Abstract
The discharging of lead-contaminated wastewater is a concern because of its toxicity to living organisms and water quality resulting in dangerous water consumption, so it is highly recommended to remove lead from wastewater to be below water quality standards for a safe environment. Zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) were synthesized and characterized in various techniques. Their lead removal efficiencies were investigated by batch experiments, adsorption isotherms, and kinetics. The specific surface area, pore volume, and pore size of ZB were close values to zeolite A standard (STD), and ZBF had the highest specific surface area and the smallest pore size than others. ZB and ZBF demonstrated crystalline phases whereas ZBB, ZBFB, and ZBBF were amorphous phases. The surface morphology of ZB was a cubic shape similar to STD. ZBF demonstrated an agglomerated formation of ZB and iron(III) oxide-hydroxide whereas ZBFB and ZBBF had sphere shapes with coarse surfaces. Si, Al, O, Fe, Na, Ca, O–H, (Si, Al)–O, H2O, and D4R were detected in all materials. The surface charges of all zeolite A materials had negatively charged at all pH values, and their surfaces increased more negatively charged with increasing pH value which pH 5 illustrated as the highest negatively charged in all materials. Their lead removal efficiencies were higher than 82%. Langmuir isotherm and pseudo-second-order kinetic models were well explained for their adsorption patterns and mechanisms. Finally, ZBBF is a good offer for applying in industrial wastewater treatment systems because of its easy operation and saving costs than ZBF.
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Discover the latest articles, news and stories from top researchers in related subjects.Introduction
Lead contamination in wastewater causes a serious environmental problem to water quality, aquatic organisms, and the environment because of its toxicity, bioaccumulation, and non-degradation. Lead can accumulate through a food chain and causes many dysfunctional systems of nervous, reproductive, blood, respiration, and tissue in humans from human consumption and water use1,2. The sources of lead contamination in the environment may be from many industries of battery, paint, steel, and plastic, so their effluents may have lead contamination that needed to remediate before discharging into the environment. Therefore, the lead-contaminated wastewater requires to treat below 0.02 mg/L following USEPA standards for a safe ecosystem in terms of environmental remediation.
Many conventional methods have been used to eliminate heavy metals in wastewater such as coagulation-flocculation, chemical precipitation, ion exchange, oxidation–reduction, and reverse osmosis; however, they have disadvantages of high-cost operation, highly required energy, creating a lot of sludge, and complicated operations3. While an adsorption method is a good method with high efficiency, reasonable cost, easy operation, low waste sludge, and many available choices of adsorbents4, so this method is a suitable choice for remediating heavy metal in wastewater. Various adsorbents of commercial, natural, wastes of agriculture, industrial, and food have been used for removing heavy metals contaminated from wastewater such as activated carbon, zeolite, chitosan, walnut shells, bagasse, eggshells, banana peels, lemon peels, potato peels, coal fly ash, sawdust, and bagasse fly ash. Especially, wastes from agriculture, industry, and food have been popularly used for eliminating both cationic and anionic heavy metals. For agriculture wastes, corncob, rice husk, peanut shell, coconut shell, and sugarcane bagasse were used for removing lead (Pb), nickel (Ni), copper (Cu), chromium (Cr), and arsenic (As) in wastewater5,6,7,8,9,10. The peels of potato, banana, and lemon are used as food waste adsorbents for lead removal11,12,13. For industrial wastes, sawdust, coal fly ash, and sugarcane bagasse fly ash have been used for removing lead and arsenic in an aqueous solution14,15,16,17. Therefore, adsorbents from waste are an interesting choice because not only they help to improve water quality for environmental remediation purposes but also using them is another benefit to waste treatment and management in terms of recycling natural resources. Especially, industrial wastes with a big load of waste, if they can be used for another benefit, their waste management can be highly reduced as well.
Sugarcane bagasse fly ash is a waste from sugar factories that has the main chemical elements of silicon (Si), aluminum (Al), iron (Fe), calcium (Ca), magnesium (Mg), potassium (K), and trace elements18. The high Si and Al contents in sugarcane bagasse fly ash can be used to synthesize zeolite-type adsorbents for removing heavy metals from wastewater. Especially, zeolite type A gives high heavy metal removals because of its higher surface area with small pore size and high adsorption capacity than other types, so it promotes good adsorption of heavy metals19. In previous studies, the synthesized zeolite P from bagasse fly ash is used for eliminating lead and cadmium in an aqueous solution20, and the removal of copper is reported by the study of Oliveira et al. by the synthesized zeolite Na-A from sugarcane bagasse fly ash21. In addition, the synthesized zeolite A from bagasse fly ash and sugarcane waste ash have been used for removing lead and cadmium in wastewater19,22. Although zeolites can adsorb with various toxic metals, improving zeolites to increase adsorption capacity with specific target contaminates is continuously interested. The natural zeolite modified with amine is used for remediating hexavalent chromium (Cr (VI)) in an aqueous media, and MEL-type zeolite nanosheet has been applied as a porous material for water purification from landfill leachate comprising PbCl2 and CuCl223,24. Moreover, many previous studies have been used various metal oxides of copper oxide (CuO), manganese oxide (MnO2), titanium dioxide (TiO2), iron (II or III) oxide (Fe2O3 or Fe3O4), and iron-zirconium (ZrFe2). For the removals of cadmium (Cd2+), arsenic (As5+), chromium (Cr2+), iron (Fe3+), and manganese (Mn2+) ions in wastewater, zeolite Na-X modified with Fe3O4, zeolite W modified with iron-zirconium, natural zeolite modified with Fe3O4, and zeolite 4A modified with titanium dioxide have been applied25,26,27,28,29. For the removal of lead (Pb2+) ion in an aqueous solution, many studies have used commercial zeolite modified with CuO and Fe3O4, natural zeolite modified with MnO2 and iron oxide, and zeolite Na-X modified with Fe3O425,30,31,32. However, no one added iron(III) oxide-hydroxide along with changing material form to improve zeolite A adsorbent for eliminating lead contamination in an aqueous solution. Thus, this study attempted to achieve this purpose by synthesizing novel zeolite A materials from sugarcane bagasse fly ash and investigating their lead removal efficiencies to offer whether adding metal oxide or changing material form help to increase material efficiency. These new zeolite A adsorbents might be a guideline for applying in industries for increasing lead removal efficiency in wastewater in the future as a low-cost adsorbent from industrial waste to achieve both remediating environmental contaminant and reducing waste management.
This study aimed to synthesize five zeolite A adsorbent materials which were zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) from sugarcane bagasse fly ash for removing lead-contaminated in an aqueous solution. Various characterized techniques of Brunauer–Emmett–Teller (BET), X-ray diffractometer (XRD), Field emission scanning electron microscopy, and focus ion beam (FESEM-FIB) with Energy dispersive X-ray spectrometer (EDX), Fourier transform infrared spectroscopy (FT-IR), and Zetasizer Nano were used to investigate their specific surface area, pore volumes, pore sizes, crystalline structures, surface morphologies, chemical compositions, chemical functional groups, and surface charges. Their lead removal efficiencies were studied through batch experiments, and their adsorption patterns and mechanisms were also determined by linear and nonlinear adsorption isotherms and kinetics.
Results and discussions
The physical characteristics
The physical characteristics of zeolite A standard (STD), zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) are illustrated in Fig. 1a–f. ZB was a white color powder similar to STD demonstrated in Fig. 1a,b. For ZBF, it was an iron-rust color powder correlated to a color of iron(III) oxide-hydroxide added into ZB shown in Fig. 1c. For bead materials, they had sphere shapes with different colors. ZBB was a white beaded color matching the color of ZB presented in Fig. 1d. For ZBFB and ZBBF, they were a light-brown beaded color and a dark-brown beaded color, so the adding iron(III) oxide-hydroxide method might affect a material color shown in Fig. 1e,f, respectively.
Brunauer–Emmett–Teller (BET) analysis
The specific surface area, pore volume, and pore size of zeolite A standard (STD), zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) by BET analysis are demonstrated in Table 1. For ZB, it had the specific surface area, pore volume, and pore size are close values to STD which could confirm the ability to synthesize zeolite A from sugarcane bagasse fly ash in this study. For ZBF, its specific surface area and pore volume were increased to 10 times of ZB whereas its pore size was decreased. Thus, it might be possible that ZBF might adsorb lead higher than ZB because it had higher specific surface area and smaller pore size than ZB corresponded to the specific characteristic of a highly efficient adsorbent12. As a result, the addition of iron(III) oxide-hydroxide helped to improve material efficiency by increasing specific surface area and decreasing pore size. For ZBB, its specific surface area and pore volume were decreased while its pore size was increased when it was compared to ZB. Thus, the changing material form affected the decreasing specific surface area and pore volume which might result in the decreasing lead removal efficiency. For ZBFB, its specific surface area and pore volume were decreased by approximately 30% and 60% of ZBF while its pore size was increased by approximately 13% of ZBF. For ZBBF, its specific surface area and pore volume were decreased by approximately 20% and 38% of ZBF while its pore size was increased by approximately 10% of ZBF. As a result, the adding iron(III) oxide-hydroxide method into ZB along with changing material form from powder to bead form affected the physiochemical properties of zeolite materials. The coating method was a smaller effect than the mixing method which meant ZBBF might have a higher lead removal efficiency than ZBFB. Finally, all zeolite A materials were classified to be mesoporous size (2–50 nm) followed by the pore dimension identified by the International Union of Pure and Applied Chemistry (IUPAC)33.
X-ray diffractometer (XRD) analysis
The crystalline formations of zeolite A standard (STD), zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) by XRD analysis are illustrated in Fig. 2a–f. For STD, it was a crystalline phase represented the specific peaks of zeolite A of 7.13°, 10.11°, 12.28°, 16.09°, 21.42°, 24.13°, 26.09°, 27.05°, 30.00°, 30.53°, 31.96°, 32.98° and 33.86° corresponding to JCPDS No. 39-22234 shown in Fig. 2a. ZB demonstrated a crystalline phase and found specific peaks of zeolite A similar to STD shown in Fig. 2b, so it could be confirmed the ability of zeolite A synthesis from sugarcane bagasse fly ash. For ZBF, it was a crystalline phase similar to ZB and also found specific peaks of iron(III) oxide-hydroxide of 21.05°, 26.88°, 33.12°, 36.58°, and 41.65° matched to JCPDS No. 29-071335 shown in Fig. 2c which it could confirm the ability to add iron(III) oxide-hydroxide into ZB. For ZBB, it was an amorphous phase and found specific peaks of alginate of 13.54°, 18.38°, 21.56°, and 38.22°36 shown in Fig. 2d which could confirm the occurrence of the bead formation in ZBB. For ZBFB, it was an amorphous phase and found both specific peaks of iron(III) oxide-hydroxide and alginate with previously mentioned above, so it could be confirmed the ability of both adding iron(III) oxide-hydroxide and bead formation in ZBFB shown in Fig. 2e. Finally, ZBBF displayed the amorphous phase with detecting both specific peaks of iron(III) oxide-hydroxide and alginate similarly to ZBFB shown in Fig. 2f.
Field emission scanning electron microscopy and focus ion beam (FESEM-FIB) analysis
FESEM-FIB micrographs of zeolite A standard (STD), zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) by FESEM-FIB analysis are demonstrated in Fig. 3a–i which the surface morphologies of STD, ZB, and ZBF were investigated by FESEM-FIB at 800 ×, 1500 ×, 1500 × magnification with 100 µm, respectively whereas the surface morphologies of ZBB, ZBFB, and ZBBF were investigated by FESEM-FIB at 130 × magnification with 1 mm and 2500 × magnification with 50 µm. ZB had a cubic shape similar to STD which corresponded to the specific structure shape of zeolite A19 shown in Fig. 3a,b, so it could confirm that ZB was zeolite A and corresponded to the BET and XRD results. For ZBF, they have agglomerated formation of ZB and iron(III) oxide-hydroxide which precipitated iron(III) oxide-hydroxide on the surface of ZBF shown in Fig. 3c similarly found in another study37. For ZBB, ZBFB, and ZBBF, they had sphere shapes with coarse surfaces at 130 × magnification with 1 mm shown in Fig. 3d–f. In 2500 × magnification with 50 µm, ZBB agglomerated formation and clumped together of ZB and sodium alginate which might be from changing material form presented in Fig. 3g whereas ZBFB and ZBBF were heterogeneous and coarse surfaces shown in Fig. 3h,i.
Energy dispersive X-ray spectrometer (EDX) analysis
The chemical compositions of zeolite A standard (STD), zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) by EDX analysis are displayed in Table 2, and the dispersions of chemical elements of each zeolite A material on the surface are shown by the elemental mapping in Fig. 4a–f. Six main elements were detected in all materials which were silicon (Si), aluminum (Al), oxygen (O), iron (Fe), sodium (Na), and calcium (Ca). In addition, potassium (K) was only found in STD and ZB whereas chloride was observed in all materials except STD and ZB. Since ZB had main chemical compositions and close percentage by weight similar to STD, it also confirmed ZB was a zeolite A. Especially, the ratio of Si/Al of ZB was close to 1 corresponding to the specific ratio of Si/Al indicating zeolite type A followed the reports of the previous study19. For ZBF, it had main chemical elements similar to ZB except K was disappearance. However, the percentages by weight of Si, Al, and O were decreased whereas the percentages by weight of Fe, Na, and Cl were increased because of chemical uses of ferric chloride hexahydrate (FeCl3·6H2O) and sodium hydroxide (NaOH) in a process of adding iron(III) oxide-hydroxide into ZB. For ZBB, the percentages by weight of Si, Al, O, and Fe were decreased whereas the percentages by weight of Na, Ca, and Cl were increased when compared to ZB because of the chemical uses of sodium alginate and calcium chloride (CaCl2) in a bead formation process. Thus, the changing material form affected the increase of Na, Ca, and Cl in ZBB. For ZBFB, the percentages by weight of Si, Al, Na, Ca, and Cl were increased whereas the percentages by weight of O and Fe were decreased when compared to ZBF. For ZBBF, the percentages by weight of Si, Al, O, Na, Ca, and Cl were decreased whereas the percentages by weight of Fe were increased when compared to ZBB. Therefore, the different methods of adding iron(III) oxide-hydroxide affected the percentages by weight of main chemical compositions of zeolite A materials which the results demonstrated that adding iron(III) oxide-hydroxide by coating method could be added iron (Fe) into zeolite A material more than the mixing method.
Fourier transform infrared spectroscopy (FT-IR) analysis
FT-IR spectra of zeolite A standard (STD), zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) with the infrared wavelengths of 4000–400 cm−1 are shown in Fig. 5a–f. Four main chemical functional groups of O–H, H2O, (Si, Al)–O, and D4R were detected in all materials. In addition, Si–O–Fe and –COOH were found in materials with adding iron(III) oxide-hydroxide or bead materials. For STD and ZB, they found the same functional groups of O–H of 3480–3450 cm−1, (Si, Al)–O asymmetric stretching of 1007–1000 cm−1, (Si, Al)–O symmetric stretching of 683–680 cm−1, double four-ring (D4R) of 577-571 cm−1 and Si, Al–O bending of 478–444 cm−1 shown in Fig. 5a and b similarly found in another study19. D4R generally presents the cubic prism formation of zeolite A crystal38, so it could be confirmed the presence of zeolite A. Moreover, α-cage, which is the fundamental structure that is linked with D4R, confirms the structure of zeolite A39. Since the functional groups of ZB were similar to STD, it could be confirmed the ability of zeolite A synthesis by sugarcane bagasse fly ash. For ZBF, ZBB, ZBFB, and ZBBF, they also found the main chemical functional groups similar to STD and ZB; however, they also represented the specific chemical functional groups of adding iron(III) oxide-hydroxide and bead formation. For ZBF, it observed the specific chemical functional groups of Si–O–Fe at 971.31 cm−1 which linked to the development of the Si–O–Fe bond into ZB similarly reported by other studies40,41 shown in Fig. 5c. For ZBB, it detected the specific chemical functional groups of –COOH symmetric stretching at 1492.47 cm−142 shown in Fig. 5d. Finally, ZBFB and ZBBF found the specific chemical functional groups of both Si–O–Fe at 972.98–972.14 cm−1 and –COOH symmetric stretching at 1475.50–1474.43 cm−1 shown in Fig. 5e and f which were the coordination of alginate with iron(III) oxide-hydroxide similarly reported the carboxyl groups of alginate in an aqueous solution coupled with Fe ion42.
The surface charges of zeolite A materials by zeta potential analysis
The zeta potential analysis was used for determining the surface charges of zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) by a Zetasizer Nano under different pH values of 1, 3, 5, 7, 9, and 11, and the results are illustrated in Fig. 6. The zeta potential values of ZB, ZBF, ZBB, ZBFB, and ZBBF were approximately in ranges of − 3.70 to − 35.27 mV, − 5.53 to − 46.13 mV, − 2.62 to − 31.30 mV, − 4.63 to − 38.50 mV, and − 5.40 to − 43.40 mV, respectively which their surfaces were negative charges, so, they could adsorb lead ions. The increase of pH values from 1 to 5 affected the increase of negative charges on the surfaces of all zeolite A materials because of the highly deprotonating of a proton (H+) from hydroxyl groups (OH−) of zeolite A materials19. After pH 5, their surface charges were more positive charges on the surface which affected the decrease of their lead adsorptions. Especially, zeolite A materials modified with iron(III) oxide-hydroxide in powder and bead forms (ZBF, ZBFB, and ZBBF) had more negative charges on the surface than zeolite A materials without modification (ZB and ZBB), so ZBF, ZBFB, and ZBBF had higher lead adsorption than ZB and ZBB. In Fig. 6, the highest negatively charged of all zeolite A materials were found at pH 5 corresponding to another study that reported the high lead adsorption at pH 5 by zeolite A19. Moreover, ZBF demonstrated more negatively charged on the surface than other zeolite A materials in all pH values, so it could adsorb lead ions more than other zeolite A materials.
Batch adsorption studies
Lead removal efficiencies of zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide- hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide- hydroxide (ZBBF) were investigated by a series of batch experiments with affecting factors of dosage, contact time, pH, and initial lead concentration which their results demonstrated in Fig. 7a–d.
The effect of dosage
Figure 7a illustrated the results of does effect of ZB, ZBF, ZBB, ZBFB, and ZBBF on lead adsorptions with the control condition of the lead concentration of 50 mg/L, a sample volume of 200 mL, a contact time of 5 h, pH 5, a temperature of 25 °C, and a shaking speed of 200 rpm. Their lead removal efficiencies were increased with increasing material dose which might be from the increase of active sites of materials. Their highest lead removal efficiencies were 89.69%, 99.60%, 82.93%, 94.41%, and 95.48% at 0.035 g, 0.020 g, 0.035 g, 0.025 g, and 0.020 g, for ZB, ZBF, ZBB, ZBFB, and ZBBF, respectively. Therefore, they were optimum doses of zeolite A materials that were used for studying the contact time effect.
The effect of contact time
Figure 7b demonstrated the results of the contact time effect of ZB, ZBF, ZBB, ZBFB, and ZBBF on lead adsorptions with the control condition of the lead concentration of 50 mg/L, a sample volume of 200 mL, pH 5, a temperature of 25 °C, a shaking speed of 200 rpm, and the optimum dose of 0.035 g (ZB) or 0.020 g (ZBF) or 0.035 g (ZBB) or 0.025 g (ZBFB) or 0.020 g (ZBBF). Their lead removal efficiencies were increased with increasing contact time similar to the dose effect. Their highest lead removal efficiencies were 87.72%, 98.65%, 80.35%, 92.50%, and 94.61% at 6 h, 3 h, 6 h, 4 h, and 4 h for ZB, ZBF, ZBB, ZBFB, and ZBBF respectively. Therefore, they were optimum contact times of zeolite A materials which were used for studying the pH effect.
The effect of pH
Figure 7c presented the results of the pH effect of ZB, ZBF, ZBB, ZBFB, and ZBBF on lead adsorptions with the control condition of the lead concentration of 50 mg/L, a sample volume of 200 mL, a temperature of 25 °C, a shaking speed of 200 rpm, and the optimum dose of 0.035 g (ZB) or 0.020 g (ZBF) or 0.035 g (ZBB) or 0.025 g (ZBFB) or 0.020 g (ZBBF) and contact time of 6 h (ZB) or 3 h (ZBF) or 6 h (ZBB) or 4 h (ZBFB) or 4 h (ZBBF). Their lead removal efficiencies were increased with increasing pH values from 1 to 5, then they were decreased. Their highest lead removal efficiencies were found at pH 5 with lead removal of 88.45%, 98.55%, 82.84%, 93.20%, and 94.74% for ZB, ZBF, ZBB, ZBFB, and ZBBF, respectively corresponding to the result of zeta potentials of all zeolite A materials that the highest negatively charged was found at pH 5. This result also corresponded to another previous study that reported the highest lead removal efficiency at pH > 4 relating to pHpzc of lead adsorptions in an aqueous solution19. Therefore, pH 5 was the optimum pH of all zeolite A materials which were used for studying the concentration effect.
The effect of initial lead concentration
Figure 7d examined the results of the initial concentration effect of ZB, ZBF, ZBB, ZBFB, and ZBBF on lead adsorptions with the control condition of the lead concentration of 50 mg/L, a sample volume of 200 mL, a temperature of 25 °C, a shaking speed of 200 rpm, and the optimum dose of 0.035 g (ZB) or 0.020 g (ZBF) or 0.035 g (ZBB) or 0.025 g (ZBFB) or 0.020 g (ZBBF), contact time of 6 h (ZB) or 3 h (ZBF) or 6 h (ZBB) or 4 h (ZBFB) or 4 h (ZBBF), and pH of 5. Their lead removal efficiencies were decreased with increasing concentration because lead ions were more than the available active sites of zeolite A materials similar to the reports by other studies12. Lead removal efficiencies from 10 to 70 mg/L of ZB, ZBF, ZBB, ZBFB, and ZBBF were 82.19–98.70%, 92.30–100%, 75.80–97.54%, 85.60–100%, and 87.80–100%, respectively. For the lead concentration of 50 mg/L, their lead removal efficiencies were 90.12%, 99.13%, 82.37%, 93.70%, and 96.53% for ZB, ZBF, ZBB, ZBFB, and ZBBF, respectively, and ZBF demonstrated the highest lead removal efficiency than other materials.
In conclusion, 0.035 g, 6 h, pH 5, 50 mg/L, 0.020 g, 3 h, pH 5, 50 mg/L, 0.035 g, 6 h, pH 5, 50 mg/L, 0.025 g, 4 h, pH 5, 50 mg/L, and 0.020 g, 4 h, pH 5, 50 mg/L were the optimum conditions in dose, contact time, pH, and concentration of ZB, ZBF, ZBB, ZBFB, and ZBBF, respectively, and they could be arranged in order from high to low of ZBF > ZBBF > ZBFB > ZB > ZBB. As a result, the addition of iron(III) oxide-hydroxide into ZB helped to improve material efficiency in both powder and bead forms (ZBF, ZBFB, and ZBBF) whereas only changing material form did not increase lead removal efficiency. As a result, ZBBF might be a good offer for application in industrial wastewater treatment systems with high lead removal efficiency along with easy separation after treatment than other zeolite A materials.
Adsorption isotherms
The adsorption patterns of zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) on lead adsorptions were determined by linear and nonlinear isotherms of Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich models. Their graphical plotting results are demonstrated in Fig. 8a–e, and their isotherm parameters are illustrated in Table 3.
The regression value (R2) is generally used to investigate which isotherm model well explains the adsorption pattern of zeolite A materials. R2 values of ZB, ZBF, ZBB, ZBFB, and ZBBF in both linear and nonlinear Langmuir models were higher than Freundlich, Temkin, and Dubinin–Radushkevich models, so their adsorption patterns corresponded to Langmuir isotherm with relating to the physical adsorption. Since the Langmuir model was well explained for the adsorption pattern of all zeolite A materials, Langmuir parameters of qm and KL values were used to consider which one gave the highest lead adsorption efficiency. The results demonstrated that qm and KL values of ZBF were higher than others, so it might have the highest lead removal efficiency than other zeolite A materials. Moreover, both linear and nonlinear isotherm models were recommended to plot graphs for confirming the results and protecting against data mistranslation43,44,45,46,47,48,49,50.
Finally, the maximum adsorption capacities (qm) of zeolite A materials in this study were compared with other zeolite adsorbents for lead adsorption reported in Table 4. The qm values of all zeolite A materials had higher than previous studies reported in Table 4 except for the studies of Panek et al. and Jangkorn et al19,51. As a result, all zeolite A materials were high potential materials for lead adsorption, and can further apply in industrial applications.
Adsorption kinetics
The adsorption mechanisms of zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) on lead adsorptions were determined by linear and nonlinear isotherms of pseudo-first-order kinetic, pseudo-second-order kinetic, elovich, and intra-particle diffusion models. Their graphical plotting results are demonstrated in Fig. 9a–e, and their isotherm parameters are illustrated in Table 5.
Normally, the regression value (R2) is used to decide which kinetic model well explains the adsorption rate and mechanism of zeolite A materials. R2 values of ZB, ZBF, ZBB, ZBFB, and ZBBF in both linear and nonlinear pseudo-second-order kinetic models were higher than pseudo-first-order kinetic, elovich, and intra-particle diffusion models, so their adsorption rate and mechanism of all zeolite A materials corresponded to a pseudo-second-order kinetic model with relating to the chemisorption process with a heterogeneous adsorption. Since a pseudo-second-order kinetic model was the best-fitted model to explain their adsorption mechanisms, its parameters of qe and k2 values were used to consider which one gave the highest lead adsorption efficiency with a fast reaction. The results illustrated qe and k2 values of ZBF were higher than others, so it might have the highest lead removal efficiency with fast reaction than other zeolite A materials. Finally, the graph plotting of both linear and nonlinear kinetic models was also recommended for correct data translations43,44,45,46,47,48,49,50.
The possible mechanisms for lead adsorption by zeolite A materials
The possible mechanisms of lead adsorptions on zeolite A materials are demonstrated in Fig. 10 which modified the idea from Fan et al., Jangkorn et al., Rahimi et al., and Isawi19,59,60,61. Firstly, lead ions (Pb2+) as positively charged are adsorbed by zeolite A materials by attaching to oxygen ions (O2−) in the structure of zeolite A materials as negatively charged following Lewis acid–base theory creating the strong coordinate bond of lead ions (Pb2+) with oxygen ions (O2−). Secondly, the hydroxyl groups (OH−) of zeolite A materials create the complex formation between hydroxyl group (OH−) and iron(III) oxide-hydroxide (Fe(OH)3) by sharing electron pair and lead ions (Pb2+) are adsorbed by this complex molecule. In addition, the carboxylic groups (–COOH) of sodium alginate formed on the surface of zeolite A materials will adsorb lead ion (Pb2+) by deprotonating hydrogen (H+) of carboxylic groups (–COOH) to be negatively charged. From zeta potential analysis, it demonstrated the negatively charged of all zeolite A materials in all pH values, and pH 5 represented their highest negatively charged in all materials. In addition, the addition of iron(III) oxide-hydroxide in zeolite A materials helped to increase negatively charged on their surfaces increasing lead adsorption, especially ZBF. Finally, lead removal by zeolite A materials might occur through an ion exchange process by releasing hydrogen ions (H+) in hydroxyl groups (OH−) of zeolite A materials instead of lead ions (Pb2+).
Conclusions
Five zeolite A materials of zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) were synthesized from sugarcane bagasse fly ash for lead adsorptions in an aqueous solution. The physicochemical properties of ZB were close values to the zeolite A standard (STD), so it could confirm the ability to synthesize zeolite A in this study. In addition, ZBF had the highest specific surface area and smallest pore size than other zeolite A materials, so it might adsorb lead higher than others. ZB and ZBF demonstrated the crystalline phases whereas ZBB, ZBFB, and ZBBF were amorphous phases. Moreover, the specific peaks of iron(III) oxide-hydroxide or sodium alginate were also detected in ZBF, ZBB, ZBFB, and ZBBF. The surface morphology of ZB was a cubic shape similar to STD related to the specific shape of zeolite A. ZBF demonstrated an agglomerated formation of ZB and iron(III) oxide-hydroxide whereas ZBFB and ZBBF had sphere shapes with coarse surfaces. Six main chemical compositions were Si, Al, O, Fe, Na, and Ca were observed in all zeolite A materials. The four main chemical functional groups of all materials were O–H, (Si, Al)–O, H2O, and D4R whereas –COOH and Si–O–Fe were only found in materials with adding iron(III) oxide-hydroxide or bead material. The surface charges of all zeolite A materials had negatively charged at all pH values, and their surfaces increased more negatively charged with increasing pH value which pH 5 illustrated as the highest negatively charged in all materials. For batch experiments, the optimum conditions of ZB, ZBF, ZBB, ZBFB, and ZBBF were 0.035 g, 6 h, pH 5, 50 mg/L, 0.020 g, 3 h, pH 5, 50 mg/L, 0.035 g, 6 h, pH 5, 50 mg/L, 0.025 g, 4 h, pH 5, 50 mg/L, and 0.020 g, 4 h, pH 5, 50 mg/L, respectively. Lead removal efficiencies of ZB, ZBF, ZBB, ZBFB, and ZBBF at 50 mg/L were 90.12%, 99.13%, 82.37%, 93.70%, and 96.53%, respectively, and it could be arranged in order from high to low of ZBF > ZBBF > ZBFB > ZB > ZBB. Thus, adding iron(III) oxide-hydroxide into ZB improved material efficiency in both powder and bead forms while only changing material form did not increase the lead removal efficiency of zeolite A material. All zeolite A materials corresponded to Langmuir isotherm and pseudo-second-order kinetic models, so their adoption patterns and mechanisms were explained by the physical adsorption and chemisorption with a heterogeneous process, respectively. Although ZBF demonstrated the highest lead removal efficiency than other zeolite A materials, ZBBF might be a good offer for applications in industrial wastewater treatment systems because it was easier separation after treatment than ZBF.
For future works, the desorption experiments need to investigate possibly reusable zeolite A materials, and continuous flow experiments are also necessary to investigate the possible application in the systems of industrial wastewater treatment.
Materials and methods
Raw material
Sugarcane bagasse fly ash was obtained by a sugar factory located in Khon Kaen province, Thailand, and then they were sieved in size of 125 µm before use. For a pretreatment, 20 g of sugarcane bagasse fly ash were burned by a furnace (Vulcan, 3-1750, Canada) with increasing temperature in a step up of 20 °C per min until 600 °C for 4 h. Then, they were cooled at room temperature and kept in a desiccator before use for zeolite A synthesis.
Chemicals
All chemicals used in this study were analytical grades (AR) without purification. Sodium aluminate (NaAlO2) (Sigma-Aldrich, Germany) and sodium hydroxide (NaOH) (RCI Labscan, Thailand) were used for the synthesis of zeolite A sugarcane bagasse fly ash powder. To confirm the occurrence of zeolite A, commercial zeolite A (Sigma-Aldrich, Germany) was used as a representative zeolite A standard (STD). Ferric chloride hexahydrate (FeCl3·6H2O) (RCI Labscan, Thailand) was used for the synthesis of zeolite A sugarcane bagasse fly ash mixed or coated iron(III) oxide-hydroxide in powder and bead materials. Sodium alginate (NaC6H7O6) (Merck, Germany) and calcium chloride (CaCl2) (Kemaus, New Zealand) were used for the bead formations. Lead nitrate (Pb(NO3)2) (QRëC, New Zealand) was used for the synthetic wastewater preparation. For pH adjustments, 1% sodium hydroxide (NaOH) (RCI Labscan, Thailand) and 1% nitric acid (HNO3) (Merck, Germany) were used.
Synthesis of zeolite A sugarcane bagasse fly ash materials
The synthesis of five zeolite A sugarcane bagasse fly ash materials which were zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), and zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) demonstrated in Fig. 11a–d and their synthesis details were below:
Zeolite A sugarcane bagasse fly ash powder (ZB)
Zeolite A bagasse fly ash (ZB) was synthesized by a two-stage method followed by a method of Jangkorn et al19. Firstly, 15 g of pre-treatment sugarcane bagasse fly ash and 22.5 g of NaOH were added to a nickel crucible (United scientific, NCR100, USA) and heated by a furnace (Carbolite, CWF, England) of 550 °C for 40 min. After that, the sample was added to a 1000 mL beaker containing 500 mL of deionized water (DI water), and then it was mixed by a magnetic stirrer of 200 rpm for 30 min called solution 1. Next, 19.1 g of NaAlO2 were added to a 1000 mL beaker containing 500 mL of DI water, and it was mixed by a magnetic stirrer of 200 rpm for 30 min called solution 2. Then, solution 2 was slowly added to a 1000 mL beaker containing solution 1, and they were homogeneously mixed by a magnetic stirrer of 200 rpm for 30 min. Next, 1000 mL of sample were separated to be 200 mL to add in 250 mL of polyethylene bottle in 5 bottles. Then, they were heated by a hot air oven (Binder, FED53, Germany) of 80 °C for 72 h, filtrated, and rinsed with DI water. Finally, they were dried in a hot air oven (Binder, FED53, Germany) of 100 °C for 24 h and kept in a desiccator before use called zeolite A sugarcane bagasse fly ash powder (ZB).
Zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF)
5 g of ZB were added to 500 mL of Erlenmeyer flask containing 160 mL of 5% FeCl3·6H2O, and they were mixed by an orbital shaker (GFL, 3020, Germany) of 200 rpm for 3 h. Then, they were filtrated and air-dried at room temperature for 12 h. After that, they were added to 500 mL of Erlenmeyer flask containing 160 mL of 5% NaOH, and they were mixed by an orbital shaker (GFL, 3020, Germany) of 200 rpm for 1 h. Then, they were filtered, air-dried at room temperature for 12 h, and kept in a desiccator before use called zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF).
Zeolite A sugarcane bagasse fly ash beads (ZBB) or zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB)
5 g of ZB or ZBF were added to 500 mL of a beaker containing 200 mL of 2% NaC6H7O6, and then they were homogeneously mixed and heated by a hot plate (Ingenieurbüro CAT, M. Zipperer GmbH, M 6, Germany) at 60 °C with a constant stirring of 200 rpm. Then, they were dropped by drop by using a 10 mL syringe with a needle size of 1.2 × 40 mm into 250 mL of 0.1 M CaCl2. The beaded samples were soaked in 0.1 M CaCl2 for 24 h, and then they were filtered and rinsed with DI water. After that, they were air-dried at room temperature for 12 h and kept in a desiccator before use called zeolite A sugarcane bagasse fly ash beads (ZBB) or zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB).
Zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF)
Firstly, ZBB were added to 500 mL of Erlenmeyer flask containing 160 mL of 5% FeCl3·6H2O, and they were mixed by an orbital shaker (GFL, 3020, Germany) of 200 rpm for 3 h. Then, they were filtrated and air-dried at room temperature for 12 h. After that, they were added to 500 mL of Erlenmeyer flask containing 160 mL of 5% NaOH, and they were mixed by an orbital shaker (GFL, 3020, Germany) of 200 rpm for 1 h. Then, they were filtered, air-dried at room temperature for 12 h, and kept in a desiccator before use called zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF).
Characterizations of zeolite A materials
Several characterized techniques were used to investigate the specific surface area, pore volumes, pore sizes, crystalline structures, surface morphologies, chemical compositions, chemical functional groups, and surface charges of zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) by using Brunauer–Emmett–Teller (BET) (Quantachrome, QUADRASORB evo™, Austria) by isothermal nitrogen gas (N2) adsorption–desorption at 77.3 K and degas temperature of 80 °C for 6 h, X-ray diffractometer (XRD) (PANalytical, EMPYREAN, United Kingdom) in the range of 2θ = 5–50°, Field emission scanning electron microscopy and focus ion beam (FESEM-FIB) with Energy dispersive X-ray spectrometer (EDX) (FEI, Helios NanoLab G3 CX, USA), Fourier transform infrared spectroscopy (FT-IR) (Thermo Fisher Scientific, Nicolet 6700, USA), and Zetasizer Nano (Malvern, Zetasizer Nano ZS, United Kingdom), respectively.
Batch adsorption studies
A series of batch adsorption studies were carried out for investigating lead adsorption efficiencies on zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) with studying affecting factors of dose, contact time, pH, and concentration, and lead concentrations were analyzed by an Atomic Adsorption Spectrophotometer (AAS) (PerkinElmer, PinAAcle 900F, USA). The details of batch adsorption studies were described below:
Effect of dose
The dosages of zeolite A materials from 0.005 to 0.035 g with the control condition of the initial lead concentration of 50 mg/L, a sample volume of 200 mL, a shaking speed of 200 rpm, a contact time of 5 h, pH 5, and a temperature of 25 °C were used for studying dose effect for lead adsorptions on ZB, ZBF, ZBB, ZBFB, and ZBBF. The lowest dose which represented the highest lead removal efficiency was used as the optimum dose for studying the effect of contact time.
Effect of contact time
The contact times from 1 to 5 h with the control condition of the initial lead concentration of 50 mg/L, a sample volume of 200 mL, a shaking speed of 200 rpm, pH 5, a temperature of 25 °C, and the optimum dose were used for investigating contact time effect for lead adsorptions on ZB, ZBF, ZBB, ZBFB, and ZBBF. The lowest contact time which represented the highest lead removal efficiency was chosen as the optimum contact time for studying of pH effect.
Effect of pH
The pH values of 1, 3, 5, 7, 9, and 11 with the control condition of initial lead concentration of 50 mg/L, a sample volume of 200 mL, a shaking speed of 200 rpm, a temperature of 25 °C, and the optimum dose and contact time were used to investigate the effect of pH for lead adsorptions on ZB, ZBF, ZBB, ZBFB, and ZBBF. The pH value showed the highest lead removal efficiency which was used as the optimum pH for studying the effect of concentration.
Effect of concentration
Lead concentrations from 10 to 70 mg/L with the control condition of a sample volume of 200 mL, a shaking speed of 200 rpm, a temperature of 25 °C, and the optimum dose, contact time, and pH were used to study the effect of concentration for lead adsorptions on ZB, ZBF, ZBB, ZBFB, and ZBBF.
Lead removal efficiency of zeolite A materials in the percentage were calculated by Eq. (1)
where Ce is the equilibrium of lead concentration in the solution (mg/L), C0 is the initial lead concentration (mg/L).
Adsorption isotherms
Linear and nonlinear Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich models are used to investigate the adsorption patterns of zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) for lead adsorptions. Graphs of linear Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich isotherms were plotted by Ce/qe versus Ce, log qe versus log Ce, qe versus ln Ce, and ln qe versus ε2, respectively whereas graphs of their nonlinear were plotted by qe versus Ce. All linear and nonlinear adsorption models were analyzed by following Eqs. (2)–(9)62,63,64,65:
Langmuir isotherm
Freundlich isotherm
Temkin isotherm
Dubinin–Radushkevich isotherm
where Ce is the equilibrium of lead concentration (mg/L), qe is the amount of adsorbed lead on adsorbent materials (mg/g), qm is indicated the maximum amount of lead adsorption on adsorbent materials (mg/g), KL is the adsorption constant (L/mg). KF is the constant of adsorption capacity (mg/g)(L/mg)1/n, and 1/n is the constant depicting the adsorption intensity. R is the universal gas constant (8.314 J/mol K), T is the absolute temperature (K), bT is the constant related to the heat of adsorption (J/mol), and AT is the equilibrium binding constant corresponding to the maximum binding energy (L/g). qm is the theoretical saturation adsorption capacity (mg/g), KDR is the activity coefficient related to mean adsorption energy (mol2/J2), and ε is the Polanyi potential (J/mol).
For adsorption isotherm experiments, 0.035 g of ZB, 0.020 g of ZBF, 0.035 g of ZBB, 0.025 g of ZBFB, and 0.020 g of ZBBF were added to 500 mL Erlenmeyer flasks with variable lead concentrations from 10 to 70 mg/L. The control condition of ZB, ZBF, ZBB, ZBFB, and ZBBF was a sample volume of 200 mL, a shaking speed of 200 rpm, pH 5, a temperature of 25 °C, and a contact time of 6 h for ZB, 3 h for ZBF, 6 h for ZBB, 4 h for ZBFB, and 4 h for ZBBF.
Adsorption kinetics
Linear and nonlinear pseudo-first-order kinetic, pseudo-second-order kinetic, elovich, and intra-particle diffusion models are used to study the adsorption mechanisms of zeolite A sugarcane bagasse fly ash powder (ZB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide (ZBF), zeolite A sugarcane bagasse fly ash beads (ZBB), zeolite A sugarcane bagasse fly ash powder mixed iron(III) oxide-hydroxide beads (ZBFB), and zeolite A sugarcane bagasse fly ash beads coated iron(III) oxide-hydroxide (ZBBF) for lead adsorptions. Graphs of linear pseudo-first-order, pseudo-second-order, elovich, and intra-particle diffusion models were plotted by ln(qe − qt) versus time (t), t/qt versus time (t), qt versus ln t, and qt versus time (t0.5), respectively whereas their nonlinear graphs were plotted by the capacity of lead adsorbed by adsorbent materials at the time (qt) versus time (t). All linear and nonlinear adsorption kinetics were analyzed by the following Eqs. (10)–(16)66,67,68,69:
Pseudo-first-order kinetic model
Pseudo-second-order kinetic model
Elovich model
Intra-particle diffusion model
where qe is the amount of adsorbed lead on adsorbent materials (mg/g), qt is the amount of adsorbed lead at the time (mg/g), k1 is a pseudo-first-order rate constant (min−1), and k2 is a pseudo-second-order rate constant (g/mg min). α is the initial adsorption rate (mg/g/min) and β is the extent of surface coverage (g/mg). ki is the intra-particle diffusion rate constant (mg/g min0.5) and Ci is the constant that gives an idea about the thickness of the boundary layer (mg/g).
For adsorption kinetic experiments, 0.175 g of ZB, 0.100 g of ZBF, 0.175 g of ZBB, 0.125 g of ZBFB, and 0.100 g of ZBBF were added to 1000 mL of breaker with the lead concentration of 50 mg/L. The control condition of ZB, ZBF, ZBB, ZBFB, and ZBBF was a sample volume of 1000 mL, a shaking speed of 200 rpm, pH 5, a temperature of 25 °C, and a contact time of 8 h.
Data availability
The datasets used and/or analyzed during the current study are available from the corresponding author upon reasonable request.
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Acknowledgements
The authors are grateful for the financial support recieved from The Office of the Higher Education Commission and The Thailand Research Fund Grant (MRG6080114), Coordinating Center for Thai Government Science and Technology Scholarship Students (CSTS) and National Science and Technology Development Agency (NSTDA) Fund Grant (SCHNR2016-122), Research and Technology Transfer Affairs of Khon Kaen University.
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Praipipat, P., Ngamsurach, P. & Roopkhan, N. Zeolite A powder and beads from sugarcane bagasse fly ash modified with iron(III) oxide-hydroxide for lead adsorption. Sci Rep 13, 1873 (2023). https://doi.org/10.1038/s41598-023-29055-4
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DOI: https://doi.org/10.1038/s41598-023-29055-4
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