni@Ni3S2 (89 F g–1) at 1 A g–1. Figure 10b shows a bird’s nest-like structures based on MnO2 [139]. The self-organized structure formed clusters with ~ 4–5 μm diameter consisting of interconnected nanowires (Fig. 10c). With such organized structure, the maximum specific capacitance of 917 F g–1 at a current density of 5 mA cm–2 was obtained.
Another nest-like structure is based on the home of ants or anthills. Anthills are commonly built underground. Inside an anthill is a massive network of interior channels and chambers. Inspired by such unique interconnected structure, ant-nest-based nanostructures have been utilized as electrode materials. A unique ant-nest-like structured electrode was prepared in NiMoO4/ carbonized melamine sponge (CMS) using solvothermal reaction (Fig. 11a) [140]. NiMoO4 nanorods are grown on the CMS by solvothermal reaction while maintaining the interconnected channels of CMS sponge. The optimized NiMoO4/CMS electrode exhibited a high specific capacitance of 1,689 F g–1 (1 A g–1). Miao et al. [141] studied carbon‐based ant-nest-like structures are prepared using NF supported hierarchical porous carbon (NF-HPC). A 3D crossed‐linked and associated backbones (diameter of ≈200 nm) aided the formation of highly uniform and well‐interconnected porous structure (Fig. 11b). As a symmetric SC device, the outstanding electrochemical performance of the device resulted in a high specific capacitance (292 at 0.25 A g–1) and long‐term cycling stability (100% at 5 A g–1 after 30,000 cycles). Lastly, a unique 3D ant-nest-like hierarchical porous carbon (ANHPC) is shown in Fig. 11c [142]. The ant-nest-like structure of ANHPC possesses large surface area (2,372 m2 g–1) and high pore volume (1.936 m3 g–1. The exceptional structure was then utilized to embed MnO2 and obtain MnO2/ANHPC composites (Fig. 11d). It is clearly observed that the carbon skeleton structure has not collapsed and retained the structure of ANHPC. The ant-nest-inspired structures give a favorable architecture for rapid ion transfer/diffusion. The combination of EDLC-based ANHPC and pseudocapacitance-based MnO2 yielded to a high specific capacitance of 662 F g–1 at 1 A g–1 compared to ANHPC at 254 F g–1. The detailed electrochemical performance of animal-inspired structure tabulated in Table 2.
2.2 Human Body-Inspired Structures
2.2.1 Spine-Like Structure
Park et al. [84] prepared spine-like nanostructured carbon interconnected by graphene with SC applications. The preparation of spine-like graphene-interconnected nanostructured carbon consists of three steps: i) preparation of platelet-type CNF (P-CNF) by chemical vapor deposition (CVD), ii) an expanding process by oxidation treatment, and iii) a co-solvent exfoliation method and reduction processes. Figure 12a-b shows the SEM and TEM image of the spine-like nanostructured carbon which is composed of regularly occurring intervals of exfoliated graphitic blocks and graphene nanoplatelets. In a three-electrode system, the spine-like nanostructured carbon exhibited significantly improved electrochemical performance (272 F g–1 at 10 mV s–1) compared to as-prepared P-CNF (19 F g–1) (Fig. 12c). To further use into practical application, the two-electrode system delivered a high capacitance (238.8 F g–1 at 2.5 A g–1), rate capability (230 F g–1 at 200 mV s–1, above 85% of the initial value at 10 mV s–1), and cycle stability (94% after 3,000 cycles) for the spine-like nanostructured carbon (Fig. 12d).
2.2.2 Finger-Like Structure
Finger-like structures are used as effective designs for electrode materials in multifunctional integrated micro/nano systems [152, 153, 154, 155, 156]. In‐plane finger-like structures are advantageous for micro‐supercapacitors for it provides suitable accessibility for ion transport as the edges of the active electrodes are exposed to the electrolyte. Also, the finger-like design eliminates the use of separators as needed in conventional sandwich structures of SCs which also decreases the resistance and leads to high-frequency response as the distance between the electrode finger arrays is small [157]. Wang et al. [158] fabricated vertical finger-like asymmetric supercapacitors (VFASCs) comprising of rGO–manganese dioxide–polypyrrole (rGO-MnO2-PPy) as positive electrode and RGO–molybdenum trioxide (rGO–MoO3) as negative electrode. Various mass loading was investigated with structures mimicking 2 to 10 finger-like electrodes (Fig. 13a). The CV (Fig. 13b) and GCD (Fig. 13c) curves showed the highest performance for the 10 finger-like electrodes (5m0). The specific capacitance increased with the increased of mass loading (Fig. 13d) with 5m0 recording the highest capacitance of 31.4 F g–1 (34.8 F cm−3). The 5m0 electrode showed a high energy density of 12.94 mW h cm−3 (power density at 0.47 W cm−3) and still maintained the high value of 2.59 mW h cm−3 (power density at 3.72 W cm−3) with 88.2% capacitance retained after 10,000 cycles (Fig. 13e-f). For practical application, bending experiment was done to show the flexibility of the electrode as shown in Fig. 13g. Moreover, two electrodes connected in series accumulating 3.2 V were successful in lighting two LEDs (Fig. 13h).
2.2.3 DNA-Like Structure
Another fascinating nature-inspired nanoarchitecture is a double helical DNA-like WO3–x/C microfiber superstructure [159]. Salkar et al. [159] prepared a self-assembly of in situ carbon fiber encapsulated by WO3–x/C nanorods depicting a DNA-like structure as shown in Fig. 14a. The double helical DNA-inspired assembly provides favored structure allowing better participation of ions during electrochemical reaction. Figure 14b shows the CV curves with different scan rate (25 to 250 mV s–1) across the − 0.5 to 0.3 V potential range. At 25 mV s–1, the specific capacitance is 169.2 F g–1. Using the GCD curves, the highest specific capacitance was recorded at 498.4 F g–1 at 1.2 A g–1 (equivalent to areal capacitance of 401.4 mF cm–2 at 2 mA cm−2) (Fig. 14c). A solid-state asymmetric supercapacitor (ASC) device was assembled a deliver a power density of 498 W kg–1 at an energy density of 15.4 Wh kg–1. The rare DNA-like morphology only justified its unusual yet important structure in the development of electrode nanoarchitectures.
2.2.4 Dendrite-Like Structure
Dendrites are pronged extensions of a nerve cell which is similar to a tree-like structures. Dendrite formation has also been observed in mineral crystal growth, as well as, in snowflake and frost pattern formations. These unique structures have been observed in the growth of Au dendrites containing long back bone stems with several branches and highly corrugated structures [160], Co3O4 nanostructure made up of nanorods [161], and dendrite-like MnO2 nanostructures grown on carbon cloth [162]. Figure 15 shows the synthesis of MnO2 nanowires grown on hollow Ni dendrites prepared by Sun et al. [163]. Initially, Cu dendrites were first prepared on Ni substrate using electrodeposition (Fig. 15a, e–g). The as-formed Cu dendrites were then coated with a thin layer of Ni using electroplating (Cu@Ni) (Fig. 15b). Then, Cu was selectively removed from Cu@Ni through anodic dissolution, leaving a hollow Ni (Fig. 15c, h-j). Finally, Ni@MnO2 was prepared by growing MnO2 nanowires on the surface of hollow Ni using anodic pulse electrochemical deposition (Fig. 15d, k-m). When applied as an electrode, the Ni@MnO2 electrode delivered a specific capacitance of 1125 F g–1 (5 mV s–1) at a MnO2 mass loading of 0.35 mg cm–2. When a higher MnO2 mass loading was increased to 1.8 mg cm–2, the specific capacitance resulted in 303 F g–1 (5 mV s–1). The outstanding electrochemical performance of the Ni@MnO2 electrode can be attributed to the following nanoarchitecture: first, the highly conductive hollow Ni dendrites acted as both support and current collector that allowed the pathway for fast electron transport; second, the MnO2 nanowire arrays permitted productive material utilization; lastly, the existence of hierarchical porous channels in the overall construction facilitates fast diffusion between the electrode and electrolyte [39, 40, 47, 48, 56, 164, 165]. The detailed electrochemical performance of human-inspired structure tabulated in Table 3.
3 Future Outlooks and Conclusion
In this review article, we have highlighted the importance of animal and human body-inspired materials down to the nanoscale level for SC application. Materials with different dimensionalities can be fabricated, tailored, and exploited according to several factors to construct nature-inspired formation of interconnected and hierarchical nanostructures. It is interesting to note that such dimensional structures can generate ordered structures, which are highly valued as the electrode materials. Still, the overall electrochemical performance will matter for practical use. Though having a high capacitance and capacitive property is highly desirable for many electrodes that has been researched, it is only one of the important properties that must be considered in constructing electrode materials. Nevertheless, a lot of hindrances have been assessed why scientifically studied electrodes cannot be launched in the market.
Nature-inspired materials with high porosity are found to be feasible for energy storage applications. The current article systematically summarized SC application of few of such nature-inspired materials. However, such materials also shave some drawbacks, which are enlisted below with future research directions.
-
1.
Large scale production of such nature-inspired materials with cost-effectiveness is quite complicated. For example, metal precursors displayed considerable electrical and chemical properties. However, researchers must consider the long-term availability of these precious metals as well as their costs if they want to concentrate on producing metal-based electrode materials in commercial scale. Moreover, precise production of such material is also highly challenging. In this aspect, the 3D printing techniques have the ability to copy the natural structures. The printed products are also found to be highly flexible, which can be applicable for constructing flexible and stretchable supercapacitors. Therefore, future manufacturing of nature-inspired materials can be focused on these techniques for scalable production.
-
2.
Apart from their structures and morphologies, other factors, like the nature of electrode materials, choice of electrolytes, use of binders, and nature of current collections, have also played significant role on the electrochemical performance of any electrode materials. Smart combination of EDLC-type and pseudocapacitive-type materials with nature-inspired structures is found to be a feasible strategy to improve the capacitive performance. Although, such combination requires much more research attention for commercialization.
-
3.
In-depth knowledge of the charge storage mechanism of such nature-inspired materials is highly required for future research. In this aspect, the in situ characterization techniques like in situ TEM, in situ XRD, in situ Raman spectra, in situ XPS, etc. can be a pivotal approach to incorporate in material characterization in order to better understand the physiochemical properties of the active materials.
-
4.
It is evident that the electrochemical performance of such nature-inspired materials can be tuned by manipulating the interfacial interactions of individual components. However, detailed theoretical study is necessary in this topic.
-
5.
Nature-inspired structures based on newly developed 2D materials like MXene should be explored for a wide variety of applications.
-
6.
The differences in EDLC-, pseudocapacitive-, and battery-type electrode materials; symmetric, asymmetric, and hybrid SC devices; and the appropriate selection of potential/voltage window as well as suitable equations for the calculations of energy density should be carefully selected as previously discussed [21, 166, 167].
References
C. Xu, A.R. Puente-Santiago, D. Rodríguez-Padrón, M.J. Muñoz-Batista, M.A. Ahsan et al., Nature-inspired hierarchical materials for sensing and energy storage applications. Chem. Soc. Rev. 50(8), 4856–4871 (2021). https://doi.org/10.1039/C8CS00652K
Y. Liu, K. He, G. Chen, W.R. Leow, X. Chen, Nature-inspired structural materials for flexible electronic devices. Chem. Rev. 117(20), 12893–12941 (2017). https://doi.org/10.1021/acs.chemrev.7b00291
Z.A. ALOthman, D. Rodriguez-Padron, R. Luque, A.M. Balu, Innovative nanomaterials for energy storage moving toward nature-inspired systems. Curr. Opinion Green Sustain. Chem. 32, 1005 (2021). https://doi.org/10.1016/j.cogsc.2021.100520
C. Wan, Y. Jiao, D. Liang, Y. Wu, J. Li, A geologic architecture system-inspired micro-/nano-heterostructure design for high-performance energy storage. Adv. Energy Mater. 8(33), 1802388 (2018). https://doi.org/10.1002/aenm.201802388
J. Tang, P. Yuan, C. Cai, Y. Fu, X. Ma, Combining nature-inspired, graphene-wrapped flexible electrodes with nanocomposite polymer electrolyte for asymmetric capacitive energy storage. Adv. Energy Mater. 6(19), 1600813 (2016). https://doi.org/10.1002/aenm.201600813
N.S. Ha, G. Lu, a review of recent research on bio-inspired structures and materials for energy absorption applications. Compos. Part B Eng. 181, 107496 (2020). https://doi.org/10.1016/j.compositesb.2019.107496
P. Trogadas, M.O. Coppens, Nature-inspired electrocatalysts and devices for energy conversion. Chem. Soc. Rev. 49(10), 3107–3141 (2020). https://doi.org/10.1039/C8CS00797G
N.K. Katiyar, G. Goel, S. Hawi, S. Goel, Nature-inspired materials: emerging trends and prospects. NPG Asia Mater. 13, 56 (2021). https://doi.org/10.1038/s41427-021-00322-y
D. Gust, T.A. Moore, A.L. Moore, Solar fuels via artificial photosynthesis. Acc. Chem. Res. 42(12), 1890–1898 (2009). https://doi.org/10.1021/ar900209b
J. Wang, T. Zhu, G.W. Ho, Nature-inspired design of artificial solar-to-fuel conversion systems based on copper phosphate microflowers. Chemsuschem 9(13), 1575–1578 (2016). https://doi.org/10.1002/cssc.201600481
E. Freeman, R. Soncini, L. Weiland, Biologically inspired water purification through selective transport. Smart Mater. Struct. 22(1), 014013 (2012). https://doi.org/10.1088/0964-1726/22/1/014013
N. Kronqvist, M. Sarr, A. Lindqvist, K. Nordling, M. Otikovs et al., Efficient protein production inspired by how spiders make silk. Nat. Commun. 8, 15504 (2017). https://doi.org/10.1038/ncomms15504
Q.F. Guan, H.B. Yang, Z.M. Han, Z.C. Ling, S.H. Yu, An all-natural bioinspired structural material for plastic replacement. Nat. Commun. 11, 5401 (2020). https://doi.org/10.1038/s41467-020-19174-1
H. Wang, Y. Yang, L. Guo, Nature-inspired electrochemical energy-storage materials and devices. Adv. Energy Mater. 7(5), 1601709 (2017). https://doi.org/10.1002/aenm.201601709
W.E. Tenhaeff, O. Rios, K. More, M.A. McGuire, Highly robust lithium ion battery anodes from lignin: an abundant, renewable, and low-cost material. Adv. Funct. Mater. 24(1), 86–94 (2014). https://doi.org/10.1002/adfm.201301420
S.K. Kim, Y.K. Kim, H. Lee, S.B. Lee, H.S. Park, Superior pseudocapacitive behavior of confined lignin nanocrystals for renewable energy-storage materials. Chemsuschem 7(4), 1094–1101 (2014). https://doi.org/10.1002/cssc.201301061
J. Zhou, C. Zheng, H. Wang, J. Yang, P. Hu et al., 3D nest-shaped Sb2O3/RGO composite based high-performance lithium-ion batteries. Nanoscale 8(39), 17131–17135 (2016). https://doi.org/10.1039/C6NR06454J
S. Sahoo, R. Kumar, E. Joanni, R.K. Singh, J.J. Shim, Advances in pseudocapacitive and battery-like electrode materials for high performance supercapacitors. J. Mater. Chem. A 10(25), 13190–13240 (2022). https://doi.org/10.1039/D2TA02357A
I. Hussain, S. Iqbal, C. Lamiel, A. Alfantazi, K. Zhang, Recent advances in oriented metal-organic frameworks for supercapacitive energy storage. J. Mater. Chem. A 10(9), 4475–4488 (2022). https://doi.org/10.1039/D1TA10213C
R. Kumar, E. Joanni, S. Sahoo, J.J. Shim, T.W. Kian et al., An overview of recent progress in nanostructured carbon-based supercapacitor electrodes: from zero to bi-dimensional materials. Carbon 193, 298–338 (2022). https://doi.org/10.1016/j.carbon.2022.03.023
I. Hussain, S. Sahoo, D. Mohapatra, M. Ahmad, S. Iqbal et al., Recent progress in trimetallic/ternary-metal oxides nanostructures: misinterpretation/misconception of electrochemical data and devices. Appl. Mater. Today 26, 101297 (2022). https://doi.org/10.1016/j.apmt.2021.101297
I. Hussain, S. Sahoo, C. Lamiel, T.T. Nguyen, M. Ahmed et al., Research progress and future aspects: metal selenides as effective electrodes. Energy Storage Mater. 47, 13–43 (2022). https://doi.org/10.1016/j.ensm.2022.01.055
J. Yan, T. Liu, X. Liu, Y. Yan, Y. Huang, Metal-organic framework-based materials for flexible supercapacitor application. Coord. Chem. Rev. 452, 214300 (2022). https://doi.org/10.1016/j.ccr.2021.214300
J. Jin, X. Geng, Q. Chen, T.L. Ren, A better Zn-ion storage device: recent progress for Zn-ion hybrid supercapacitors. Nano-Micro Lett. 14, 64 (2022). https://doi.org/10.1007/s40820-022-00793-w
T. Kar, S. Godavarthi, S.K. Pasha, K. Deshmukh, L. Martínez-Gómez et al., Layered materials and their heterojunctions for supercapacitor applications: a review. Crit. Rev. Solid State Mater. Sci. 47(3), 357–388 (2022). https://doi.org/10.1080/10408436.2021.1886048
H. He, J. Lian, C. Chen, Q. Xiong, C.C. Li et al., Enabling multi-chemisorption sites on carbon nanofibers cathodes by an in-situ exfoliation strategy for high-performance Zn-ion hybrid capacitors. Nano-Micro Lett. 14, 106 (2022). https://doi.org/10.1007/s40820-022-00839-z
T. Xu, D. Wang, Z. Li, Z. Chen, J. Zhang et al., Electrochemical proton storage: from fundamental understanding to materials to devices. Nano-Micro Lett. 14, 126 (2022). https://doi.org/10.1007/s40820-022-00864-y
M.S. Javed, T. Najim, I. Hussain, S. Batool, M. Idrees et al., 2D V2O5 nanoflakes as a binder-free electrode material for high-performance pseudocapacitor. Ceram. Int. 47(17), 25152–25157 (2021). https://doi.org/10.1016/j.ceramint.2021.05.181
I. Hussain, A. Ali, C. Lamiel, S.G. Mohamed, S. Sahoo et al., A 3D walking palm-like core-shell CoMoO4@NiCo2S4@ nickel foam composite for high-performance supercapacitors. Dalton Transact. 48(12), 3853–3861 (2019). https://doi.org/10.1039/C8DT04045A
I. Hussain, T. Hussain, S.B. Ahmed, T. Kaewmaraya, M. Ahmad et al., Binder-free trimetallic phosphate nanosheets as an electrode: theoretical and experimental investigation. J. Power Sources 513, 230556 (2021). https://doi.org/10.1016/j.jpowsour.2021.230556
L. Zhang, X. Hu, Z. Wang, F. Sun, D.G. Dorrell, a review of supercapacitor modeling, estimation, and applications: a control/management perspective. Renew. Sustain. Energy Rev. 81, 1868–1878 (2018). https://doi.org/10.1016/j.rser.2017.05.283
S. Kumar, G. Saeed, L. Zhu, K.N. Hui, N.H. Kim et al., 0D to 3D carbon-based networks combined with pseudocapacitive electrode material for high energy density supercapacitor: a review. Chem. Eng. J. 403, 126352 (2021). https://doi.org/10.1016/j.cej.2020.126352
Z. Yang, J. Tian, Z. Yin, C. Cui, W. Qian et al., Carbon nanotube-and graphene-based nanomaterials and applications in high-voltage supercapacitor: a review. Carbon 141, 467–480 (2019). https://doi.org/10.1016/j.carbon.2018.10.010
A. Mohanty, D. Jaihindh, Y.P. Fu, S.P. Senanayak, L.S. Mende et al., An extensive review on three dimension architectural metal-organic frameworks towards supercapacitor application. J. Power Sources 488, 229444 (2021). https://doi.org/10.1016/j.jpowsour.2020.229444
Z. Bi, Q. Kong, Y. Cao, G. Sun, F. Su et al., Biomass-derived porous carbon materials with different dimensions for supercapacitor electrodes: a review. J. Mater. Chem. A 7(27), 16028–16045 (2019). https://doi.org/10.1039/C9TA04436A
D.G. Wang, Z. Liang, S. Gao, C. Qu, R. Zou, Metal-organic framework-based materials for hybrid supercapacitor application. Coord. Chem. Rev. 404, 213093 (2020). https://doi.org/10.1016/j.ccr.2019.213093
A. Gopalakrishnan, S. Badhulika, Effect of self-doped heteroatoms on the performance of biomass-derived carbon for supercapacitor applications. J. Power Sources 480, 228830 (2020). https://doi.org/10.1016/j.jpowsour.2020.228830
M. Ahmad, I. Hussain, T. Nawaz, Y. Li, X. Chen et al., Comparative study of ternary metal chalcogenides (MX; M= Zn-Co-Ni; X= S, Se, Te): formation process, charge storage mechanism and hybrid supercapacitor. J. Power Sources 534, 231414 (2022). https://doi.org/10.1016/j.jpowsour.2022.231414
I. Hussain, T. Hussain, C. Lamiel, K. Zhang, Turning indium oxide into high-performing electrode materials via cation substitution strategy: preserving single crystalline cubic structure of 2D nanoflakes towards energy storage devices. J. Power Sources 480, 228873 (2020). https://doi.org/10.1016/j.jpowsour.2020.228873
S. Gu, R. Hao, J. Chen, K. Liu, X. Chen et al., Star-shaped polyimide covalent organic framework for high-voltage lithium-ion batteries. Mater. Chem. Front. 6(17), 2545–2550 (2022). https://doi.org/10.1039/D2QM00578F
S. Iqbal, A.H. Mady, Y.I. Kim, U. Javed, P.M. Shafi et al., Self-templated hollow nanospheres of B-site engineered non-stoichiometric perovskite for supercapacitive energy storage via anion-intercalation mechanism. J. Colloid Interface Sci. 600, 729–739 (2021). https://doi.org/10.1016/j.jcis.2021.03.147
S. Gu, Y. Chen, R. Hao, J. Zhou, I. Hussain et al., Redox of naphthalenediimide radicals in a 3D polyimide for stable Li-ion batteries. Chem. Commun. 57(63), 7810–7813 (2021). https://doi.org/10.1039/D1CC02426D
I. Hussain, T. Mak, K. Zhang, Boron-doped trimetallic Cu-Ni-Co oxide nanoneedles for supercapacitor application. ACS Appl. Nano Mater. 4(1), 129–141 (2021). https://doi.org/10.1021/acsanm.0c02411
I. Hussain, C. Lamiel, S.G. Mohamed, S. Vijayakumar, A. Ali et al., Controlled synthesis and growth mechanism of zinc cobalt sulfide rods on Ni-foam for high-performance supercapacitors. J. Indust. Eng. Chem. 71, 250–259 (2019). https://doi.org/10.1016/j.jiec.2018.11.033
Y. Chen, S. Gu, S. Wu, X. Ma, I. Hussain et al., Copper activated near-full two-electron Mn4+/Mn2+ redox for mild aqueous Zn/MnO2 battery. Chem. Eng. J. 450, 137923 (2022). https://doi.org/10.1016/j.cej.2022.137923
G. Dhakal, D. Mohapatra, T.L. Tamang, M. Lee, Y.R. Lee et al., Redox-additive electrolyte-driven enhancement of the electrochemical energy storage performance of asymmetric Co3O4//carbon nano-onions supercapacitors. Energy 218, 119436 (2021). https://doi.org/10.1016/j.energy.2020.119436
U. Zubair, D. Versaci, M. Umer, J. Amici, C. Francia et al., Lithium polysulfides immobilization exploiting formate-ion doped polyaniline wrapped carbon for long cycle life sulfur cathodes via conventional electrode processing. Mater. Today Commun. 26, 101970 (2021). https://doi.org/10.1016/j.mtcomm.2020.101970
S. Kumar, I.A. Mir, Z. Ahmad, K.S. Hui, D.A. Dinh et al., Microflowers of Sn-Co-S derived from ultra-thin nanosheets for supercapacitor applications. J. Energy Storage 49, 104084 (2022). https://doi.org/10.1016/j.est.2022.104084
W. Kim, H.J. Lee, S.J. Yoo, C.K. Trinh, Z. Ahmad et al., Preparation of a polymer nanocomposite via the polymerization of pyrrole: biphenyldisulfonic acid: pyrrole as a two-monomer-connected precursor on MoS2 for electrochemical energy storage. Nanoscale 13(11), 5868–5874 (2021). https://doi.org/10.1039/D0NR08941A
M.S. Javed, T. Najam, M. Sajjad, S.S.A. Shah, I. Hussain et al., Design and fabrication of highly porous 2D bimetallic sulfide ZnS/FeS composite nanosheets as an advanced negative electrode material for supercapacitors. Energy Fuels 35(18), 15185–15191 (2021). https://doi.org/10.1021/acs.energyfuels.1c02444
I. Hussain, C. Lamiel, N. Qin, S. Gu, Y. Li et al., Development of vertically aligned trimetallic Mg-Ni-Co oxide grass-like nanostructure for high-performance energy storage applications. J. Colloid Interface Sci. 582, 782–792 (2021). https://doi.org/10.1016/j.jcis.2020.08.064
I. Hussain, T. Hussain, S. Yang, Y. Chen, J. Zhou et al., Integration of CuO nanosheets to Zn-Ni-Co oxide nanowire arrays for energy storage applications. Chem. Eng. J. 413, 127570 (2020). https://doi.org/10.1016/j.cej.2020.127570
M.Z. Ansari, K.M. Seo, S.H. Kim, S.A. Ansari, Critical aspects of various techniques for synthesizing metal oxides and fabricating their composite-based supercapacitor electrodes: a review. Nanomaterials 12(11), 1873 (2022). https://doi.org/10.3390/nano12111873
N. Abbas, I. Shaheen, I. Ali, M. Ahmad, S.A. Khan et al., Effect of growth duration of Zn0.76Co0.24S interconnected nanosheets for high-performance flexible energy storage electrode materials. Ceram. Int. (2022). https://doi.org/10.1016/j.ceramint.2022.07.225
M.Z. Ansari, D.K. Nandi, P. Janicek, S.A. Ansari, R. Ramesh et al., Low-temperature atomic layer deposition of highly conformal tin nitride thin films for energy storage devices. ACS Appl. Mater. Interfaces 11(46), 43608–43621 (2019). https://doi.org/10.1021/acsami.9b15790
I. Hussain, D. Mohapatra, C. Lamiel, M. Ahmad, M.A. Ashraf et al., Phosphorus containing layered quadruple hydroxide electrode materials on lab waste recycled flexible current collector. J. Colloid Interface Sci. 609, 566–574 (2021). https://doi.org/10.1016/j.jcis.2021.11.063
S.G. Mohamed, I. Hussain, J.J. Shim, One-step synthesis of hollow C-NiCo2S4 nanostructures for high-performance supercapacitor electrodes. Nanoscale 10(14), 6620–6628 (2018). https://doi.org/10.1039/C7NR07338K
M.S. Javed, M. Imran, M.A. Assiri, I. Hussain, S. Hussain et al., One-step synthesis of carbon incorporated 3D MnO2 nanorods as a highly efficient electrode material for pseudocapacitors. Mater. Lett. 295, 129838 (2021). https://doi.org/10.1016/j.matlet.2021.129838
S.G. Mohamed, I. Hussain, M.S. Sayed, J.J. Shim, One-step development of octahedron-like CuCo2O4@ carbon fibers for high-performance supercapacitors electrodes. J. Alloys Compd. 842, 155639 (2020). https://doi.org/10.1016/j.jallcom.2020.155639
Z. Li, X. Yu, A. Gu, H. Tang, L. Wang et al., Anion exchange strategy to synthesis of porous NiS hexagonal nanoplates for supercapacitors. Nanotechnology 28(6), 065406 (2017). https://doi.org/10.1088/1361-6528/28/6/065406
N. Soudi, S. Nanayakkara, N.M. Jahed, S. Naahidi, Rise of nature-inspired solar photovoltaic energy convertors. Sol. Energy 208, 31–45 (2020). https://doi.org/10.1016/j.solener.2020.07.048
M.S. Javed, T. Najam, I. Hussain, S.S.A. Shah, S. Ibraheem et al., Novel 2D vanadium oxysulfide nano-spindles decorated carbon textile composite as an advanced electrode for high-performance pseudocapacitors. Mater. Lett. 303, 130478 (2021). https://doi.org/10.1016/j.matlet.2021.130478
C. Lamiel, I. Hussain, O.R. Ogunsakin, K. Zhang, MXene in core-shell structures: research progress and future aspects. J. Mater. Chem. A 10(27), 14247–14272 (2022). https://doi.org/10.1039/D2TA02255A
I. Hussain, T. Hussain, M. Ahmad, X. Ma, M.S. Javed et al., Modified KBBF-like material for energy storage applications: ZnNiBo3(OH) with enhanced cycle life. ACS Appl. Mater. Interfaces 14(6), 8025–8035 (2022). https://doi.org/10.1021/acsami.1c23583
I. Hussain, T. Hussain, S. Yang, Y. Chen, J. Zhou et al., Integration of CuO nanosheets to Zn-Ni-Co oxide nanowires for energy storage applications. Chem. Eng. J. 413, 127570 (2020). https://doi.org/10.1016/j.cej.2020.127570
R. Schneider, M.H. Facure, P.A. Chagas, R.S. Andre, D.M. Santos et al., Tailoring the surface properties of micro/nanofibers using 0D, 1D, 2D, and 3D nanostructures: a review on post-modification methods. Adv. Mater. Interfaces 8(13), 2100430 (2021). https://doi.org/10.1002/admi.202100430
J.N. Tiwari, R.N. Tiwari, K.S. Kim, Zero-dimensional, one-dimensional, two-dimensional and three-dimensional nanostructured materials for advanced electrochemical energy devices. Prog. Mater. Sci. 57(4), 724–803 (2012). https://doi.org/10.1016/j.pmatsci.2011.08.003
N. Abbas, I. Shaheen, I. Hussain, C. Lamiel, M. Ahmad et al., Glycerol-mediated synthesis of copper-doped zinc sulfide with ultrathin nanoflakes for flexible energy electrode materials. J. Alloys Compd. 919, 165701 (2022). https://doi.org/10.1016/j.jallcom.2022.165701
U. Amara, K. Mahmood, M. Hassan, M. Hanif, M. Khalid et al., Functionalized thiazolidone-decorated lanthanum-doped copper oxide: novel heterocyclic sea sponge morphology for the efficient detection of dopamine. RSC Adv. 12(23), 14439–14449 (2022). https://doi.org/10.1039/D2RA01406H
M. Sabar, U. Amara, S. Riaz, A. Hayat, M. Nasir et al., Fabrication of MoS2 enwrapped carbon cloth as electrochemical probe for non-enzymatic detection of dopamine. Mater. Lett. 308, 131233 (2022). https://doi.org/10.1016/j.matlet.2021.131233
U. Amara, B. Sarfraz, K. Mahmood, M.T. Mehran, N. Muhammad et al., Fabrication of ionic liquid stabilized MXene interface for electrochemical dopamine detection. Microchim. Acta 189(2), 64 (2022). https://doi.org/10.1007/s00604-022-05162-3
U. Amara, S. Riaz, K. Mahmood, N. Akhtar, M. Nasir et al., Copper oxide integrated perylene diimide self-assembled graphitic pencil for robust non-enzymatic dopamine detection. RSC Adv. 11(40), 25084–25095 (2021). https://doi.org/10.1039/D1RA03908C
I. Hussain, S. Iqbal, T. Hussain, W.L. Cheung, S.A. Khan et al., Zn-Co-MOF on solution-free CuO nanowires for flexible hybrid energy storage devices. Mater. Today Phys. 23, 100655 (2022). https://doi.org/10.1016/j.mtphys.2022.100655
I. Hussain, D. Mohapatra, G. Dhakal, C. Lamiel, M.S. Sayed et al., Uniform growth of ZnS nanoflakes for high-performance supercapacitor applications. J. Energy Storage 36, 102408 (2021). https://doi.org/10.1016/j.est.2021.102408
I. Hussain, S.G. Mohamed, A. Ali, N. Abbas, S.M. Ammar et al., Uniform growth of Zn-Mn-Co ternary oxide nanoneedles for high-performance energy-storage applications. J. Electroanal. Chem. 837, 39–47 (2019). https://doi.org/10.1016/j.jelechem.2019.01.052
W. Tian, Q. Gao, Y. Tan, K. Yang, L. Zhu et al., Bio-inspired beehive-like hierarchical nanoporous carbon derived from bamboo-based industrial by-product as a high performance supercapacitor electrode material. J. Mater. Chem. A 3(10), 5656–5664 (2015). https://doi.org/10.1039/C4TA06620K
D. Puthusseri, V. Aravindan, S. Madhavi, S. Ogale, 3D micro-porous conducting carbon beehive by single step polymer carbonization for high performance supercapacitors: the magic of in situ porogen formation. Energy Environ. Sci. 7(2), 728–735 (2014). https://doi.org/10.1039/C3EE42551G
J. Cao, J. Luo, P. Wang, X. Wang, W. Weng, Biomass-based porous carbon beehive prepared in molten KOH for capacitors. Mater. Technol. 35(9–10), 522–528 (2020). https://doi.org/10.1080/10667857.2019.1699270
L. Chang, Y.H. Hu, One-step synthesis of high surface-area honeycomb graphene clusters for highly efficient capacitive deionization. J. Phys. Chem. Solids 134, 64–68 (2019). https://doi.org/10.1016/j.jpcs.2019.05.040
X. Feng, Y. Huang, C. Li, Y. Xiao, X. Chen et al., Construction of carnations-like Mn3O4@NiCo2O4@NiO hierarchical nanostructures for high-performance supercapacitors. Electrochim. Acta 308, 142–149 (2019). https://doi.org/10.1016/j.electacta.2019.04.048
X. He, P. Liu, J. Liu, Y. Muhammad, M. Zhu et al., Facile synthesis of hierarchical N-doped hollow porous carbon whiskers with ultrahigh surface area via synergistic inner-outer activation for casein hydrolysate adsorption. J. Mater. Chem. B 5(46), 9211–9218 (2017). https://doi.org/10.1039/C7TB02345F
A. Gopalakrishnan, T.D. Raju, S. Badhulika, Green synthesis of nitrogen, sulfur-co-doped worm-like hierarchical porous carbon derived from ginger for outstanding supercapacitor performance. Carbon 168, 209–219 (2020). https://doi.org/10.1016/j.carbon.2020.07.017
Y. Wang, X. Tang, M. Han, Y. Li, Y. Zhang et al., One-step synthesis of the N and P co-doped nest-like mesoporous carbon by a microwave-assisted ultra-high temperature solvothermal method for supercapacitor application. ChemistrySelect 4(3), 1108–1116 (2019). https://doi.org/10.1002/slct.201803006
S.H. Park, S.B. Yoon, H.K. Kim, J.T. Han, H.W. Park et al., Spine-like nanostructured carbon interconnected by graphene for high-performance supercapacitors. Sci. Rep. 4, 6118 (2014). https://doi.org/10.1038/srep06118
J. Liu, H. Li, H. Zhang, Q. Liu, R. Li et al., Three-dimensional hierarchical and interconnected honeycomb-like porous carbon derived from pomelo peel for high performance supercapacitors. J. Solid State Chem. 257, 64–71 (2018). https://doi.org/10.1016/j.jssc.2017.07.033
Q. Liang, L. Ye, Z.H. Huang, Q. Xu, Y. Bai et al., A honeycomb-like porous carbon derived from pomelo peel for use in high-performance supercapacitors. Nanoscale 6(22), 13831–13837 (2014). https://doi.org/10.1039/C4NR04541F
H. Fan, W. Liu, W. Shen, Honeycomb-like composite structure for advanced solid state asymmetric supercapacitors. Chem. Eng. J. 326, 518–527 (2017). https://doi.org/10.1016/j.cej.2017.05.121
T. Liu, Y. Zheng, W. Zhao, L. Cui, J. Liu, Uniform generation of NiCo2S4 with 3D honeycomb-like network structure on carbon cloth as advanced electrode materials for flexible supercapacitors. J. Colloid Interface Sci. 556, 743–752 (2019). https://doi.org/10.1016/j.jcis.2019.08.094
C.M. Chen, Q. Zhang, X.C. Zhao, B. Zhang, Q.Q. Kong et al., Hierarchically aminated graphene honeycombs for electrochemical capacitive energy storage. J. Mater. Chem. 22(28), 14076–14084 (2012). https://doi.org/10.1039/c2jm31426f
P.X. Thinh, C. Basavaraja, D. Kim, Characterization and electrochemical behaviors of honeycomb-patterned poly (N-vinylcarbazole)/polystyrene composite films. Polym. Bull. 69(1), 81–94 (2012). https://doi.org/10.1007/s00289-012-0727-9
L.G. Beka, X. Li, X. Wang, C. Han, W. Liu, A hierarchical NiCo2S4 honeycomb/NiCo2S4 nanosheet core-shell structure for supercapacitor applications. RSC Adv. 9(55), 32338–32347 (2019). https://doi.org/10.1039/C9RA05840K
H.W. Nam, C.V.V.M. Gopi, S. Sambasivam, R. Vinodh, K.V.G. Raghavendra et al., Binder-free honeycomb-like FeMoO4 nanosheet arrays with dual properties of both battery-type and pseudocapacitive-type performances for supercapacitor applications. J. Energy Storage 27, 101055 (2020). https://doi.org/10.1016/j.est.2019.101055
E. Samuel, A. Aldalbahi, M. El-Newehy, H. El-Hamshary, S.S. Yoon, Nickel ferrite beehive-like nanosheets for binder-free and high-energy-storage supercapacitor electrodes. J. Alloys Compd. 852, 156929 (2021). https://doi.org/10.1016/j.jallcom.2020.156929
L. Yao, G. Yang, P. Han, Z. Tang, J. Yang, Three-dimensional beehive-like hierarchical porous polyacrylonitrile-based carbons as a high performance supercapacitor electrodes. J. Power Sources 315, 209–217 (2016). https://doi.org/10.1016/j.jpowsour.2016.03.006
M. Ding, G. Chen, W. Xu, C. Jia, H. Luo, Bio-inspired synthesis of nanomaterials and smart structures for electrochemical energy storage and conversion. Nano Mater. Sci. 2(3), 264–280 (2020). https://doi.org/10.1016/j.nanoms.2019.09.011
A. Zhang, H. Bai, L. Li, Breath figure: a nature-inspired preparation method for ordered porous films. Chem. Rev. 115(18), 9801–9868 (2015). https://doi.org/10.1021/acs.chemrev.5b00069
Q. Zhang, X. Yang, P. Li, G. Huang, S. Feng et al., Bioinspired engineering of honeycomb structure-using nature to inspire human innovation. Prog. Mater. Sci. 74, 332–400 (2015). https://doi.org/10.1016/j.pmatsci.2015.05.001
D.R. Kumar, K.R. Prakasha, A.S. Prakash, J.J. Shim, Direct growth of honeycomb-like NiCo2O4@Ni foam electrode for pouch-type high-performance asymmetric supercapacitor. J. Alloys Compd. 836, 155370 (2020). https://doi.org/10.1016/j.jallcom.2020.155370
X. Wu, L. Jiang, C. Long, Z. Fan, From flour to honeycomb-like carbon foam: carbon makes room for high energy density supercapacitors. Nano Energy 13, 527–536 (2015). https://doi.org/10.1016/j.nanoen.2015.03.013
Z. Lv, Y. Tang, Z. Zhu, J. Wei, W. Li et al., Honeycomb-lantern-inspired 3D stretchable supercapacitors with enhanced specific areal capacitance. Adv. Mater. 30(50), 1805468 (2018). https://doi.org/10.1002/adma.201805468
S. Sun, J. Luo, Y. Qian, Y. Jin, Y. Liu et al., Metal-organic framework derived honeycomb Co9S8@C composites for high-performance supercapacitors. Adv. Energy Mater. 8(25), 1801080 (2018). https://doi.org/10.1002/aenm.201801080
Z. Peng, X. Liu, H. Meng, Z. Li, B. Li et al., Design and tailoring of the 3D macroporous hydrous RuO2 hierarchical architectures with a hard-template method for high-performance supercapacitors. ACS Appl. Mater. Interfaces 9(5), 4577–4586 (2017). https://doi.org/10.1021/acsami.6b12532
E. Raymundo-Piñero, M. Cadek, F. Béguin, Tuning carbon materials for supercapacitors by direct pyrolysis of seaweeds. Adv. Funct. Mater. 19(7), 1032–1039 (2009). https://doi.org/10.1002/adfm.200801057
Q. Wang, J. Yan, T. Wei, J. Feng, Y. Ren et al., Two-dimensional mesoporous carbon sheet-like framework material for high-rate supercapacitors. Carbon 60, 481–487 (2013). https://doi.org/10.1016/j.carbon.2013.04.067
T. Sun, L. Feng, X. Gao, L. Jiang, Bioinspired surfaces with special wettability. Acc. Chem. Res. 38(8), 644–652 (2005). https://doi.org/10.1021/ar040224c
L. Jiang, Y. Zhao, J. Zhai, A lotus-leaf-like superhydrophobic surface: a porous microsphere/nanofiber composite film prepared by electrohydrodynamics. Angwn. Chem. Int. Ed. 43(33), 4338–4341 (2004). https://doi.org/10.1002/anie.200460333
Y. Zheng, H. Bai, Z. Huang, X. Tian, F.Q. Nie et al., Directional water collection on wetted spider silk. Nature 463(7281), 640–643 (2010). https://doi.org/10.1038/nature08729
J. Sun, R.N. Zuckermann, Peptoid polymers: a highly designable bioinspired material. ACS Nano 7(6), 4715–4732 (2013). https://doi.org/10.1021/nn4015714
M.E. McConney, K.D. Anderson, L.L. Brott, R.R. Naik, V.V. Tsukruk, Bioinspired material approaches to sensing. Adv. Funct. Mater. 19(16), 2527–2544 (2009). https://doi.org/10.1002/adfm.200900606
X. Deng, S. Zhu, J. Li, F. He, E. Liu et al., Bio-inspired three-dimensional carbon network with enhanced mass-transfer ability for supercapacitors. Carbon 143, 728–735 (2018). https://doi.org/10.1016/j.carbon.2018.11.055
X. Deng, S. Zhu, J. Li, F. He, E. Liu et al., Bio-inspired three-dimensional carbon network with enhanced mass-transfer ability for supercapacitors. Carbon 143, 728–735 (2019). https://doi.org/10.1016/j.carbon.2018.11.055
S. Boukhalfa, K. Evanoff, G. Yushin, Atomic layer deposition of vanadium oxide on carbon nanotubes for high-power supercapacitor electrodes. Energy Environ. Sci. 5(5), 6872–6879 (2012). https://doi.org/10.1039/c2ee21110f
M.A. Elsaid, A.Z. Sayed, A.M. Ashmawy, A.A. Hassan, A.F. Waheed et al., Hierarchically nanocoral reefs-like ZnCo2S4 deposited on Ni foam as an electrode material for high-performance battery-type symmetric supercapacitor. Bull. Tabbin Inst. Metall. Stud. (2022). https://doi.org/10.21608/tims.2022.147815.1003
M.S. Javed, A. Mateen, S. Ali, X. Zhang, I. Hussain et al., The emergence of 2D MXenes based Zn-ion batteries: recent development and prospects. Small 18(26), 2201989 (2022). https://doi.org/10.1002/smll.202201989
I. Hussain, D. Mohapatra, G. Dhakal, C. Lamiel, S.G. Mohamed et al., Different controlled nanostructures of Mn-doped ZnS for high-performance supercapacitor applications. J. Energy Storage 32, 101767 (2020). https://doi.org/10.1016/j.est.2020.101767
I. Hussain, C. Lamiel, N. Qin, S. Gu, Y. Li et al., Development of vertically aligned trimetallic Mg-Ni-Co oxide grass-like nanostructure for high-performance energy storage applications. J. Colloid Interface Sci. 582, 782–792 (2020). https://doi.org/10.1016/j.jcis.2020.08.064
M.S. Javed, T. Najim, I. Hussain, S. Batool, M. Idrees et al., 2D V2O5 nanoflakes as a binder-free electrode material for high-performance pseudocapacitor. Ceram. Int. 47(17), 25152–25157 (2021). https://doi.org/10.1016/j.ceramint.2021.05.181
R. Manikandan, C.J. Raj, M. Rajesh, B.C. Kim, G. Nagaraju et al., Rationally designed spider web-like trivanadium heptaoxide nanowires on carbon cloth as a new class of pseudocapacitive electrode for symmetric supercapacitors with high energy density and ultra-long cyclic stability. J. Mater. Chem. A 6(24), 11390–11404 (2018). https://doi.org/10.1039/C8TA03011A
P. Sun, W. He, H. Yang, R. Cao, J. Yin et al., Hedgehog-inspired nanostructures for hydrogel-based all-solid-state hybrid supercapacitors with excellent flexibility and electrochemical performance. Nanoscale 10(40), 19004–19013 (2018). https://doi.org/10.1039/C8NR04919J
Y. Tao, L. Zaijun, L. Ruiyi, N. Qi, K. Hui et al., Nickel-cobalt double hydroxides microspheres with hollow interior and hedgehog-like exterior structures for supercapacitors. J. Mater. Chem. 22(44), 23587–23592 (2012). https://doi.org/10.1039/c2jm35263j
H. Wan, J. Jiang, Y. Ruan, J. Yu, L. Zhang et al., Direct formation of hedgehog-like hollow Ni-Mn oxides and sulfides for supercapacitor electrodes. Part. Part. Syst. Charact. 31(8), 857–862 (2014). https://doi.org/10.1002/ppsc.201400020
Y. Luo, J. Jiang, W. Zhou, H. Yang, J. Luo et al., Self-assembly of well-ordered whisker-like manganese oxide arrays on carbon fiber paper and its application as electrode material for supercapacitors. J. Mater. Chem. 22(17), 8634–8640 (2012). https://doi.org/10.1039/c2jm16419a
J. Wei, J. Zhang, Y. Liu, G. Xu, Z. Chen et al., Controlled growth of whisker-like polyaniline on carbon nanofibers and their long cycle life for supercapacitors. RSC Adv. 3(12), 3957–3962 (2013). https://doi.org/10.1039/c3ra23040f
Y. Tang, Y. Liu, W. Guo, S. Yu, F. Gao, Floss-like Ni-Co binary hydroxides assembled by whisker-like nanowires for high-performance supercapacitor. Ionics 21(6), 1655–1663 (2015). https://doi.org/10.1007/s11581-014-1319-5
K. Khawas, P. Kumari, S. Daripa, R. Oraon, B.K. Kuila, Hierarchical polyaniline-MnO2-reduced graphene oxide ternary nanostructures with whiskers-like polyaniline for supercapacitor application. ChemistrySelect 2(35), 11783–11789 (2017). https://doi.org/10.1002/slct.201702345
X. Chen, D. Chen, X. Guo, R. Wang, H. Zhang, Facile growth of caterpillar-like NiCo2S4 nanocrystal arrays on nickle foam for high-performance supercapacitors. ACS Appl. Mater. Interfaces 9(22), 18774–18781 (2017). https://doi.org/10.1021/acsami.7b03254
Y. Yang, Y. Hao, J. Yuan, L. Niu, F. Xia, In situ preparation of caterpillar-like polyaniline/carbon nanotube hybrids with core shell structure for high performance supercapacitors. Carbon 78, 279–287 (2014). https://doi.org/10.1016/j.carbon.2014.07.004
Z. Liu, K. Xiao, H. Guo, X. Ning, A. Hu et al., Nitrogen-doped worm-like graphitized hierarchical porous carbon designed for enhancing area-normalized capacitance of electrical double layer supercapacitors. Carbon 117, 163–173 (2017). https://doi.org/10.1016/j.carbon.2017.02.087
D. Yuan, J. Chen, S. Tan, N. Xia, Y. Liu, Worm-like mesoporous carbon synthesized from metal-organic coordination polymers for supercapacitors. Electrochem. Commun. 11(6), 1191–1194 (2009). https://doi.org/10.1016/j.elecom.2009.03.045
X. Tian, X. Li, T. Yang, K. Wang, H. Wang et al., Porous worm-like NiMoO4 coaxially decorated electrospun carbon nanofiber as binder-free electrodes for high performance supercapacitors and lithium-ion batteries. Appl. Surf. Sci. 434, 49–56 (2018). https://doi.org/10.1016/j.apsusc.2017.09.153
P. Yang, Y. Li, Z. Lin, Y. Ding, S. Yue et al., Worm-like amorphous MnO2 nanowires grown on textiles for high-performance flexible supercapacitors. J. Mater. Chem. A 2(3), 595–599 (2014). https://doi.org/10.1039/C3TA14275B
N. Tantawy, F.E.T. Heakal, S. Ahmed, Synthesis of worm-like binary metallic active material by electroless deposition approach for high-performance supercapacitor. J. Energy Storage 31, 101625 (2020). https://doi.org/10.1016/j.est.2020.101625
L. Jinlong, L. Tongxiang, Y. Meng, K. Suzuki, H. Miura, The plume-like Ni3S2 supercapacitor electrodes formed on nickel foam by catalysis of thermal reduced graphene oxide. J. Electroanal. Chem. 786, 8–13 (2017). https://doi.org/10.1016/j.jelechem.2017.01.004
J.Y. Liang, C.C. Wang, S.Y. Lu, Glucose-derived nitrogen-doped hierarchical hollow nest-like carbon nanostructures from a novel template-free method as an outstanding electrode material for supercapacitors. J. Mater. Chem. A 3(48), 24453–24462 (2015). https://doi.org/10.1039/C5TA08007J
D. Dubal, C. Lokhande, Significant improvement in the electrochemical performances of nano-nest like amorphous MnO2 electrodes due to Fe doping. Ceram. Int. 39(1), 415–423 (2013). https://doi.org/10.1016/j.ceramint.2012.06.042
S.F. Shaikh, F.F. Shaikh, A.V. Shaikh, M. Ubaidullah, A.M. Al-Enizi et al., Electrodeposited more-hydrophilic nano-nest polyaniline electrodes for supercapacitor application. J. Phys. Chem. Solids 149, 109774 (2021). https://doi.org/10.1016/j.jpcs.2020.109774
D. Zhao, Q. Zhu, D. Chen, X. Li, Y. Yu et al., Nest-like V3O7 self-assembled by porous nanowires as an anode supercapacitor material and its performance optimization through bonding with n-doped Carbon. J. Mater. Chem. A 6(34), 16475–16484 (2018). https://doi.org/10.1039/C8TA06820H
L. Mi, W. Wei, S. Huang, S. Cui, W. Zhang et al., A nest-like Ni@Ni1.4Co1.6S2 electrode for flexible high-performance rolling supercapacitor device design. J. Mater. Chem. A 3(42), 20973–20982 (2015). https://doi.org/10.1039/C5TA06265A
F. Ran, H. Fan, L. Wang, L. Zhao, Y. Tan et al., A bird nest-like manganese dioxide and its application as electrode in supercapacitors. J. Energy Chem. 22(6), 928–934 (2013). https://doi.org/10.1016/S2095-4956(14)60274-6
Y. Huang, F. Cui, Y. Zhao, J. Lian, J. Bao et al., NiMoO4 nanorod deposited carbon sponges with ant-nest-like interior channels for high-performance pseudocapacitors. Inorg. Chem. Front. 5(7), 1594–1601 (2018). https://doi.org/10.1039/C8QI00247A
F. Miao, N. Lu, P. Zhang, Z. Zhang, G. Shao, Multidimension-controllable synthesis of ant nest-structural electrode materials with unique 3D hierarchical porous features toward electrochemical applications. Adv. Funct. Mater. 29(29), 1808994 (2019). https://doi.org/10.1002/adfm.201808994
Q. Lu, X. Wang, M. Chen, B. Lu, M. Liu et al., Manganese dioxide/ant-nest-like hierarchical porous carbon composite with robust supercapacitive performances. ACS Sustain. Chem. Eng. 6(6), 7362–7371 (2018). https://doi.org/10.1021/acssuschemeng.7b04492
F. Wang, L. Chen, H. Li, G. Duan, S. He et al., N-doped honeycomb-like porous carbon towards high-performance supercapacitor. Chin. Chem. Lett. 31(7), 1986–1990 (2020). https://doi.org/10.1016/j.cclet.2020.02.020
Y. Wang, Z. Zhao, W. Song, Z. Wang, X. Wu, From biological waste to honeycomb-like porous carbon for high energy density supercapacitor. J. Mater. Sci. 54(6), 4917–4927 (2019). https://doi.org/10.1007/s10853-018-03215-8
X. Ren, C. Guo, L. Xu, T. Li, L. Hou et al., Facile synthesis of hierarchical mesoporous honeycomb-like NiO for aqueous asymmetric supercapacitors. ACS Appl. Mater. Interfaces 7(36), 19930–19940 (2015). https://doi.org/10.1021/acsami.5b04094
G.K. Veerasubramani, A. Chandrasekhar, M. Sudhakaran, Y.S. Mok, S.J. Kim, Liquid electrolyte mediated flexible pouch-type hybrid supercapacitor based on binderless core-shell nanostructures assembled with honeycomb-like porous Carbon. J. Mater. Chem. A 5(22), 11100–11113 (2017). https://doi.org/10.1039/C7TA01308F
J. Wang, F. Qin, Z. Guo, W. Shen, Oxygen- and nitrogen-enriched honeycomb-like porous carbon from Laminaria japonica with excellent supercapacitor performance in aqueous solution. ACS Sustain. Chem. Eng. 7(13), 11550–11563 (2019). https://doi.org/10.1021/acssuschemeng.9b01448
A. Ali, M. Aadil, A. Rasheed, I. Hameed, S. Ajmal et al., Honeycomb like architectures of the Mo doped ZnS@Ni for high-performance asymmetric supercapacitors applications. Synth. Met. 265, 116408 (2020). https://doi.org/10.1016/j.synthmet.2020.116408
R. Kumar, S.M. Youssry, H.M. Soe, M.M. Abdel-Galeil, G. Kawamura et al., Honeycomb-like open-edged reduced-graphene-oxide-enclosed transition metal oxides (NiO/Co3O4) as improved electrode materials for high-performance supercapacitor. J. Energy Storage 30, 101539 (2020). https://doi.org/10.1016/j.est.2020.101539
X. Dong, Y. Yu, X. Jing, H. Jiang, T. Hu et al., Sandwich-like honeycomb Co2SiO4/rGO/honeycomb Co2SiO4 structures with enhanced electrochemical properties for high-performance hybrid supercapacitor. J. Power Sources 492, 229643 (2021). https://doi.org/10.1016/j.jpowsour.2021.229643
L. Du, W. Du, H. Ren, N. Wang, Z. Yao et al., Honeycomb-like metallic nickel selenide nanosheet arrays as binder-free electrodes for high-performance hybrid asymmetric supercapacitors. J. Mater. Chem. A 5(43), 22527–22535 (2017). https://doi.org/10.1039/C7TA06921A
L. Cao, S. Yang, W. Gao, Z. Liu, Y. Gong et al., Direct laser-patterned micro-supercapacitors from paintable MoS2 films. Small 9(17), 2905–2910 (2013). https://doi.org/10.1002/smll.201203164
X. Chen, S. Wang, J. Shi, X. Du, Q. Cheng et al., Direct laser etching free-standing MXene-MoS2 film for highly flexible micro-supercapacitor. Adv. Mater. Interfaces 6(22), 1901160 (2019). https://doi.org/10.1002/admi.201901160
S.K. Kim, H.J. Koo, A. Lee, P.V. Braun, Selective wetting-induced micro-electrode patterning for flexible micro-supercapacitors. Adv. Mater. 26(30), 5108–5112 (2014). https://doi.org/10.1002/adma.201401525
L. Liu, D. Ye, Y. Yu, L. Liu, Y. Wu, Carbon-based flexible micro-supercapacitor fabrication via mask-free ambient micro-plasma-jet etching. Carbon 111, 121–127 (2017). https://doi.org/10.1016/j.carbon.2016.09.037
W. Sun, X. Chen, Preparation and characterization of polypyrrole films for three-dimensional micro supercapacitor. J. Power Sources 193(2), 924–929 (2009). https://doi.org/10.1016/j.jpowsour.2009.04.063
D. Qi, Y. Liu, Z. Liu, L. Zhang, X. Chen, Design of architectures and materials in in-plane micro-supercapacitors: current status and future challenges. Adv. Mater. 29(5), 1602802 (2017). https://doi.org/10.1002/adma.201602802
S. Wang, N. Liu, J. Rao, Y. Yue, K. Gao et al., Vertical finger-like asymmetric supercapacitors for enhanced performance at high mass loading and inner integrated photodetecting systems. J. Mater. Chem. A 5(42), 22199–22207 (2017). https://doi.org/10.1039/C7TA06306G
A.V. Salkar, A.P. Naik, S.V. Bhosale, P.P. Morajkar, Designing a rare DNA-like double helical microfiber superstructure via self-assembly of in situ carbon fiber-encapsulated Wo3-x nanorods as an advanced supercapacitor material. ACS Appl. Mater. Interfaces 13(1), 1288–1300 (2020). https://doi.org/10.1021/acsami.0c21105
P. Avasthi, V. Balakrishnan, Electroless growth of high surface area Au dendrites with corrugated edge structure for hybrid supercapacitor applications. ChemistrySelect 3(13), 3866–3870 (2018). https://doi.org/10.1002/slct.201703132
H. Pang, F. Gao, Q. Chen, R. Liu, Q. Lu, Dendrite-like Co3O4 nanostructure and its applications in sensors, supercapacitors and catalysis. Dalton Transact. 41(19), 5862–5868 (2012). https://doi.org/10.1039/c2dt12494g
Y. Zhao, M. Dai, D. Zhao, L. Xiao, X. Wu et al., Asymmetric pseudo-capacitors based on dendrite-like MnO2 nanostructures. CrystEngComm 21(21), 3349–3355 (2019). https://doi.org/10.1039/C9CE00423H
Z. Sun, S. Firdoz, E.Y.X. Yap, L. Li, X. Lu, Hierarchically structured MnO2 nanowires supported on hollow Ni dendrites for high-performance supercapacitors. Nanoscale 5(10), 4379–4387 (2013). https://doi.org/10.1039/c3nr00209h
S. Iqbal, A.H. Mady, U. Javed, P.M. Shafi, N.V. Quang et al., Self-templated hollow nanospheres of b-site engineered non-stoichiometric perovskite for supercapacitive energy storage via anion-intercalation mechanism. J. Colloid Interface Sci. 600, 729–739 (2021). https://doi.org/10.1016/j.jcis.2021.03.147
I. Hussain, J.M. Lee, S. Iqbal, H.S. Kim, S.W. Jang et al., Preserved crystal phase and morphology: electrochemical influence of copper and iron co-doped cobalt oxide and its supercapacitor applications. Electrochim. Acta 340, 135953 (2020). https://doi.org/10.1016/j.electacta.2020.135953
I. Hussain, C. Lamiel, M. Ahmad, Y. Chen, S. Shuang et al., High entropy alloys as electrode material for supercapacitors: a review. J. Energy Storage 44, 103405 (2021). https://doi.org/10.1016/j.est.2021.103405
T.S. Mathis, N. Kurra, X. Wang, D. Pinto, P. Simon et al., Energy storage data reporting in perspective-guidelines for interpreting the performance of electrochemical energy storage systems. Adv. Energy Mater. 9(39), 1902007 (2019). https://doi.org/10.1002/aenm.201902007
Acknowledgements
This work was supported by the Donations for Research Projects_RMGS (project number 9229006). M.A.A. expresses appreciation to the Deanship of Scientific Research at King Khalid University Saudi Arabia (R.G.P. 2/40/43).
Funding
Open access funding provided by Shanghai Jiao Tong University.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
About this article
Cite this article
Hussain, I., Lamiel, C., Sahoo, S. et al. Animal- and Human-Inspired Nanostructures as Supercapacitor Electrode Materials: A Review. Nano-Micro Lett. 14, 199 (2022). https://doi.org/10.1007/s40820-022-00944-z
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s40820-022-00944-z