Abstract
Earth’s mantle isotopic composition is highly heterogeneous, with enriched and depleted regions1,2,3 shaped by a complex history of depletion and re-enrichment over 4.5 billion years. The spatial configuration of large-scale heterogeneity in the mantle is not random4,5, but the timing and mechanisms that caused such heterogeneity are still debated2,6,7. We compiled radiogenic isotope data of mid-ocean ridge and plume-induced basalts from both present-day and past oceans for the past 900 million years of the relatively isotopically enriched African mantle domain. Our analysis shows that oceanic rocks of the African mantle domain exhibit a relatively homogenous composition similar to the prevalent mantle estimates (PREMA8) until ca. 350 million years ago when plume-derived rocks started becoming isotopically enriched with maximum enrichment reached in the mid-Cretaceous. From that point in time, plume-derived rocks shift toward depletion, getting closer to the prevalent mantle value. The enrichment trend is interpreted to have resulted from the recycling of crustal material during the assembly and the early stage of a break-up of Gondwana and Pangea, whereas the subsequent depletion trend is due to the outward retreat of the subduction girdle during the break-up of Pangea, thus both are legacies of geodynamic processes related to the supercontinent cycle.
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Introduction
The Earth’s mantle as sampled by its melting products is remarkably heterogeneous. Both mantle-derived basaltic rocks formed along mid-ocean ridges, and plume-induced igneous rocks, display a wide range of distinct isotopic compositions that reflect the long history of mantle depletion and recycling processes1,2,3. Mixing of melts from compositional endmembers or mantle source regions can explain most observed isotopic variabilities in such rocks. One particular end member, the enriched mantle (EM), is believed to be caused by the recycling of continental crustal or lithospheric material2,3,9,10. It has long been recognised that the geographic distribution of rocks with EM signatures is not random, with a North-South isotopic dichotomy being first suggested based on the prevalence of EM compositions in the southern hemisphere6,7, with two enrichment maxima located in the Indian and South-Atlantic Oceans (the Dupal anomaly)4 and the South Pacific Ocean (SOPITA)11, respectively. Such enrichment features were often regarded to have been a long-lived feature of the mantle, perhaps even a primordial feature5. More recently, an east-west hemispheric isotopic dichotomy was identified using samples from deep plumes in the present-day ocean, with a more depleted Pacific mantle domain and a more enriched African mantle domain (Fig. 1a) divided by the circum-Pacific subduction girdle, interpreted to reflect distinct evolutionary histories of the two domains during the Rodinia and Pangea supercontinent cycles12. According to this latter model, the African mantle domain received preferential enrichment during the multiple subduction-collision events responsible for the formation of Gondwana and eventually the supercontinent Pangea, along with ongoing subductions during the existence and later breakup of the supercontinent; whereas the Pacific mantle domain largely avoided of such enrichment since its inception during the breakup of the previous supercontinent Rodinia12,13.
One way to better understand the formation mechanism of such large-scale mantle heterogeneity, and thus potentially to verify the two contrasting mantle dichotomy models, is to examine the starting age of such enrichment. So far, our understanding of the present-day mantle isotopic composition relied entirely on mantle-derived basaltic rocks from the present-day oceanic lithosphere, which is limited to the last 200 Ma14 due to recycling of oceanic lithosphere at convergent margins. However, fragments of older oceanic lithosphere are found as parts of subduction-accretion complexes and obducted ophiolitic complexes in old orogens15. Such rocks would allow us to peer into the isotopic composition of the mantle underlying the now-closed paleo-oceans of deep time. In this paper we systematically investigate the isotopic composition of spreading ridge and plume-induced basaltic rocks preserved in ophiolites through time along suture zones formed during the assembly of Gondwana and Pangea, as well as samples from the present-day African mantle domain oceans, so to document the timing and extent of the mantle enrichment in the African domain.
Clues from past oceans
The more recent full-plate paleogeographic reconstructions suggest that the transition from Rodinia to Pangea supercontinents occurred through the closure of Rodinia’s external superocean, with the proto-Pacific Ocean formed during the break-up of Rodinia which later became the Pangean-time Panthalassa Superocean and now the Pacific Ocean13,16. Therefore, the mantle region that would eventually become the African mantle domain was initially the external oceanic area during 900–700 Ma. The mantle domain of the Rodinia external superocean (the Mirovoi Superocean; Supplementary Fig. 1) would have received little recycled material, at least since the time of Rodinia formation at 900 Ma. As Rodinia disaggregated and its constituent blocks drifted into the external ocean, the oceanic lithosphere in that space would get recycled, but fragments from some of those past oceans have been preserved in the Gondwana- and Pangea-forming sutures.
We compiled data from ophiolite belts of such lost oceans (and related minor seaways) as well as the Paleo-Tethys and Tethyan oceans, and some ophiolites in the Central Asian Orogenic Belt derived from the so-called Paleo-Asian Ocean (Supplementary Fig. 1). The present-day locations of the ophiolite samples are shown in Fig. 1b, and the represented paleo-oceans and sample distributions are shown in Fig. 1c. These ophiolites can be linked back to now-closed paleo-oceanic basins using the geotectonic context of their surrounding terranes and global plate-tectonic reconstruction models16,17. This is demonstrated schematically in Supplementary Fig. 2.
In total, we compiled isotopic data from 88 such ophiolites. While there are 947 Nd isotopic analyses, Sr and Pb isotopic measurements are far less common (Supplementary Fig. 3). The data from ophiolites was used in combination with data from present-day oceanic lithosphere, including normal ocean floor basalts and plume-derived rocks. We focused on oceanic basalts because continental basalts are likely contaminated by continental crust during ascent and storage through the crust which makes any interpretation based on enriched isotopic signatures difficult. The Nd isotopic system not only has the largest number of analyses available in the dataset, but it is also resistant to alteration processes such as seawater alteration18. Therefore, we focus on the Nd isotopic system as a proxy for isotopic enrichment or depletion, because a low Nd isotopic ratio is the most definitive feature of the EM signature1,2,3,6. We divided the ophiolite dataset into two groups: plume-derived ophiolite samples and upper mantle-derived ophiolite samples, with the latter including both supra-subduction zone and mid-ocean ridge-related ophiolites (Supplementary Data 1). The ages of the ophiolites range from 900 to 70 Ma (Supplementary Data 1; Fig. 1). We group supra-subduction zone and ocean ridge basalts because Nd isotopes between basalts of these two environments are almost indistinguishable (Supplementary Fig. 4). The difference between the plume-related and upper mantle-derived samples is highlighted by their distinct incompatible trace element patterns (Supplementary Fig. 5).
A common way of expressing variations in Nd isotopes when studying mantle evolution is using εNd as defined by DePaolo and Wasserburg19, which measures the deviation from the chondritic uniform reservoir (CHUR) reference line. The upper mantle, however, due to isotopic ingrowth, is constantly becoming more depleted relative to CHUR and, consequently, its εNd is increasing over time20. Consequently, two samples with the same εNd value but different ages might possess different degrees of depletion. For this reason, to compare the degree of depletion/enrichment in samples with distinct ages, we propose a new index ΔDM to measure the deviation of Nd isotope composition of a sample from the linear model-depleted mantle that has a present-day εNd = 10, equivalent to a 143Nd/144Nd ratio of 0.5131421 (see Methods); when ΔDM < 0, the sample is more enriched than the depleted mantle, whereas when ΔDM > 0 the sample is more depleted than the depleted mantle. Therefore, the lower the ΔDM value the more isotopically enriched a sample is in terms of Nd isotopes.
Isotopic evolution of the African mantle domain through time
The upper mantle-derived and plume-derived rocks exhibit distinct evolution paths through time (Fig. 2). While the upper mantle-derived rocks present consistent scatter through time, their mean ΔDM values remain relatively constant throughout the post-900 Ma period. On the other hand, the plume-derived rocks display markedly decreased ΔDM values in late Phanerozoic, indicating a long period of increased isotopic enrichment. We modelled the evolution curve of the upper mantle and plume-derived rocks with a non-parametric Gaussian Process approach22 (see Methods). The advantage of such a non-parametric approach is that it can account for the non-uniform distribution of data through time. The Gaussian Process approach models the way correlation between samples varies with distance, where correlation decreases with increasing distance22,23. In this case, distance refers to the time difference between samples. The regression results are shown in Fig. 2. The separation between plume- and upper mantle-derived rocks started from ca.350 Ma, but becomes most striking after 200 Ma. Such results are consistent between different regression methods (Supplementary Fig. 6).
The regression curve for the upper mantle-derived rocks (Fig. 2a) is mostly flat, at ΔDM ~ −2.44, with some minor spikes. On the other hand, the plume-derived rocks display a roughly three-stage evolution in which the trend begins at a similar level to that of the upper mantle-derived rocks, i.e., ΔDM = −3.5, but starts to decrease from ~350 Ma towards isotopic enrichment (more negative ΔDM values) with a minimum ΔDM = −6.87 reached at 100–90 Ma, before it starts to increase again toward upper mantle value (Fig. 2b). The pattern of decrease in ΔDM values is also present if we only look at plume-derived ophiolites (Supplementary Fig. 7). This indicates that the enrichment trend observed is not an artefact of combining the ophiolite and present-day ocean datasets. Furthermore, the means of each 10 Ma bin for the plume-derived samples older than 300 Ma are significantly different at the 95% level from the means of the same sample size drawn from the present-day ocean plume Nd isotopic dataset (see Methods, Supplementary Fig. 8), ruling out the trend being due to sampling density bias. The increasing depletion trend in the data after the minimum ΔDM at 100–90 Ma may partly reflect increased volcanism in the northern hemisphere after 60 Ma, where rocks are generally more isotopically depleted, but even if only southern hemisphere rocks are considered a statistically significant depletion trend can still be observed (Supplementary Fig. 9).
We find further support for isotopic enrichment in the Palaeozoic by zooming in on samples showing extreme isotopic enrichment. Jackson et al.6 suggested a threshold of 0.5126 for discriminating EM compositions. Here we opt to use the present-day 143Nd/144Nd composition of the Chondritic Uniform Reservoir (CHUR)24 as a threshold. By reconstructing the ΔDM CHUR evolution from 900 Ma, we observe that ca. 250 Ma Paleo-Tethyan plume-related rocks of the Tangjia-Sumdo ophiolite25 were more enriched than CHUR. The regression results track the average African mantle domain plume source isotopic composition through time and show that a fundamental change in the plume source had been underway since the beginning of the Late Palaeozoic, and the observation of extreme enrichment at the Palaeozoic-Mesozoic boundary is the result of a longer enrichment process.
A geodynamic cause for the observed mantle isotopic anomalies
The EM signature in plume-derived rocks is commonly attributed to the recycling of crustal materials that are then incorporated into the sources of mantle plume1,2,9,10. Because of its high buoyancy, continental material introduced into the mantle is likely to be exhumed back to the crustal level, or relaminated to the base of the continental lithosphere26. The introduction of continental crustal material in the mantle can be attained by lower crust foundering, sedimentary subduction, subduction erosion, and wholesale continental crust subduction27. In a recent study, Jackson and MacDonald7 suggested that the origin of the EM signature in the mantle was caused by the subduction of rifted passive margins starting at 650 Ma and, therefore, the input of continental crustal material into the mantle. This model explains the generally ancient isotopic signature commonly attributed to recycled materials7, as evidenced mostly by Pb isotopes1 and mass-independent fractionated signatures in S isotopes28, although younger recycled crust materials of 650–200 Ma have also been proposed for some enriched plume sources based on Sr and Os isotopes29,30. However, the contribution of wholesale continental crust recycling in total crustal recycling is relatively minor compared to subduction erosion and sedimentary subduction27, all of which occur in convergent margins which were concentrated in the African domain over the last supercontinent cycle13,16. Therefore, crustal recycling that gave origin to the enriched mantle domains probably happened by a combination of different processes.
The geochemical evolution trend observed for the African mantle domain plume-derived rocks (from both ophiolites and present-day oceans) clearly demonstrates a post-1 Ga origin for the enriched isotopic signal. In addition, EM-signatures are much more widespread in the African mantle domain in comparison to the Pacific mantle domain, particularly prior to 20 Ma (Supplementary Fig. 10), when isotopically enriched volcanism such as that in the Pitcairn and Cook Islands started occurring31,32. Overall, our observations support the presence of an isotopic dichotomy on a hemispheric scale, with the African mantle domain inside the Circum-Pacific subduction girdle being more enriched than the Pacific mantle domain outside of the girdle12.
This interpretation is also supported by the observed ca. 350 Ma onset of the EM signal in the African mantle domain (Fig. 2). The estimates for the processing time of recycled material in the mantle vary, but estimates based on experiments33, and on the calculated slab sinking rates of 1.1 to 1.9 cm/yr34 and plume upwelling times of up to 80–100 Myr35, are in the order of 200–300 Myr7. This lag time between crustal material input, entrainment in the plume source, and finally detection in the plume-derived magmas is consistent with the estimates presented here for the isotopic enrichment of the plume source in the African mantle domain: a ca. 300 Myr lag time between the ca. 650 Ma subduction of passive margin material associated with the assembly of Gondwana7 and the ca. 350 Ma onset of the EM signal. This isotopic tipping point observed at the Late Palaeozoic for the plume source, marking a shift from a relatively steady PREMA-like signature to noticeable isotopic enrichment close to the Palaeozoic-Mesozoic boundary by 250 Ma (Fig. 2) is also close to the time estimate for the formation of an enriched kimberlite reservoir36. Continental crust material was likely also recycled back to the mantle before 650 Ma, but probably mostly into the Rodinia (present-day Pacific) mantle domain. Such an enrichment signal is thus not expected to be seen in the African domain, as shown by our observation (Fig. 2).
We use Fig. 3 to illustrate how the Rodinia-to-Pangea supercontinent cycle might have caused the observed mantle enrichment trend. After the breakup of Rodinia at ca 700 Ma37, its constituent continental blocks drifted into the external oceanic domain (Fig. 3a, b). Some continental blocks later collided to form Gondwana by ca. 540 Ma16. Coupled zircon U-Pb and Hf data indicate net continental loss during the amalgamation of Gondwana38, which suggests strong continental crustal recycling during this period, introducing low 143Nd/144Nd material in the mantle. Moreover, Gondwana possessed large peripheral orogens (Terra Australis, Avalonian-Cadomian, North Indo-Australie)39 that must have allowed for sustained input of crustal material into the African mantle domain through sedimentary subduction and subduction erosion, even before the formation of the circum-Pacific subduction girdle at Pangea times (Fig. 3c, d). Based on the almost continuous isotopic record provided by the ophiolites, we envisage a scenario where the transition from Rodinia to Gondwana during the Neoproterozoic, and accompanying change in subduction polarity along the margin of the growing Paleo-Pacific Ocean (Fig. 3a, b), that caused a switch in the recycled material accumulation locus12,13 (Fig. 3). This switch coincided with the beginning of passive margin subduction at ca. 650 Ma, allowing wholesale continental subduction and a larger input of recycled material into the future African mantle domain (shown in beige colour in Fig. 3)7. Rodinia’s external oceanic domain (future African mantle domain; Fig. 3a) therefore switched from receiving no recycled material to receiving the largest share of it, eventually yielding the enriched isotopic signature that characterises the African mantle domain. After the formation of Gondwana and eventually Pangea, the continued presence of the circum-African mantle domain subduction girdle (now the circum-Pacific subduction girdle) means that crustal materials would have continuously been recycled into the African mantle domain12 (Fig. 3c, d), causing the steady enrichment through time past >600 Ma. The origin of the enriched isotopic signal in the African mantle domain is thus a consequence of global geotectonic evolution since the Neoproterozoic, which concentrated subduction in the African mantle domain relative to the Pacific mantle domainomain, creating the prevalence of enriched isotopic signatures in the African Domain since late Palaeozoic.
We note that our analysis based on the reconstruction model of reference13 remains valid for other recent global reconstruction models16,17. Although the shapes of oceanic basins might vary between reconstruction models, their relative positions in terms of continental break-up and amalgamation remain similar. For example, in all these models the Paleo-Pacific Ocean opened by the break-up of Rodinia between the present-day eastern Australian and western North American margins (with or without South China and other continental blocks in-between), which eventually evolved into the Panthalassa superocean and now the Pacific Ocean. On the other hand, in all these models Pangaea assembled through the closure of the previous superocean, i.e., an extroversion assembly of Pangaea.
Our regression model also suggests that the plume sources in the African mantle domain are progressively becoming less enriched after the late Cretaceous time. We interpret this as a possible consequence of a reduction in recycled continental crustal material into the mantle of the African mantle domain as the subduction girdle grows larger and further away from the AMD plume source regions during Pangea’s break-up (Fig. 3c, d). This would imply that large-scale geochemical anomalies in the mantle might be evolving features reflective of the planet’s geodynamic evolution through time, instead of static features present since early Earth.
Methods
Data compilation
The samples presented in the isotopic dataset of ophiolites were compiled from 88 ophiolites with ages spanning from 900 to 70 Ma. The radiogenic ingrowth-correction ages were provided using the same references as the samples. Only tholeiitic alkaline and mafic samples with metamorphism not beyond amphibolite facies were considered in the compilation. The filtered dataset contains 947 samples, which were divided into four categories: MOR (mid-ocean ridge-like), SSZ (supra-subduction zone), OIB (ocean island basalt-like), and OPB (oceanic plateau-like). The categorisation was based on trace element signatures and geological context as documented in the literature. The Sm-Nd isotopic system was utilised because of its representativeness and resistance to alteration. This system is very resistant to alteration by seawater due to the low abundance of Sm and Nd in this fluid (8 × 10−7 and 4 × 10−6 ppm, respectively18,40). Thus, even highly altered oceanic crust can still retain comparable 143Nd/144Nd ratios to that of mid-ocean ridge basalt18.
The ophiolite data was used together with data from samples from present-day oceans to build a full evolutionary picture. Data from mid-ocean ridges in the African domain (the Atlantic, Indian and Arctic oceans) was taken from the compilation of Stracke et al.41. We also used data from old oceanic crust compiled from PetDB (https://earthchem.org/). Where age data was not readily available for the ocean floor samples in PetDB, we utilised a 6-arc minute resolution age grid of the present-day ocean floor based on the Seton et al.14 model of ocean floor ages to estimate the age for the sample.
Current oceanic plume data used were collected from the compilations of Homrighausen et al.42 and Olierook et al.43 for the Tristan-Walvis and Kerguelen plumes, respectively, and from the compilation of Stracke et al.41 for Réunion, Iceland, Faroe Islands, Jan Mayen, Madeira, Ascension, Amsterdam and St. Paul, Canary Islands, Cape Verde and Azores. We also compiled data from the Crozet, Afanasy-Nikitin, Discovery, Meteor-Shona and Trindade tracks (see relevant references in Supplementary Data 1).
ΔDM calculation
Delta DM was calculated as the deviation from a linear model depleted mantle21 in the same way, as εNd is calculated as a deviation from the CHUR evolution line. Depleted mantle values were back-calculated using present-day 147Sm/144Nd and 143Nd/144Nd values of 0.22244 and 0.5131421, respectively. For samples with initial εNd reported but without the Nd isotopic ratio, the initial ratio was estimated from the εNd value. The equation for calculating ΔDM is similar to that of εNd:
Statistical methods
Given the non-uniform sample distribution through time, we adopted a non-parametric approach for regression of ΔDM values. We utilised Gaussian Process regression22 through the scikit-learn library (version 1.2.2)45 for Python. ΔDM values were pooled into bins of 10 million years, and the mean value of each bin was used as the input value for the regression. Plume-related rocks (OIB and OPB) and upper mantle-related (MOR and SSZ) were treated separately. For both plume and upper mantle rocks, the Kernel was set as a sum of constant kernel (modifier of the mean of the Gaussian process), Matérn kernel (with ν = 1.5) and white noise kernel. The hyperparameters for each dataset were optimised by attempting to maximise the log marginal likelihood of the model using the built-in scikit-learn algorithm. The optimised length scales for the Matérn kernels were 75.3 and 5.64 for the plume and upper mantle-related rocks, respectively. The other regression methods used for comparison with the Gaussian Process were the generalised additive model (GAM) smoothing23,46, with adaptative and thin-plate smoothing and LOWESS47. The GAMs were fitted using the mgcv48 package for R. In the GAM approach, the means of each 10 Ma bin were weighted by the number of samples used to calculate the mean. The adaptative GAM smooth for the plume-related rocks had 3.88 effective degrees of freedom (edf) with a p-value of 1.34*10−6 and 72% of deviance explained, whereas for the upper mantle-related rocks the edf was 2.612 with a non-significant p-value of 0.0528 and 16.8% of deviance explained. The thin-plate GAM smooth had a higher edf of 5.779 and a p-value of 2.06*10−5 and 71.4% of deviance explained for the plume-related rocks. Thin-plate regression for the upper mantle-related rocks has an edf of 2.955 with a non-significant p-value of 0.366 and 12% deviance explained. The LOWESS was fit with the statsmodels package for Python (v. 0.14.0)49.
To account for sampling bias, we compared the means of each of the 10 Ma bins of the plume dataset to the means of one thousand re-sampling of the same sample size drawn from the Nd isotopic dataset of present-day plume-derived rocks in order to test the statistical significance of the limited sample sizes per age bin. For example, if 15 analyses were used to determine the mean at a given age bin, the means of 1000 sets of 15 analyses drawn from the present-day dataset were used to determine the confidence intervals at the 1σ (68%) and 2σ (95%) levels. Although for some samples older than 300 Ma, the mean is not distinguishable from the present-day distribution at the 95% confidence level, the mean ΔDM value for rocks older than 300 Ma is significantly different at the 95% confidence level from the present-day distribution, while for rocks younger than 300 Ma the means cannot be statistically distinguished (Supplementary Fig. 8).
Data availability
Supplementary Data 1 contains all the supporting data for this article and can be accessed at: https://figshare.com/articles/dataset/SupplementaryTable1_xlsx/26242157.
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Acknowledgements
This study was supported by the Australian Research Council Laureate Fellow grant (FL150100133) and the National Natural Science Foundation of China PGP RFIS-III grant (42350710792) awarded to ZXL. PABS would like to acknowledge Curtin University for PhD scholarship no. RES55354. We thank Jiten Pattnaik and two anonymous reviewers for their comments and suggestions.
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P.A.B.S.: writing—original draft, visualisation, conceptualisation, methodology, investigation, data curation. Z.X.L.: writing—review and editing, conceptualisation, visualisation, supervision, funding acquisition. L.S.D.: writing—review and editing, conceptualisation, visualisation, supervision.
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Communications Earth & Environment thanks Nicolas Flament, Jiten Pattnaik and the other, anonymous, reviewer(s) for their contribution to the peer review of this work. Primary handling editor: Carolina Ortiz Guerrero. A peer review file is available.
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de Sampaio, P.A.B., Li, ZX. & Doucet, L.S. Global mantle isotopic anomalies linked to supercontinent-superocean evolution for the past 700 million years. Commun Earth Environ 5, 468 (2024). https://doi.org/10.1038/s43247-024-01627-w
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DOI: https://doi.org/10.1038/s43247-024-01627-w
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